Nutrient attenuation in a shallow,gravel-bed river. II. Spatial and temporal changes in nitrogen dynamics and community metabolism

ABSTRACT

Instream processes alter the concentration and bioavailability of nutrients as they are transported downstream. By relating primary production and periphyton composition to changes in nutrient concentration in a gravel-bed river this study made inferences about recycling and attenuation. Where dissolved inorganic nitrogen (DIN) was abundant, concentrations decreased linearly with distance but by less than required to meet the nitrogen demand of primary production. Where DIN was barely measurable photosynthesis was reduced but only by 50%. We infer that recycling sustained primary production even when DIN concentrations were negligibly small. One implication is that DIN removal underestimates attenuation. Further experimental research on recycling and improved modelling is required to better quantify the length of streams adversely affected by nutrients.     

GIScience Journals Ranking and Evaluation: An International Delphi Study

Researchers’ fame in most scientific fields is closely linked to their publishing capacity, both in terms of quantity and quality. In GIScience, as in other fields, this situation demands that the researcher evaluate and to be very familiar with the scientific journals in which they could publish. Some specialized journals (e.g. Journal of Citation Reports or JCR) are devoted to ranking these reviews according to various methods and criteria. Compared to other scientific communities, GIScience is relatively new and constantly evolving. Therefore, the journals of this field do not benefit from any real formal ranking yet. The objective of this paper is to present the process and results of a study aimed at addressing this gap. More specifically, the challenge is to elaborate an importance ranking of the scientific journals in the field of GIScience. To do so, both a qualitative (Delphi study carried out with 40 international experts) and a quantitative (JCR impact factor) approach has been implemented. This triangulation method leads to an early global ranking of the journals of this field.     

Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.     

Behavioural-geographical aspects of environmental quality

The behavioural approach in human geography accentuates the view of quality of the environment through man and his value orientations. The quality of environment from the point of view of human experience raises behavioural-geographical questions that are the core of the presented topic. Aspects of environmental imaginations and sensations as well as human value system are presented as variables affecting the structure of the perceived environment and human spatial behaviour. In this context, the authors present results of two behavioural studies that correspond to new models of man and environment from the viewpoint of a behavioural approach. The suggested humanistic approach in behavioural geography emphasizes above all the emotional aspect of the relationship between man and environment, which through environmental values, spatial sensations, and meanings, leads to human spatial behaviour.     

An analysis of the time scales of variability in centuries-long enso-sensitive records in the last 1000 years

We document the characteristic time scales of variability for seven climate indices whose time-dependent behavior is sensitive to some aspect of the El Niño/Southern Oscillation (ENSO). The ENSO sensitivity arises from the location of these long-term records on the periphery of the Indian and Pacific Oceans. Three of the indices are derived principally from historical sources, three others consist of tree-ring reconstructions (one of summer temperature, and the other two of winter rainfall), and one is an annual record of oxygen isotopic composition for a high-elevation glacier in Peru. Five of the seven indices sample at least portions of the Medieval Warm Period (~ A.D. 950 to 1250).Time series spectral analysis was used to identify the major time scales of variability among the different indices. We focus on two principal time scales: a high frequency band (~ 2–10 yr), which comprises most of the variability found in the modern record of ENSO activity, and a low frequency band to highlight variations on decadal to century time scales (11 <P < 150 yr). This last spectral band contains variability on time scales that are of general interest with respect to possible changes in large-scale air-sea exchanges. A technique called evolutive spectral analysis (ESA) is used to ascertain how stable each spectral peak is in time. Coherence and phase spectra are also calculated among the different indices over each full common period, and following a 91-yr window through time to examine whether the relationships change.In general, spectral power on time scales of ~ 2–6 yr is statistically significant and persists throughout most of the time intervals sampled by the different indices. Assuming that the ENSO phenomenon is the source of much of the variability at these time scales, this indicates that ENSO has been an important part of interannual climatic variations over broad areas of the circum-Pacific region throughout the last millennium. Significant coherence values were found for El Niño and reconstructed Sierra Nevada winter precipitation at ~ 2–4 yr throughout much of their common record (late 1500s to present) and between 6 and 7 yr from the mid-18th to the early 20th century.At decadal time scales each record generally tends to exhibit significant spectral power over different periods at different times. Both the Quelccaya Ice Cap ¹⁸O series and the Quinn El Niño event record exhibit significant spectral power over frequencies ~ 35 to 45 yr; however, there is low coherence between these two series at those frequencies over their common record. The Sierra Nevada winter rainfall reconstruction exhibits consistently strong variability at periods of ~ 30–60 yr.     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie     

The role of bathymetry and directional wave conditions on observed crescentic bar dynamics

Nearshore sandbars are important features in the surf zone of many beaches because they strongly influence the mean circulation and evolving morphology. Due to variations in wave conditions, sandbars can experience cross-shore migration and vary in shape from alongshore uniform (shore-parallel) to alongshore rhythmic (crescentic). Sandbar dynamics have been studied extensively, but existing observational studies usually do not quantify the processes leading to crescentic bar formation and straightening. This study analyses the dynamics of crescentic bar events at the fetch-limited beach of Castelldefels (northwestern Mediterranean Sea, Spain) using 7.5 years of hourly time-exposure video images and detailed wave conditions. The results show that, despite the generally calm wave conditions, the sandbars were very dynamic in the cross-shore and longshore directions. They often migrated rapidly offshore during storms (up to 70 m in one day) and more slowly onshore during post-storm conditions. Crescentic bars were often present at the study site (48% of the time), but only when the sandbar was at least 10 m from the shoreline. They displayed a large variability in wavelengths (100–700 m), alongshore migration speeds (0–50 m/day) and cross-shore amplitudes (5–20 m). Wavelengths increased for larger bar–shoreline distances and the alongshore migration speeds were strongly correlated with the alongshore component of the radiation stresses. Crescentic patterns typically developed during low–medium energetic waves with limited obliquity ( $\theta \lesssim 20$° at 10 m depth), while bar straightening occurred during medium–high energetic waves with strong oblique angles of incidence ( $\theta \gtrsim 15$°). Overall, this study provides further proof for the important role of wave direction in crescentic bar dynamics and highlights the strong dependence of crescentic bar development on the initial bathymetric configuration.     

Ozone production due to emissions from vegetation burning

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.