Evolution de la structure de la couche limite planetaire sur des sites oceaniques et continentaux

We have studied the evolution of the planetary boundary layer using both oceanic and continental stations. This has been possible through the analysis of twice-daily temperature radiosondes at three different oceanic stations (Point A; Point K; and Azores) and also at three continental stations (Berlin, Trappes and Madrid) all situated in the Northern Hemisphere. We have studied the annual evolution of mixing layers and of temperature inversion levels; an annual evolution presenting a minimum in winter and a maximum in summer has been observed in the continental stations; the oceanic stations present a lesser variation and in the opposite sense. As for the elevated inversion layers, their maximum frequency can be observed in summer at the oceanic stations and in winter at the continental stations. We have shown that considering the studied stations, both the level and the frequency of the elevated inversion layers are similar at 00 h and at 12 h; such a result is important because these layers regulate the intensity of the exchanges between the ground and the free atmosphere. Using the equivalent coefficient, we have determined the annual variation of the vertical exchanges between the surface and different altitudes. At the continental stations, the vertical exchanges are more important in summer than they are in winter; the opposite behaviour occurs at the oceanic stations.     

The danger of overvaluing methane’s influence on future climate change

Minimizing the future impacts of climate change requires reducing the greenhouse gas (GHG) load in the atmosphere. Anthropogenic emissions include many types of GHG’s as well as particulates such as black carbon and sulfate aerosols, each of which has a different effect on the atmosphere, and a different atmospheric lifetime. Several recent studies have advocated for the importance of short timescales when comparing the climate impact of different climate pollutants, placing a high relative value on short-lived pollutants, such as methane (CH₄) and black carbon (BC) versus carbon dioxide (CO₂). These studies have generated confusion over how to value changes in temperature that occur over short versus long timescales. We show the temperature changes that result from exchanging CO₂ for CH₄ using a variety of commonly suggested metrics to illustrate the trade-offs involved in potential carbon trading mechanisms that place a high value on CH₄ emissions. Reducing CH₄ emissions today would lead to a climate cooling of approximately ~0.5 °C, but this value will not change greatly if we delay reducing CH₄ emissions by years or decades. This is not true for CO₂, for which the climate is influenced by cumulative emissions. Any delay in reducing CO₂ emissions is likely to lead to higher cumulative emissions, and more warming. The exact warming resulting from this delay depends on the trajectory of future CO₂ emissions but using one business-as usual-projection we estimate an increase of 3/4 °C for every 15-year delay in CO₂ mitigation. Overvaluing the influence of CH₄ emissions on climate could easily result in our “locking” the earth into a warmer temperature trajectory, one that is temporarily masked by the short-term cooling effects of the CH₄ reductions, but then persists for many generations.     

A quantitative reconstruction of organic matter and nutrient diagenesis in Mediterranean Sea sediments over the Holocene

A multicomponent diagenetic model was developed and applied to reconstruct the conditions under which the most recent sapropel, S1, was deposited in the eastern Mediterranean Sea. Simulations demonstrate that bottom waters must have been anoxic and sulphidic during the formation of S1 and that organic matter deposition was approximately three times higher than at present. Nevertheless, most present day sediment and pore water profiles — with the exception of pyrite, iron oxyhydroxides, iron-bound phosphorus and phosphate — can be reproduced under a wide range of redox conditions during formation of S1 by varying the depositional flux of organic carbon. As a result, paleoredox indicators (e.g., C_org:S ratio, C_org:P_org ratio, trace metals) are needed when assessing the contribution of oxygen-depletion and enhanced primary production to the formation of organic-rich layers in the geological record. Furthermore, simulations show that the organic carbon concentration in sediments is a direct proxy for export production under anoxic bottom waters.The model is also used to examine the post-depositional alteration of the organic-rich layer focussing on nitrogen, phosphorus, and organic carbon dynamics. After sapropel formation, remineralisation is dominated by aerobic respiration at a rate that is inversely proportional to the time since bottom waters became oxic once again. A sensitivity analysis was undertaken to identify the most pertinent parameters in regulating the oxidation of sapropels, demonstrating that variations in sedimentation rate, depositional flux of organic carbon during sapropel formation, bottom water oxygen concentration, and porosity have the largest impact. Simulations reveal that sedimentary nutrient cycling was markedly different during the formation of S1, as well as after reoxygenation of bottom waters. Accumulation of organic nitrogen in sediments doubled during sapropel deposition, representing a significant nitrogen sink. Following reventilation of deep waters, N₂ production by denitrification was almost 12 times greater than present day values. Phosphorus cycling also exhibits a strong redox sensitivity. The benthic efflux of phosphate was up to 3.5 times higher during the formation of S1 than at present due to elevated depositional fluxes of organic matter coupled with enhanced remineralisation of organic phosphorus. Reoxygenation of bottom waters leads to a large phosphate pulse to the water column that declines rapidly with time due to rapid oxidation of organic material. The oxidation of pyrite at the redox front forms iron oxyhydroxides that bind phosphorus and, thus, attenuate the benthic phosphate efflux. These results underscore the contrasting effects of oxygen-depletion on sedimentary nitrogen and phosphorus cycling. The simulations also confirm that the current conceptual paradigm of sapropel formation and oxidation is valid and quantitatively coherent.     

Preface: Proceedings of the 5th International Symposium on Lithographic Limestone and Plattenkalk

Magmatic rocks from the pre-Mesozoic basements of the Sambuco and Maggia nappes have been dated by U–Pb zircon ages with the LA-ICPMS technique. Several magmatic events have been identified in the Sambuco nappe. The mafic banded calc-alkaline suite of Scheggia is dated at 540 Ma, an age comparable to that of mafic rocks in the Austroalpine Silvretta nappe. The Sasso Nero peraluminous augengneiss has an age of 480–470 Ma, like many other “older orthogneisses” in Alpine basement units. It hosts a large proportion of inherited zircons, which were dated around 630 Ma, a Panafrican age indicating the Gondwanan affiliation of the Sambuco basement. The calc-alkaline Matorello pluton yielded ages around 300 Ma, similar to numerous Late Carboniferous intrusions in other basement units of the Lower Penninic (Monte Leone, Antigorio, Verampio) and Helvetic domains (Gotthard and other External Crystalline Massifs). Associated lamprophyric dykes are slightly younger (300–290 Ma), like similar dykes sampled in gneiss blocks included in the sedimentary cover of the underlying Antigorio nappe (290–285 Ma). The Cocco granodiorite and Rüscada leucogranite, both intruding the basement of the neighbouring Maggia nappe, yielded ages of ca. 300–310 Ma, identical within errors to the age of the Matorello pluton. They are significantly older than former age determinations. This age coincidence, coupled with remarkable petrologic similarities between the Cocco and Matorello granodiorites, strongly suggests paleogeographic proximity of the Sambuco and Maggia nappes in Late Carboniferous times. In recent publications these two nappes have been interpreted as belonging to distinct Mesozoic paleogeographic domains: “European” for Sambuco and “Briançonnais” for Maggia, separated by the “Valais” oceanic basin. In this case, the similarity of the Matorello and Cocco intrusions would demonstrate the absence of any significant transcurrent movement between these two continental domains. Alternatively, according to a more traditional view, Sambuco and Maggia might belong to a single large Alpine tectonic unit.     

Metasomatized lithospheric mantle beneath Turkana depression in southern Ethiopia (the East Africa Rift): geochemical and Sr–Nd–Pb isotopic characteristics

Mantle xenoliths entrained in Quaternary alkaline basalts from the Turkana Depression in southern Ethiopia (the East Africa Rift) were studied for their geochemical and Sr–Nd–Pb isotopic compositions to constrain the evolution of the lithosphere. The investigated mantle xenoliths are spinel lherzolites in composition with a protogranular texture. They can be classified into two types: anhydrous and hydrous spinel lherzolites; the latter group characterized by the occurrences of pargasite and phlogopite. The compositions of whole-rock basaltic component (CaO = 3.8–5.6 wt%, Al₂O₃ = 2.5–4.1 wt%, and MgO = 34.7–38.1 wt%), spinel (Cr# = 0.062–0.117, Al₂O₃ = 59.0–64.4 wt%) and clinopyroxene (Mg# = 88.4–91.7, Al₂O₃ = 5.2–6.7 wt%) indicate that the lherzolites are fertile and have not experienced significant partial melting. Both types are characterized by depleted ⁸⁷Sr/⁸⁶Sr (0.70180–0.70295) and high ¹⁴³Nd/¹⁴⁴Nd (0.51299–0.51348) with wide ranges of ²⁰⁶Pb/²⁰⁴Pb (17.86–19.68) isotopic compositions. The variations of geochemical and isotopic compositions can be explained by silicate metasomatism induced by different degree of magma infiltrations from ascending mantle plume. The thermobarometric estimations suggest that the spinel lherzolites were derived from depths of 50–70 km (15.6–22.2 kb) and entrained in the alkaline magma at 847–1,052°C. Most of the spinel lherzolites from this study record an elevated geotherm (60–90 mW/m²) that is related to the presence of rising mantle plume in an active tectonic setting. Sm–Nd isotopic systematic gives a mean T_DM model age of 0.95 Ga, interpreted as the minimum depletion age of the subcontinental lithosphere beneath the region.     

Regionalisation of population growth projections in coastal exposure analysis

Large-area coastal exposure and impact analysis has focussed on using sea-level rise (SLR) scenarios and has placed little emphasis on socioeconomic scenarios, while neglecting spatial variations of population dynamics. We use the Dynamic Interactive Vulnerability Assessment (DIVA) Framework to assess the population exposed to 1 in 100-year coastal flood events under different population scenarios, that are consistent with the shared socioeconomic pathways (SSPs); and different SLR scenarios, derived from the representative concentration pathways (RCPs); and analyse the effect of accounting for regionalised population dynamics on population exposure until 2100. In a reference approach, we use homogeneous population growth on national level. In the regionalisation approaches, we test existing spatially explicit projections that also account for urbanisation, coastal migration and urban sprawl. Our results show that projected global exposure in 2100 ranges from 100 million to 260 million, depending on the combination of SLR and population scenarios and method used for regionalising the population projections. The assessed exposure based on the regionalised approaches is higher than that derived from the reference approach by up to 60 million people (39%). Accounting for urbanisation and coastal migration leads to an increase in exposure, whereas considering urban sprawl leads to lower exposure. Differences between the reference and the regionalised approaches increase with higher SLR. The regionalised approaches show highest exposure under SSP5 over most of the twenty-first century, although total population in SSP5 is the second lowest overall. All methods project the largest absolute growth in exposure for Asia and relative growth for Africa.     

Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston,Texas urban area

As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~10² atoms cm⁻³ and 50 _{- 30} ^{+ 70} ×10⁴ 50_{ - 30}^{ + 70} \times {10^4} atoms cm⁻³. Cl concentration during all the episodes averaged 7.6 _{- 2.0} ^{+ 4.7} ×10⁴ 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm⁻³ and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.