Abundant natural gas inclusions were found in calcite veins filled in fractures of Central Fault Belt across the centre of Ordos Basin. Time of the calcite veins and characteristics of natural gas fluid inclusion were investigated by means of dating of thermolum luminescence (TL) and analyzing stable isotope of fluid inclusion. Results show that natural gas inclusion formed at 130–140°C with salinity of 5.5 wt%–6.0 wt% NaCl. It indicates that natural gas inclusion is a kind of thermal hydrocarbon fluid formed within the basin. Method of opening inclusion by heating was used to analyze composition of fluid inclusion online, of which the maximal hydrocarbon gas content of fluid inclusion contained in veins is 2.4219 m3/t rock and the maximal C1/ΣCi ratio is 91%. Laser Raman spectroscopy (LRS) was used to analyze chemistry of individual fluid inclusion in which the maximal hydrocarbon gas content is 91.6% compared with little inorganic composition. Isotope analysis results of calcite veins show that they were deposited in fresh water, in which the δ13CPDB of calcite veins is from −5.75‰ to 15.23‰ and δ18OSMOW of calcite veins is from 21.33‰ to 21.67‰. Isotope results show that δ13C1 PDB of natural gas fluid inclusion is from −21.36‰ to −29.06‰ and δDSMOW of that is from −70.89‰ to −111.03‰. It indicates that the gas of fluid inclusion formed from coal source rocks and it is the same as that of natural gas of Mizhi gas reservoir. Results of TL dating show that time of calcite vein is (32.4±3.42)×104 a, which is thought to be formation time of gas inclusion. It indicated that natural gas inclusion contained in calcite veins recorded natural gas leakage from Mizhi gas reservoir through the Central Fault Belt due to Himalayan tectonic movement.
<正>Precambrian tectonic history of Zhejiang,Fujian,and Jiangxi provinces of south China is important for understanding the tectonic evolution of South China but its magmatic activity, petrogenesis,stratigraphic sequence of the Mamianshan Group is still strongly controversial.Here we present new sensitive high resolution ion micro-probe(SHRIMP) U-Pb zircon geochronological data for the Mamianshan Group and petrographical data to constrain the tectonic framework of the regions.Our results showed that the SHRIMP U-Pb zircon age of green schists of the Dongyan Formation is 796.5±9.3 Ma,the Daling Formation is 756.2±7.2 Ma,and mica-quartz schist of the Longbeixi Formation is 825.5±9.8 Ma.These data indicate that the Mamianshan Group was formed not in the Mesoproterozoic,but in the Neoproterozoic and its stratigraphic sequences should be composed of Longbeixi,Dongyan,and Daling Formations from the bottom to the top.Rocks from this Group, from Zhejiang,Fujian and Jiangxi provinces,constituted the upper basement of the Cathaysia Block that overlay the lower basement of the Mayuan Group.Detailed petrographic studies demonstrate that the amphibole schists of the Dongyan Formation in the Mamianshan Group were formed within an intra-arc rift setting rather than a continental rift as previously suggested.Rather,this island-arc type formation was developed by collision and/or subduction between various blocks resulting from the breakup of the supercontinent Rodinia at c.850-750 Ma.The Zhuzhou conglomerate,distributed near Dikou Town,Jian'ou City,Fujian Province and previously considered as evidence of the Mesoproterozoic Dikou movement,is shown here not to be the basal conglomerate above the angular unconformity between the upper and lower basements.Our conclusions have important implications for understanding the Precambrian tectonics of South China. 相似文献