Chemical constituents of marine medicinal mangrove plant Sonneratia caseolaris

Twenty-four compounds including eight steroids (1-8), nine triterpenoids (9-16, 24), three flavonoids (20-22), and four benzenecarboxylic derivatives (17-19, 23) were isolated and identified from stems and twigs of medicinal mangrove plant Sonneratia caseolaris. The structures of the isolated compounds were determined by extensive analysis of their spectroscopic data. Among these metabolites, compounds 1, 4-20 and 22-24 were isolated and identified for the f'urst time from S. caseolaris. In the in vitro cytotoxic assay against SMMC-7721 human hepatoma cells, compound 21 (3',4',5,7-tetrahydroxyflavone)exhibited significant activity with IC50 2.8 μg/mL, while oleanolic acid (14), 3,3'-di-O-methyl ether ellagic acid (18), and 3,3',4-O-tri-O-methyl ether ellagic acid (19) showed weak activity. None of these compounds displayed significant antibacterial activites.     

Weakening laws of slip zone soils during wetting–drying cycles based on fractal theory: a case study in the Three Gorges Reservoir (China)

Acta Geotechnica - Slip zone soils play a crucial role in the evolution of landslides. In this paper, slip zone soils of the Huangtupo Landslide in the Three Gorges Reservoir area, which is an...     

气孔玄武岩古高程计:原理、方法及应用

古高程可以重建高山地区(尤其是高原)的隆升历史,可以更好地约束造山带的地球动力学过程.气孔玄武岩古高程计是通过熔岩流顶部和底部标准气孔体积比计算出古大气压,进而计算古高程的方法.该方法的研究对象是厚度为1～5m的且具有简单侵住历史的玄武质熔岩.高原隆升之前、期间和后期喷发的熔岩均可应用该方法.尽管该方法已经趋于成熟,但是国内还没有任何报道.对其基本原理、研究方法与应用做了详细的综述,并探讨了该方法在青藏高原和中国东部高原应用的潜力.     

电感耦合等离子体发射光谱法测定硼硅酸盐玻璃中的硼等常见元素

硼硅酸盐玻璃中的硼、钙、镁、铝、铁、钛、硅等常见元素普遍采用各元素分别测定的方式进行分析,分析效率很低;而且硼的测定普遍采用容量法,当B2O3含量低于1%时,容量法测定误差较大。本文以KOH熔融的方式消解样品,采用电感耦合等离子体发射光谱法(ICP-AES)进行分析。通过实验研究了KOH用量和不同称样量对B2O3测定结果的影响。结果表明,KOH用量在3 g以上时有较好的熔样效率和熔样效果,称样量低于0.4 g对B2O3测定结果无明显影响,考虑到其他元素的测定,确定了KOH用量优选3 g,称样量优选0.1 g。在此条件下,测定B2O3等常见元素的精密度(RSD,n=6)≤2%,加标回收率在96.0%~105.6%之间,除Si O2测定误差较大外,其他元素的测定结果均令人满意。本方法确定的B2O3的定量限为0.067%,且对于B2O3最高含量达到16%的测定结果也令人满意,因此可测定B2O3含量的范围至少为0.067%~16%。当样品中的B2O3含量高于4%时,方法准确度和精密度与国家标准分析方法(容量法)相当;当B2O3含量低于1%时,方法准确度和精密度都优于容量法。与现有报道相比,本方法显著拓宽了B2O3的测定范围,并具有良好的准确度,而且在B2O3准确测定的同时,也实现了Ca、Mg、Al、Fe、Ti的定量分析和Si的半定量分析,大大提高了分析效率,可以实现硼硅酸盐玻璃中B2O3等常见元素的准确快速分析。     

海洋胶体与痕量金属的相互作用

痕量金属的胶体结合态是海洋中金属的一种相当普遍的存在形式。胶体与痕量金属之间的相互作用影响着痕量金属在海水中的形态、迁移、生物可利用性及其归宿。总结了海洋胶体态金属的存在及其显著性,概述了胶体对金属在河口混合过程中行为的影响,并简要讨论了胶体在海水中痕量金属的固液相分配中的作用。     

海洋地震资料相位控制处理——东海研究实例

为了满足定量解释的需要,地震资料处理必须是高分辨率、振幅保持和相位控制的.面向海洋地震资料的相位控制处理技术包括利用远场信号进行确定性零相位化、Q补偿、预测反褶积及剩余相位校正等.利用模拟远场信号求取确定性去气泡及零相位化算子.此文基于相位控制处理,讨论了海洋地震资料的相位和极性判别方法,探讨了大于24 ms算子长度的预测反褶积对于保持信号形状的必要性,介绍了东海三维地震资料相位控制流程.     

Paleocurrent and fabric analyses of the imbricated fluvial gravel deposits in Huangshui Valley, the northeastern Tibetan Plateau, China

Gravel deposits on fluvial terraces contain a wealth of information about the paleofluvial system. In this study, flow direction and provenance were determined by systematic counts of more than 2000 clasts of imbricated gravel deposits in the Xining Region, northeastern Tibetan Plateau, China. These gravel deposits range in age from the modern Huangshui riverbed to Miocene-aged deposits overlain by eolian sediments. Our major objectives were not only to collect first-hand field data on the fluvial gravel sediments of the Xining Region, but also to the reconstruct the evolution of the fluvial system. These data may offer valuable information about uplift of the northeastern Tibetan Plateau during the late Cenozoic era. Reconstructed flow directions of the higher and lower gravel deposits imply that the river underwent a flow reversal of approximately 130–180°. In addition, the lithological compositions in the higher gravel deposits differ significantly from the lower terraces, suggesting that the source areas changed at the same time. Eolian stratigraphy overlying the gravel deposits and paleomagnetic age determination indicate that this change occurred sometime between 1.55 Ma and 1.2 Ma. We suggest that tectonic activity could explain the dramatic changes in flow direction and lithological composition during this time period. Therefore, this study provides a new scenario of fluvial response to tectonic uplift: a reversal of flow direction. In addition, field observation and statistical analyses reveal a strong relationship between rock type, size and roundness of clasts.     

圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。     

基于载噪比及参数先验信息的抗差模型

结合GPS应用的特点,建立了一种综合载噪比(C/No)及参数先验信息的抗差模型。试验结果表明该模型具有更高的抗差性能,从而能更有效地削弱GPS观测量中各种误差的影响。     

TJ-1模拟月壤承载特性的现场试验研究

采用TJ-1模拟月壤作为试验材料,通过静力触探、静载荷试验的对比分析,探讨适合月壤承载力计算的经验公式,以期为未来载人登月时宇航员和着陆器登陆可能涉及到有关月面承载能力的问题提供必要的参考。首先,使用近255 t TJ-1模拟月壤人工制备出13 m×12 m×1.2 m试验用地基,后在试验地基均匀布置6个静力触探测点和2个静载荷试验测点进行测试。针对太沙基承载力计算半经验公式以及规范和国内外学者提出的12个适合中密实砂土静力触探承载力计算的经验公式,对试验结果进行探讨。发现直接运用太沙基提出的半经验公式计算月壤承载力结果明显偏小,而由联合试验小组提出的经验公式 能够用来近似计算月壤地基承载力。计算结果表明,该经验公式在计算承载力时能够与静载荷试验值较好的吻合。