Dichte und Lichtbrechung der Moldavite von Něchov

In this experimental work I studied the correlation of the specific gravity and index of refraction at 19 moldavites from a finding place in Nchov. This place is in the south of Bohemia, in a district of eské Budjovice (Budweis). The reason for this work was the extraordinary declaration of the correlation of the specific gravity and index of refraction at one moldavite from Nchov that is: d=2,395 and n _D =1,5033.These declarations were settled by Nováek. The results of these measurings have shown that the linear correlation of the specific gravity and index of refraction of the moldavites from other finding places are characteristic also for these ones. The definition of this correlation at 19 pieces of moldavites from Nchov shows also this linear character in the measuring of values d=2,355–2,395 and n _D =1,4870–1,4950.In this work there were settled also some other dates of unity (so-called in couple-moldavites). But we must not oversee certain vaccilations of the declaration at the moldavites from Nchov, as at those from other finding places. The secularity of these declarations about the moldavites of Nchov lies also therein, that the avarage value of the correlation of specific gravity and index of refraction of this finding place is higher than those of other places.

---

---

Herrn Dr. Walter Weiskirchner, Dozent an der Universität Tübingen, danke ich herzlich für die freundliche Durchsicht der Arbeit.     

Electron-probe check of fe-distribution in sphalerite grains of the Nagybörzsöny hydrothermal ore deposits,Hungary

Micron-scale iron-distribution patterns in sphalerite grains derived from two contrasting mineral assemblages of the Nagybörzsöny hydrothermal ore deposits (high temperature stockwork and low temperature veins), were determined with electron microprobe, pointcounter and continuous chart-recorder measurements along radial profiles. A significant oscillation of iron-content ranging from 8.1 to 18 per cent for stockwork and 4.3 to 15.8 per cent for veins took place during crystal growth. Homogeneous crystal cores are characteristic for vein-filling, while replacement occurring in deeper levels of the stockwork results in mosaic cores. Frequent oscillation of iron content is relevant to top-sections of the ore bodies, copious supply being recorded in recurring shells, whereas scanty, unilateral ones produce crescents arranged in onion-like structure.

---

Zusammenfassung Bestimmungen der Eisenverteilung wurden an Zinkblendekörnern aus zwei verschiedenen Mineralparagenesen (Hochtemperatur-Stockwerk und Gangfüllungen niederiger Bildungstemperatur) der hydrothermalen Erzlagerstätte Nagybörzsöny im Mikronbereich durch Elektronen-Mikrosonde-Messungen (Punktzählung und kontinuierliche Band-Registrierung) entlang radialer Profile vorgenommen. Bedeutende Schwankungen des Eisengehaltes (8,1–18% für das Stockwerk und 4,3–15,8% für die Gänge) wurden registriert. Homogene Kristallkerne kennzeichnen die Gangfüllungen, wogegen in tieferen Horizonten des Stockwerks Verdrängungen zur Bildung von Kristallen mit Mosaik-Kernen führen. Allgemein ist in den Gipfel-Partien der Erzkörper Fluktuation des Eisengehaltes häufig. Gleichmäßiger Nachschub während des Kristallwachstums führte zu ringförmigen Zonen gleicher Eisengehalte, spärlicher oder einseitiger dagegen zu halbmondförmigen Hüllen mit Zwiebelstruktur.

     

Kanonaite, (Mn 0.76 3+ Al0.23Fe 0.02 3+ )[6]Al[5][O¦SiO4], a new mineral isotypic with andalusite

Kanonaite forms rare porphyroblasts up to 12mm long in a gahnite— Mg-chlorite — coronadite — quartz schist occurring near Kanona, Zambia. The composition is (microprobe analysis): SiO₂ 32.2, Al₂O₃ 33.9, Mn as Mn₂O₃ 32.2, Fe₂O₃ 0.66, ZnO 0.13, MgO 0.04, BaO 0.04, TiO₂ 0.01, CaO 0.01, PbO 0.01, CuO 0.01, total 99.21, corresponding to $$\left( {{\text{Mn}}_{{\text{0}}{\text{.76}}}^{{\text{3 + }}} {\text{Al}}_{{\text{0}}{\text{.23}}} {\text{Fe}}_{{\text{0}}{\text{.015}}}^{{\text{3 + }}} } \right)_{1.005}^{\left[ 6 \right]} {\text{AL}}_{1.00}^{\left[ 5 \right]} \left[ {{\text{O}}_{{\text{1}}{\text{.00}}} |{\text{Si}}_{{\text{0}}{\text{.99}}} {\text{O}}_{{\text{4}}{\text{.00}}} } \right]$$ The mineral is greenish black, strongly pleochroic with X(∥a) yellow green, Y(∥b) bluish green, Z(∥c) deep golden yellow, biaxial positive, with 2V = 53°(3°), α = 1.702, β = 1.730, γ = 1.823. Vickers microhardness (100 gram load) ranges between 906 and 1017kp/mm². The structure is orthorhombic, isotypic with andalusite, space group Pnnm, a = 0.7953(2), b = 0.8038(2), c = 0.5619(2) nm, V = 0.3592(1) nm³, a/b = 0.9895(3), c/b = 0.6990(3), S.G.(_x) = 3.395 g/cm³, Z = 4. The strongest X-ray powder lines are (d in nm, I, hkl):0.5669, 100, 110; 0.4590, 75, 011 and 101; 0.3577, 90, 120 and 210; 0.2827, 94, 220; 0.2517, 90, 310 and 112; 0.2212, 83, 320, 122 and 212. Comparison of the intensities of 373 observed X-ray reflections with those calculated for several models of Mn³⁺-distribution indicates octahedral coordination of all or most of the manganese present. Interpretation of magnetic measurements (μ_eff = 3.15B.M. per Mn atom at 25 ° C) indirectly supports octahedral coordination of Mn³⁺. The name of the mineral is for Kanona, a town near the type locality. The name is proposed for the end member Mn^{3+ [6]}Al^[5][O¦SiO₄] and for members of the solid-solution series towards andalusite with octahedral Mn³⁺>Al. The presently described mineral may be referred to as aluminian kanonaite.     

The role of principles and methods in loess-paleosol investigations

In the process of loessification, the development of loess fabric, the role of zonal, regional and partly of local environmental factors is regarded decisive. In the loess sequences various genetic types of loess pockets and paleosols occur and reflect different climatic and paleogeographical conditions.As a consequence, even within a single profile the colour, grain size and mineral composition, CaCO₃ content, degree of weathering and fabric of loess may vary. Zonal, regional or even local variations in such loess properties may equally derive from syngenetic or postgenetic processes. For similar reasons, spatially and temporally different forms, types and subtypes of paleosol also developed.This way, loess and soil formation resulted in various spatial types in the same glacial, interstadial or interglacial phase in the various geographical zones and regions. Although there exist major loess regions where the interglacial soils (eg brown forest soils) are markedly distinct from interstadial steppe soils or from other types of humic soils, continental loess areas can also be observed where the paleosols developed under interglacial and interstadial conditions (eg steppe or forest steppe soils) cannot be referred into different genetic types. In such cases the changes in paleoenvironments are difficult and uncertain to reconstruct.The interregional correlation of paleosols is occasionally hindered by the various terminologies applied to denote them. In addition, there are uncertainties concerning the dating and identification of paleoenvironments of polygenetic soils and of soil complexes consisting of paleosol units: how many soil formation phases they represent and how long erosional gaps can be reckoned with between these phases.     

The infrared dielectric properties of maghemite, γ-Fe2O3, from reflectance measurement on pressed powders

The infrared complex permittivity functions of three varieties of maghemite, γ-Fe₂O₃, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors.     

Assessment of loess as parent material for agroecological potential

Due to its physical and chemical properties, areas with a loess mantle of proper thickness favour arable farming. Loess as a parent material promotes the formation of soils of good structure, nutrient supply and water budget. The ongoing land evaluation project places particular emphasis on the consideration of parent material in its scoring system as soil and climatic parameters are assessed in conjunction with the grain size composition of subsurface material and soil texture.A test area most suitable for the presentation of the method seems to be a sandy alluvial fan with loess mantle and this circumstance allows the contrasting of the agroecological potentials of soils developed on the two parent materials of different nature.The favourable water storage properties of loess make this deposit particularly valuable under the conditions of climatic aridification. The geographical information system applied here is capable of simulating the agroecological potential changes caused by reduced precipitation, increased evaporation and dropping groundwater levels.The research for this paper was carried out as part of the MEDALUS II (Mediterranean Desertification and Land Use) collaborative research project. MEDALUS II was funded by the EC under its Environment Progamme, contract no. EV5V 0128/0166. A grant was also provided by the OTKA (Hungarian National Science Foundation), project no 1278. The support is gratefully acknowledged.     

Andalusite in granulites of the bohemian massif

Summary In granulites of South-Bohemia not only the usually occurring Al₂SiO₅ polymorphs, kyanite and sillimanite, were found but also andalusite. Its presence indicates that the metamorphic development of these granulites is characterized by a high PT-gradient. The granulitic rocks of the Bohemian Massif can be regarded as a facies series ranging from the granulite facies through the amphibolite facies to the hornblende-hornfels facies. The lower limit of the PT-conditions of this series should be placed below the position of the triple point of Al₂SiO₅.

---

Andalusit in Granuliten der Böhmischen Masse

Zusammenfassung In den Mineralparagenesen der südböhmischen Granulite wurde neben den üblicherweise auftretenden Al₂SiO₅-Modifikationen, Disthen und Sillimanit, auch Andalusit gefunden. Seine Anwesenheit weist darauf hin, daß die metamorphe Entwicklung der erwähnten Granulite durch einen ausgeprägten PT-Gradienten gekennzeichnet wurde. Die Granulitgesteine der Böhmischen Masse kann man als eine Faziesserie ansehen, die von der Granulitfazies über die Amphibolitfazies bis in die Hornblende-Hornfelsfazies reicht. Die untere Grenze der PT-Bedingungen dieser Serie ist unter die Lage des Tripelpunktes von Al₂SiO₅ zu setzen.

---

---

With 5 Figures     

Estimation of seismic hazard parameters in TERESA test areas

A general overview of some of the problems involved in earthquake catalogue handling is given as part of the works carried out into the ESC/SC8-TERESA project related with the seismic hazard assessment in two selected test areas: Sannio-Matese in Italy and the northern Rhine region (BGN). Furthermore, the necessary input data to be used in the calculation of seismic hazard has been obtained, including earthquake source zones and their seismic hazard parameters.The importance is pointed out of detailed analysis of seismic catalogues, mainly in relation to the use of aftershock information, the historical records of the region, and the possible temporal and spatial variation of seismicity, which could have an important influence on short-term hazard assessment.     

Applicability of palaeomagnetism of pyrrhotite to ore-genetic studies

Pyrrhotite has never before been used in palaeomagnetic investigations, being highly anisotropic magnetically. The aim of this paper is to show that fine-grained pyrrhotite aggregates of hydrothermal origin can be used for palaeomagnetic purposes. This has been proved with polymetallic Turkak veins from Kutná Hora in Central Bohemia as an example. It can be assumed that other localities with occurrence of hydrothermal pyrrhotite aggregates which contain directionless, uniformly scattered pyrrhotite grains and therefore forming a magnetically isotropic medium may be suitable for palaeomagnetic studies.

---

Zusammenfassung Pyrrhotin, mit einem hohen Grad magnetischer Anisotropie, ist bisher für die paläomagnetische Datierung unbeachtet geblieben. Diese Arbeit will zeigen, daß feinkörnige Pyrrhotinaggregate hydrothermalen Ursprungs für paläomagnetische Untersuchungen geeignet sind, was am Beispiel polymetallischer Gänge von Turkak in Kutná Hora in Zentralböhmen dargestellt wird. Es ist anzunehmen, daß auch andere Vorkommen hydrothermaler Pyrrhotinaggregate in denen regelmäßig verteilte Körner richtungslos orientiert vorliegen und so ein magnetisch isotropes Medium bilden, sich für paläomagnetische Untersuchungen eignen.