Seismic stratigraphy, buried beach ridges and contourite drifts: the Late Quaternary history of the closed Lago Cardiel basin, Argentina (49°S)

The results of a seismic stratigraphic analysis of a closed lake basin, Lago Cardiel, in southernmost South America are reported. Very few high-resolution, continental records spanning the Late Quaternary have been obtained from this region. Seismic sequence stratigraphic analysis allows a reconstruction of lake level variations. Two major hiatuses of unknown age occurred during the early evolution of the basin with the deposition of an alluvial fan in a restricted area in the intervening time period. Following the development of a relatively shallow lake during the late Pleistocene and a short desiccation pulse around 11 220 ¹⁴C yr BP, a transgression of over 135 m occurred at the beginning of the Holocene. The transgression was associated with the formation of beach ridges preserved in the lake stratigraphy on the floor of the modern Lago Cardiel at four different elevations. The preservation of largely unreworked beach ridges indicates a stepwise rise in the lake level. There is no seismic evidence of a major lowering of the lake below modern level during the entire Holocene. Deposition since the mid-Holocene is marked by strong lateral differences in sediment accumulation with a depocentre slightly to the north of the basin midpoint and a pronounced mounded distribution. Seismic reflection geometries, as well as sedimentological characteristics indicate a lacustrine contourite drift covering an area of 80–100 km². As Lago Cardiel is under the influence of westerly winds, these most likely drove lake circulation. The identification of drowned beach ridges and of contourite drifts illustrates that high-resolution seismic stratigraphy is not only a powerful tool in reconstructing past lake level elevations for closed lake basins, but it can also provide information about the rate of lake level changes and the presence and strength of lake currents.     

Ab initio study of the high-pressure behavior of CaSiO3 perovskite

Using density functional simulations, within the generalized gradient approximation and projector-augmented wave method, we study structures and energetics of CaSiO₃ perovskite in the pressure range of the Earths lower mantle (0–150 GPa). At zero Kelvin temperature the cubic CaSiO₃ perovskite structure is unstable in the whole pressure range, at low pressures the orthorhombic (Pnam) structure is preferred. At 14.2 GPa there is a phase transition to the tetragonal (I4/mcm) phase. The CaIrO₃-type structure is not stable for CaSiO₃. Our results also rule out the possibility of decomposition into oxides.

Application of lead stable isotopes to the Guadiamar Aquifer study after the mine tailings spill in Aznalcóllar (SW Spain)

On 25 April 1998 the tailings dam of the Aznalcóllar mine burst, a great quantity of pyrite waste sludge and acid water was spilled reaching the vicinity of the Doñana National Park. In surface and ground water samples taken a week after dam breaking, metals, trace elements and Pb isotopic ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) were analysed. In September 1998 a second sampling survey was carried out. The surface waters have a similar isotopic composition as the lead contained in the pyrite from the Aznalcóllar mine. The polluted groundwater of the Guadiamar aquifer also shows the influence of the mining origin of the lead. Lead isotope ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) in the groundwater of the Almonte-Marismas are very low and they differ clearly from the rest of groundwater samples. A further group of wells has a lead isotope composition intermediate between the Aznalcóllar mine and the atmospheric aerosols of the Iberian Peninsula.     

Inverse problem in hydrogeology

The state of the groundwater inverse problem is synthesized. Emphasis is placed on aquifer characterization, where modelers have to deal with conceptual model uncertainty (notably spatial and temporal variability), scale dependence, many types of unknown parameters (transmissivity, recharge, boundary conditions, etc.), nonlinearity, and often low sensitivity of state variables (typically heads and concentrations) to aquifer properties. Because of these difficulties, calibration cannot be separated from the modeling process, as it is sometimes done in other fields. Instead, it should be viewed as one step in the process of understanding aquifer behavior. In fact, it is shown that actual parameter estimation methods do not differ from each other in the essence, though they may differ in the computational details. It is argued that there is ample room for improvement in groundwater inversion: development of user-friendly codes, accommodation of variability through geostatistics, incorporation of geological information and different types of data (temperature, occurrence and concentration of isotopes, age, etc.), proper accounting of uncertainty, etc. Despite this, even with existing codes, automatic calibration facilitates enormously the task of modeling. Therefore, it is contended that its use should become standard practice.

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Resumen Se sintetiza el estado del problema inverso en aguas subterráneas. El énfasis se ubica en la caracterización de acuíferos, donde los modeladores tienen que enfrentar la incertidumbre del modelo conceptual (principalmente variabilidad temporal y espacial), dependencia de escala, muchos tipos de parámetros desconocidos (transmisividad, recarga, condiciones limitantes, etc), no linealidad, y frecuentemente baja sensibilidad de variables de estado (típicamente presiones y concentraciones) a las propiedades del acuífero. Debido a estas dificultades, no puede separarse la calibración de los procesos de modelado, como frecuentemente se hace en otros campos. En su lugar, debe de visualizarse como un paso en el proceso de entendimiento del comportamiento del acuífero. En realidad, se muestra que los métodos reales de estimación de parámetros no difieren uno del otro en lo esencial, aunque sí pueden diferir en los detalles computacionales. Se discute que existe amplio espacio para la mejora del problema inverso en aguas subterráneas: desarrollo de códigos amigables al usuario, acomodamiento de variabilidad a través de geoestadística, incorporación de información geológica y diferentes tipos de datos (temperatura, presencia y concentración de isótopos, edad, etc), explicación apropiada de incertidumbre, etc. A pesar de esto, aún con los códigos existentes, la calibración automática facilita enormemente la tarea de modelado. Por lo tanto, se sostiene que su uso debería de convertirse en práctica standard.

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Résumé Létat du problème inverse des eaux souterraines est synthétisé. Laccent est placé sur la caractérisation de laquifère, où les modélisateurs doivent jouer avec lincertitude des modèles conceptuels (notamment la variabilité spatiale et temporelle), les facteurs déchelle, plusieurs inconnues sur différents paramètres (transmissivité, recharge, conditions aux limites, etc.), la non linéarité, et souvent la sensibilité de plusieurs variables détat (charges hydrauliques, concentrations) des propriétés de laquifère. A cause de ces difficultés, le calibrage ne peut être séparé du processus de modélisation, comme cest le cas dans dautres cas de figure. Par ailleurs, il peut être vu comme une des étapes dans le processus de détermination du comportement de laquifère. Il est montré que les méthodes dévaluation des paramètres actuels ne diffèrent pas si ce nest dans les détails des calculs informatiques. Il est montré quil existe une large panoplie de techniques d ‹inversion : codes de calcul utilisables par tout-un-chacun, accommodation de la variabilité via la géostatistique, incorporation dinformations géologiques et de différents types de données (température, occurrence, concentration en isotopes, âge, etc.), détermination de lincertitude. Vu ces développements, la calibration automatique facilite énormément la modélisation. Par ailleurs, il est souhaitable que son utilisation devienne une pratique standardisée.

     

Summary results from a pilot study conducted around an oil production platform on the Northwest Shelf of Australia

The Australian Institute of Marine Science (AIMS) conducted a pilot study around the Harriet A oil production platform on the Northwest Shelf of Australia. We evaluated hepatic ethoxyresorufin-O-deethylase (EROD) activity, fluorescent aromatic compounds (FACs) in bile and immunodetection of CYP1A-like proteins in two Australian tropical fish species, Gold-Spotted Trevally (Carangoides fulvoguttatus) and Bar-Cheeked Coral Trout (Plectropomus maculatus) to assess exposure to petroleum hydrocarbons associated with produced formation water (PFW). Additionally, the incidence of hydrocarbon-degrading bacteria isolated from the liver and bile of all fish captured was examined. Low EROD activity was found in both species, with EROD activity in C. fulvoguttatus showing significant site differences. FACs and CYP1A protein levels in C. fulvoguttatus showed a clear trend in hydrocarbon exposure consistent with hydrocarbon chemistry data: Harriet A>Harriet C>reference site. P. maculatus showed elevated levels of FACs at Harriet A as compared to the reference site and demonstrated detectable levels of CYP1A-like proteins at these two sites. Hydrocarbon-degrading bacteria were found in the liver and bile of both species, yet there was no correlation by sites. Our results demonstrate that C. fulvoguttatus and P. maculatus have potential as indicator species for assessing the effects from exposure to petroleum hydrocarbons. Both FACs and CYP1A are providing warning signs that there is potential for biological effects on fish populations exposed to PFW around the Harriet A production platform.     

An anisotropic hardening model for soils and its application to cyclic loading

An anisotropic hardening model for soils is proposed by applying the concept of a field of hardening moduli developed previously for metals. Besides the yield surface, a set of nesting surfaces in the stress-space specifies the variation of hardening moduli during the deformation process. Both drained and undrained soil behaviour can be treated and distortional as well as volumetric strain cycles can be considered. The model can be applied in studying soil behaviour under cyclic loading and in particular to describe densification or liquefaction phenomena.     

TU Ophiuchi: Mira variable — Not dwarf nova

High-speed photometry, spectroscopy, and visual observations of TU Oph show it to be a Mira variable, not a dwarf nova as originally classified or a UV Cet star as tentatively classified.     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: V. Palynological evidence for deforestation and increased erosion

Pollen spectra from seven short cores taken from deltaic sites in the central and northern parts of Lake Tanganyika provide information about vegetation changes around the lake during the last 5000 years. Pollen analysis was undertaken to understand the history and timing of catchment deforestation and its causal linkage to excess sedimentation and ecosystem change in Lake Tanganyika. The spectra are dominated by grass pollen at all levels in every core. Grass pollen percentage values range between 40 and 80%. Low values of arboreal pollen taxa (1–20%) were documented from most cores except core LT-98-2M. Core LT-98-2M represents the longest duration vegetation record of this study (close to 5000 years BP), and records the onset of increasingly arid conditions in the Late Holocene, especially after 500 A.D., with the probable replacement of forest by open grassland in the Mahale Mountains region. The pollen/spore content for other cores showed a consistent trend of a decrease in grass pollen and an increase in pteridophyte and forest indicator pollen taxa during the last few centuries, contemporaneous with other indications of increased watershed disturbance from forest clearing (especially isotopes and lake faunal change). The timing or strength of this trend is not tied to specific levels of watershed disturbance. However, increasing fern spore abundance does occur progressively later towards the south, where modern human population densities are lower. Although increasing fern spore abundance is consistent with a land-clearing hypothesis, the rising arboreal pollen percentages are seemingly counterintuitive. One possible explanation is that increasing arboreal pollen proportions reflects the recycling of abundant pollen of this type from rapidly eroding soils. Another likely explanation for this finding is that land clearing involved the replacement of miombo woodland, with its mixture of trees producing little pollen and understory grasses producing large amounts of pollen, by the present day cassava, banana, and legume agricultural systems, all of which are poor pollen producers. This shift in catchment vegetation would increase the relative contribution of Afromontane pollen transported long distances from the surrounding highland regions. This hypothesis is consistent with both the lack of correlation of palynological history with specific watershed deforestation attributes, as well as the broader historical record of human habitation in the Lake Tanganyika region. This study also highlights the need for both modern pollen transect data from the region and comparative cores from low elevation swamps or ponds (wetlands) in the region with smaller catchment areas.     

Moonquakes and lunar tectonism

With the succesful installation of a geophysical station at Hadley Rille, on July 31, 1971, on the Apollo 15 mission, and the continued operation of stations 12 and 14 approximately 1100 km SW, the Apollo program for the first time achieved a network of seismic stations on the lunar surface. A network of at least three stations is essential for the location of natural events on the Moon. Thus, the establishment of this network was one of the most important milestones in the geophysical exploration of the Moon. The major discoveries that have resulted to date from the analysis of seismic data from this network can be summarized as follows:

1. Lunar seismic signals differ greatly from typical terrestrial seismic signals. It now appears that this can be explained almost entirely by the presence of a thin dry, heterogeneous layer which blankets the Moon to a probable depth of few km with a maximum possible depth of about 20 km. Seismic waves are highly scattered in this zone. Seismic wave propagation within the lunar interior, below the scattering zone, is highly efficient. As a result, it is probable that meteoroid impact signals are being received from the entire lunar surface.
2. The Moon possesses a crust and a mantle, at least in the region of the Apollo 12 and 14 stations. The thickness of the crust is between 55 and 70 km and may consist of two layers. The contrast in elastic properties of the rocks which comprise these major structural units is at least as great as that which exists between the crust and mantle of the earth. (See Toks?zet al., p. 490, for further discussion of seismic evidence of a lunar crust.)
3. Natural lunar events detected by the Apollo seismic network are moonquakes and meteoroid impacts. The average rate of release of seismic energy from moonquakes is far below that of the Earth. Although present data do not permit a completely unambiguous interpretation, the best solution obtainable places the most active moonquake focus at a depth of 800 km; slightly deeper than any known earthquake. These moonquakes occur in monthly cycles; triggered by lunar tides. There are at least 10 zones within which the repeating moonquakes originate.
4. In addition to the repeating moonquakes, moonquake ‘swarms’ have been discovered. During periods of swarm activity, events may occur as frequently as one event every two hours over intervals lasting several days. The source of these swarms is unknown at present. The occurrence of moonquake swarms also appears to be related to lunar tides; although, it is too soon to be certain of this point.

These findings have been discussed in eight previous papers (Lathamet al., 1969, 1970, 1971) The instrument has been described by Lathamet al. (1969) and Sutton and Latham (1964). The locations of the seismic stations are shown in Figure 1.     

Boltzmann constant in the model of expansive non-decelerative universe

From the observed present parameters of the Universe and the model properties of an expansive non-decelerative universe it results that the value of Boltzmann's constant (coefficient)k does not change only before the end of radiation era, but also in the matter era; with the increase of gauge factora, it decreases as (a ^–1)^1/4.