某污染场地土壤苯并(a)芘含量的三维估值及不确定性分析

污染场地修复前的准确评估是开展场地修复行动的基础和前提。建立了一套评估污染场地中污染土方量的三维插值方法,采用该方法模拟了某污染场地土壤苯并(a)芘(BaP)含量的空间分布并分析其不确定性。结果表明：场地地下环境中BaP含量数据服从对数正态分布,土壤中污染严重区域分别位于研究区的西南部和北部。通过普通克里格插值得到的BaP浓度超过0.4 mg·kg^-1的污染羽体积为14134 m³,对应的累积概率为0.585。依据给定变差范围值计算,得出现有收集数据对整个场地的描述程度为65%。基于该三维插值方法能准确地反映场地污染物空间分布特征,其不确定性分析可为补充采样布点及精准评估提供参考。     

Distribution of arsenic and mercury in subtropical coastal beachrock,Gulf of Mannar,India

An assessment of coastal pollution was made on the basis of trace element concentrations (arsenic — As, mercury — Hg) in the Gulf of Mannar. The beachrock samples were collected along the coastal tracts between Rameswaram and Kanyakumari. The samples were dried and digested to determine the As and Hg using atomic absorption spectrophotometer (AAS-air-acetylene and nitrous oxide method). The As and Hg accumulation status of the beachrock was assessed using geo-accumulation index values (I _geo). The accumulation of As and Hg in the beachrock ranges from 2.75 to 20.72 μg g⁻¹ and from 0.06 to 0.31 μg g⁻¹, respectively. The As and Hg concentrations in the beachrocks are compared with crustal average values and average of other region sediments. The possible source of the contamination is from atmospheric deposition and anthropogenic activities.     

Preserved organic matter in a fossil Ocean Continent Transition in the Alps: the example of Totalp,SE Switzerland

Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C₁₇–C₃₆. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems.     

The Complete Sequence of Mitochondrial COⅡ Gene of Fenneropenaeus chinensis and Its Applicability as a Marker for Phylogenetic Analysis

The complete mitochondrial cytochrome oxidase subunit Ⅱ （COⅡ） gene of Penaeinae shrimp Fenneropenaeus chinensis was cloned and sequenced. The gene is 688 bp in length and codes for 229 amino acids. It shows 83.2%, 87.0% and 83.8% sequence similarity to Marsupenaeus Japonicus, Penaeus monodon and Farfantepenaeus notialis, respectively. The A＋T content of the whole gene and that at the third position of codons are 64.7% and 78.2%, respectively. The phylogenetic relationship between F. chinensis and three other species representing genera Farfanatepenaeus, Marsupenaeus and Penaeus was analyzed. Results showed that the genetic distances among the four taxa ranged from 0.144 0 to 0.200 5, exceeding those estimated with COⅠ and partial 16S rRNA gene sequences among Marsupenaeus, Litopenaeus and Melicertus, and being therefore larger than the value among subgenera. It has been suggested that the COⅡ gene has a faster evolutionary rate than that of the COⅠ gene and partial 16S rRNA gene and could be used for phylogenetic analysis at genus or species level. The results of the present study indicated that Farfantepenaeus, Fenneropenaeus, Marsupenaeus and Penaeus are at a higher phylogenetic level than subgenus, which supports the opinion of the elevation of phylogenetic status of the four subgenera to genus level.     

Undrained creep failure of a drainage canal slope stabilized with deep cement mixing columns

This paper presents an analysis of the slope failure of a Suvarnabhumi drainage canal during construction. The Suvarnabhumi drainage canal project includes a large drainage canal with a road on both sides. The width of the bottom of the drainage canal is 48.0 m, the depth of the drainage canal is 3.0 m, and the length of the drainage canal is 10.5 km. Because the project was constructed on very soft Bangkok clay, deep cement mixing (DCM) columns were employed to increase the stability of the excavated canal. The failure of the drainage canal slope occurred 25 days after the end of excavation. The field monitoring data show that lateral movement of the canal slope continuously increased with time, which caused failure due to the instability of the canal slope. The time-dependent deformation and undrained creep behavior of very soft clay was suspected to be the cause of the canal failure. A laboratory investigation of undrained creep behavior and a finite element analysis (FEA) using the soft soil creep (SSC) model were performed to confirm the causes of the canal failure. The results indicate that very soft clay specimens that are subjected to deviator creep stress levels of 70 and 100 % of the peak strength failed by creep rupture within 60 days and 8 min, respectively. The factor of safety for the canal slope, which was obtained from the FEA, shows significant reduction from the initial value of 1.710 to 1.045 within 24 days after the end of excavation due to the effect of undrained creep. This paper also describes a solution method that is applied to a new section of the canal. Field monitoring and an FEA of the new trial section were performed to prove the effectiveness of the solution method.     

A public Cloud-based China’s Landslide Inventory Database (CsLID): development,zone, and spatiotemporal analysis for significant historical events, 1949-2011

Landslide inventory plays an important role in recording landslide events and showing their temporal-spatial distribution. This paper describes the development, visualization, and analysis of a China's Landslide Inventory Database (CsLID) by utilizing Google’s public cloud computing platform. Firstly, CsLID (Landslide Inventory Database) compiles a total of 1221 historical landslide events spanning the years 1949-2011 from relevant data sources. Secondly, the CsLID is further broken down into six zones for characterizing landslide cause-effect, spatiotemporal distribution, fatalities, and socioeconomic impacts based on the geological environment and terrain. The results show that among all the six zones, zone V, located in Qinba and Southwest Mountainous Area is the most active landslide hotspot with the highest landslide hazard in China. Additionally, the Google public cloud computing platform enables the CsLID to be easily accessible, visually interactive, and with the capability of allowing new data input to dynamically augment the database. This work developed a cyber-landslide inventory and used it to analyze the landslide temporal-spatial distribution in China.     

An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

Study on biogenic amines in various dry salted fish consumed in China

This study was carried out to investigate the biogenic amines（BAs）, physicochemical property and microorganisms in dry salted fish, a traditional aquatic food consumed in China. Forty three samples of dry salted fish were gathered from retail and wholesale markets and manufacturers, which had been produced in various regions in China. Cadaverine（CAD） and putrescine（PUT） were quantitatively the most common biogenic amines. About 14% of the samples exceeded the histamine content standards established by the FDA and/or EU. The highest histamine content was found in Silver pomfret（Pampus argenteus）(347.79 mg kg^-1). Five of forty three samples exceeded the acceptable content of TYR(100 mg kg^-1), and 23.26% of dried-salted fish contained high contents of biogenic amines(above 600 mg kg^-1). In addition, species, regions, pickling processes and drying methods made the physicochemical property, microorganisms and biogenic amines in dry salted fish to be different to some extents. The total plate count（TPC） was much higher than that of total halophilic bacteria in all samples. The biogenic amines, physicochemical property and microbiological counts exhibited large variations among samples. Furthermore, no significant correlation between biogenic amines and physicochemical property and TPC was observed. This study indicated that dry salted fish may still present healthy risk for BAs, depending on the processing methods, storage conditions among others.     

Tide and current observations in the central Chukchi Sea during the summer of 2012

Current data from a moored Acoustic Doppler Current Profiler(ADCP) deployed at 69?30.155′N,169?00.654′W in the central Chukchi Sea during 2012 summertime is analyzed in the present paper.Characteristics of tidal and residual currents are ob-tained with Cosine-Lanczos filter and cross-spectral analyses.The main achievements are as follows:1) Along with the local inertial frequency of 12.8 h,two other peaks at ~12-h and ~10-d dominate the time series of raw velocity;2) The M_2 dominates the 6 resolved tide constituents with significant amplitude variations over depth and the ratios of current speed of this constituent to that of the total tidal current are 54% and 47% for u and v components,respectively.All the resolved tidal constituents rotate clockwise at depth with the exception of MM and O1.The constituents of M_2 and S_2 with the largest major semi-axes are similar in eccentricity and orientation at deeper levels;3) The maximum of residual currents varies in a range of 20–30 cms~(-1) over depth and the current with lower velocities flow more true north with smaller magnitudes compared to the current in surface layer.The ~10 d fluctuation of residual current is found throughout the water column and attributed to the response of current to the local wind forcing,with an approximate 1.4 d lag-time at the surface level and occurring several hours later in the lower layer;4) Mean residual currents flow toward the north with the magnitudes smaller than 7 cms~(-1) in a general agreement with previous studies,which suggests a relatively weaker but stable northward flow indeed exists in the central Chukchi Sea.