Non-food-chain transfer of sediment-associated persistent organic pollutants to a marine benthic fish

We investigated the transfer of persistent organic pollutants (POPs) from unspiked bottom sediment to a benthic marine fish, marbled sole (Pleuronectes yokohamae), via non-food-chain pathways, i.e., via sediment particles and water column. One-year-old sole were held for 28 days in an exposure tank with bottom sediment or in a control tank. o,p′-DDE and tri- to penta-chlorobiphenyls were transferred from the sediment to the fish via non-food-chain pathways, as demonstrated by concentrations in the exposed fish at 2.5-30 times the control levels. A model analysis based on first-order kinetic equations indicated that the overall rate constant of transfer of these compounds from sediment to fish was generally lower than that from food (median of ratio, 0.48). It also suggested that relatively high concentrations of the other POPs in the food and the longer times necessary for them to reach a steady state masked any transfer of them from the sediment.     

Modeling of damage,permeability changes and pressure responses during excavation of the TSX tunnel in granitic rock at URL,Canada

This paper presents numerical modeling of excavation-induced damage, permeability changes, and fluid-pressure responses during excavation of a test tunnel associated with the tunnel sealing experiment (TSX) at the Underground Research Laboratory (URL) in Canada. Four different numerical models were applied using a wide range of approaches to model damage and permeability changes in the excavation disturbed zone (EDZ) around the tunnel. Using in situ calibration of model parameters, the modeling could reproduce observed spatial distribution of damage and permeability changes around the tunnel as a combination of disturbance induced by stress redistribution around the tunnel and by the drill-and-blast operation. The modeling showed that stress-induced permeability increase above the tunnel is a result of micro and macrofracturing under high deviatoric (shear) stress, whereas permeability increase alongside the tunnel is a result of opening of existing microfractures under decreased mean stress. The remaining observed fracturing and permeability changes around the periphery of the tunnel were attributed to damage from the drill-and-blast operation. Moreover, a reasonably good agreement was achieved between simulated and observed excavation-induced pressure responses around the TSX tunnel for 1 year following its excavation. The simulations showed that these pressure responses are caused by poroelastic effects as a result of increasing or decreasing mean stress, with corresponding contraction or expansion of the pore volume. The simulation results for pressure evolution were consistent with previous studies, indicating that the observed pressure responses could be captured in a Biot model using a relatively low Biot-Willis’ coefficient, α ≈ 0.2, a porosity of n ≈ 0.007, and a relatively low permeability of k ≈ 2 × 10⁻²² m², which is consistent with the very tight, unfractured granite at the site.     

A case study on the influence of THM coupling on the near field safety of a spent fuel repository in sparsely fractured granite

In order to demonstrate the feasibility of geological disposal of spent CANDU fuel in Canada, a safety assessment was performed for a hypothetical repository in the Canadian Shield. The assessment shows that the maximum long term radionuclide release from such repository would meet international criteria for dose rate; however, uncertainties in the assumed evolution of the repository were identified. Such uncertainties could be resolved by the consideration of coupled Thermal-Hydro-Mechanical-Chemical (THMC) processes. In Task A of the DECOVALEX-THMC project, THM models were developed within the framework of the theory of poroelasticity. Such model development was performed in an iterative manner, using experimental data from laboratory and field tests. The models were used to perform near-field simulations of the evolution of the repository in order to address the above-mentioned uncertainties. This paper presents the definition and rationale of task A and the results of the simulations. From a repository safety point of view, the simulations predict that the maximum temperature would be well below the design target of 100°C; however, the stress on the container can marginally exceed the design value of 15 MPa. However, the most important finding from the simulations is that a rock damage zone could form around the emplacement borehole. Such damage zone can extend a few metres from the walls of the emplacement holes, with permeability values that are orders of magnitude higher than the initial values. The damage zone has the potential to increase the radionuclide transport flux from the geosphere; the effect of such an increase should be taken into account in the safety assessment and mitigated if necessary by the provision of sealing systems. Prepared for publication in Environmental Geology. DECOVALEX-THMC Special Issue.     

Image Stabilization System for Hinode (Solar-B) Solar Optical Telescope

The Hinode Solar Optical Telescope (SOT) is the first space-borne visible-light telescope that enables us to observe magnetic-field dynamics in the solar lower atmosphere with 0.2 – 0.3 arcsec spatial resolution under extremely stable (seeing-free) conditions. To achieve precise measurements of the polarization with diffraction-limited images, stable pointing of the telescope (<0.09 arcsec, 3σ) is required for solar images exposed on the focal plane CCD detectors. SOT has an image stabilization system that uses image displacements calculated from correlation tracking of solar granules to control a piezo-driven tip-tilt mirror. The system minimizes the motions of images for frequencies lower than 14 Hz while the satellite and telescope structural design damps microvibration in higher frequency ranges. It has been confirmed from the data taken on orbit that the remaining jitter is less than 0.03 arcsec (3σ) on the Sun. This excellent performance makes a major contribution to successful precise polarimetric measurements with 0.2 – 0.3 arcsec resolution. K. Kobayashi now at NASA/Marshall Space Flight Center, Huntsville, AL 35812, USA.     

Balloon-Borne Hard X-Ray Spectrometer Using CdTe Detectors

Spectroscopic observation of solar flares in the hard X-ray energy range, particularly the 20 ∼ 100 keV region, is an invaluable tool for investigating the flare mechanism. This paper describes the design and performance of a balloon-borne hard X-ray spectrometer using CdTe detectors developed for solar flare observation. The instrument is a small balloon payload (gondola weight 70 kg) with sixteen 10×10×0.5 mm CdTe detectors, designed for a 1-day flight at 41 km altitude. It observes in an energy range of 20−120 keV and has an energy resolution of 3 keV at 60 keV. The second flight on 24 May 2002 succeeded in observing a class M1.1 flare.     

Development of the Emulsion Chamber Detector for Space Observations

The emulsion chamber detector on board the “ShiJian-8” satellite is the first one in China designed especially for observing in space the highenergy electrons and γ-rays. In this paper, the principle of the detector design, the method of data processing and the preliminary results of observations are introduced. The design lifetime of the detector is 15 days on the orbit, and the energy range of detectable particles is 100GeV∼5TeV.     

Responses of Estuarine Bacterioplankton,Phytoplankton and Zooplankton to Dissolved Organic Carbon (DOC) and Inorganic Nutrient Additions

The response of planktonic bacteria and phytoplankton to various additions of dissolved organic carbon (DOC) as glucose, with and without inorganic nutrients (nitrogen and phosphorus), was tested in the upper to mid Hunter Estuary, Australia. In situ microcosms (1.25 L) were performed at two sites with varying salinities over three seasons. Analysis of variance showed a significant difference among control and treatments for all seasons for the bacterial, dissolved oxygen and chlorophyll a responses (P < 0.05). A significant interaction between treatment and site was found in autumn for dissolved oxygen, autumn and spring for bacterial and spring for chlorophyll a responses. At both sites for each season, and on nearly all occasions, bacterial surface area was enhanced by DOC addition as indicated by both increased bacterial abundance and dissolved oxygen utilisation. DOC in combination with inorganic nutrients sometimes further enhanced the bacterial response compared to DOC alone. Inorganic nutrients alone did not enhance growth of the heterotrophic bacterioplankton. Addition of DOC alone led to decreased chlorophyll a relative to the control, probably due to competition for limited inorganic nutrients with the bacterioplankton DOC non-limiting conditions. Results suggest that the heterotrophic community was limited by DOC at both sites and across seasons. An experiment with a larger volume (70 L), performed over a longer time, compared a control with DOC addition. Increased bacterial biomass as a result of DOC addition occurred at day 2. Chlorophyll a did not significantly differ between treatments. An increase in zooplankton density was recorded in the DOC treatment relative to the control at day 10. This study supports the contention that increased DOC delivery with river inflows through environmental flow allocations will stimulate heterotrophic bacterioplankton production in the upper Hunter Estuary.     

Dynamical structure and wind-driven upwelling in a summertime anticyclonic eddy within Funka Bay,Hokkaido, Japan

We conducted hydrographic observations in 2002 to investigate the anticyclonic eddy that emerges every summer in Funka Bay, Hokkaido, Japan, and elucidate dynamical structure and wind-driven upwelling within the eddy. The anticyclonic eddy has a vertical scale of 32 m and is characterized by a strong baroclinic flow and a sharp pycnocline with a concave isopycnal structure. The sharp pycnocline occurs below a warm and relatively low-salinity water termed summer Funka Bay water (FS), which is formed by heating from solar radiation and dilution from river discharge in summertime Funka Bay. Flow of the anticyclonic eddy rotates as a rigid body at each layer, and the horizontal scale and rotation period of the eddy in the surface layer are about 15 km and 2.2 days, respectively. The dynamical balance of the anticyclonic eddy is well explained by the gradient flow balance. The contribution of centrifugal force to the gradient flow balance is about 27%. Therefore, the effect of the nonlinear term associated with centrifugal force cannot be neglected in considering the dynamics of the anticyclonic eddy in summertime Funka Bay. In addition, upwelling of subsurface water was observed in the surface layer of the central part of the eddy. The formation mechanism of this upwelling is consistent with interaction between horizontal uniform wind and the eddy. This upwelling is driven by upward Ekman pumping velocity related to the horizontal divergence of Ekman transport. In summertime Funka Bay, there are two wind effects that affect the anticyclonic eddy: a decay effect of the upwelling of subsurface water resulting from horizontal uniform wind (mainly northwesterly wind), and a maintenance or spin-up effect of horizontal non-uniform wind (mainly southerly–southeasterly seasonal wind) with negative wind stress curl.