湘西南石英脉型金矿矿物流体包裹体pH值和Eh值的估算

以湘西南石英脉型金矿床为例,研究ｐ Ｈ、Ｅｈ 估算值的结果表明利用围岩蚀变反应方程以及采用碱金属离子、卤素元素离子估算ｐＨ 值是不完善的。本文根据热力学原则（ 相平衡、电价中和） 提出了矿物流体包裹体成分体系计算ｐＨ 估算值的方法,并且讨论了测试包裹体时气体成分外逸是影响ｐＨ 和Ｅｈ 估算值的主要因素之一。     

Timing and Processes of Ore Formation in the Qingchengzi Polymetallic Orefield, Northeast China: Evidence from 40Ar/39Ar Geochronology

The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral ~(40)Ar/~(39)Ar dating and report reliable ~(40)Ar/~(39)Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.     

我国砷中毒病区的环境特征研究

我国饮水型砷中毒的流行屡见报道,台湾嘉南,新疆奎屯,内蒙古河套及山西大同等地是我国几个有代表性的病区。病区多为河湖相和滨海相沉积,粘土,粘土质淤泥和有机淤泥层发育,为富含有要质的还原环境,地下水中的含量一般为０．２－０．６ｍｇ／Ｌ。有时还有氟,腐殖酸,甲基胂酸和某些烷烃类等的有害有机化合物。     

1980～～2014年中国中东部持续性霾天气的多尺度变化特征

对1980～2014年中国中东部地区324个台站的持续性霾天气的时空变化和相关气象影响因子进行分析，结果表明:中东部地区年平均持续性霾事件和其在所有霾事件的贡献比例逐年增加，增长率分别为0.79 (10 a)-1和2.7% (10 a)-1。主要表现为3个大值区:华北平原地区（包括山西省、京津冀地区）、长江三角洲和四川盆地东部，增加最显著的区域位于黄淮地区，增长率分别为6.3 (10 a)-1、13.95 d (10 a)-1。1月是持续性霾事件的高发月，月均2.56 d。夏季和秋季持续性霾事件增加最为明显，增长率分别为0.38 (10 a)-1和0.46 (10 a)-1。不利的气象条件，如静风日数的增加，风速和大风日数的减少，以及不利的环流形势，如东亚冬季风的减弱，都可能造成持续性霾天气的增加和异常维持。     

Solar flare injection and propagation of low-energy protons and electrons in the event of 7–9 July, 1966

Simultaneous observations of the 7–9 July 1966 solar particle event by energetic particle detectors on three satellites, IMP-III, OGO-III and Explorer 33 are utilized to show that large spatial gradients are present in the fluxes of 0.5–20 meV protons and 45 keV electrons. The event is divided into three parts: the ordinary diffusive component, the halo, and the core. The core corotates with the interplanetary field, and therefore it and the surrounding halo are interpreted as spatial features which are connected by the interplanetary magnetic field lines to the vicinity of the flare region. Upper limits to the interplanetary transverse diffusion coefficient for 4–20 meV protons at 1 AU are derived from the width of the halo. These are at least two orders of magnitude less than the parallel diffusion coefficient for the same energy particles.It is argued that the observed flux variations cannot be explained by an impulsive point source injection for any physically reasonable diffusion model. Instead, since the interplanetary transverse-diffusion coefficient is small for these low-energy particles, the observed spatial features are interpreted as the projection to 1 AU by the interplanetary field lines of an extensive injection profile at the sun. The geometry of the injection mechanism is discussed and it is suggested that some temporary storage of the flare particles occurs near the sun.Now at NASA, Goddard Space Flight Center, Greenbelt, Md., U.S.A.     

Cosmic-ray exposure histories of two Antarctic meteorites from Chinese collections and the Guangmingshan and Zhuanghe chondrites

In this paper, we report cosmic-ray exposure ages (3He, 21Ne, 38Ar) and gas retention ages (4He, 40Ar) of two Antarctic meteorites, and the Guangmingshan and Zhuanghe ordinary chondrites. The Antarctic meteorites (GRV98002 and GRV98004) were collected on …     

Evaluation of aluminum speciation in surface waters in China and its environmental risk assessment

As the ongoing global research on acid precipitation is developing in depth, more and more attention has been paid to the ecological effects of aluminum (Al) due to its toxicity to plants and animals, which is caused by acid precipitation. As a very serious problem of terrestrial and aquatic environmental acidification occurs in China, especially in southwestern China, a systematic investigation of Al speciation in these regions is very important. In this paper, the Al speciation results of surface waters in China are reported and its ecological impacts is evaluated. More than 100 water samples were collected from about twenty provinces of China. Driscoll's Al speciation scheme combined with the modified MINQEL computer model is used for speciation of Al. This study shows that the ecological impacts of acidification are quite different between China and Western countries, because of different geographical environments and geological settings. In Western countries, acidification is mainly caused by NO₂^-. Due to low concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺, the buffer capacities of soil and water are weak. Therefore, natural waters can be acidified to pH<5 very easily, resulting in a considerable mobilization of Al and worsening of the ecological environment. In China, acid precipitation is mainly in the form of sulfuric acid. In northwestern China, concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ are high in soil and surface waters. This leads to much higher capacity and a high resistance ability to acidification. The pH values of waters in this region are high (around 7) and no serious Al toxicity is found at present. However, in northeastern and southeastern China, the soil is rich in Al (unsaturated aluminosilicates in northeastern China, saturated aluminosilicates in north and central China, aluminum-rich soil in southeastern and southwestern China). The concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ in soil and waters are lower than those of northwestern China. Therefore the buffer capacity is limited. Numerous surface waters have already been acidified and pH values declined to 5. The impacts of Al toxicity on ecological systems in these regions are very serious, especially in Jiangxi, Hubei Provinces and Chongqing Municipality.     

佛坪自然保护区植物群落物种多样性与海拔梯度的关系

用多元统计分析方法研究了佛坪自然保护区植物群落多种性及群落各生长型多样性特征沿海拔梯度的变化。结果表明：1）植物群落的Shannon指数与Simpson指数及物种丰富度与海拔梯度均呈显著负相关关系;2）乔木层的物种多样性沿海拔梯度的变化则体现了“中国高度膨胀”的规律,即中等海拔高度上多样性高而低海拔和高海拔多样性较低;3）灌木层丰富度指数在1600-1700m之间有个很不明显的峰值,而其它4个指标沿海拔呈单调的下降趋势;4）草本层植物多样性呈先降后升的趋势,在中等海拔高度较低。     

"96.1"高原暴雪过程三维条件性对称不稳定的数值研究

利用“96．1”青藏高原东北部暴雪过程的较成功的中尺度模拟的输出资料,用非纬向非平行基流中的对称不稳定模式,对“96．1”暴雪发生发展过程的动力学机制进行了三维基流中二维非线性对称不稳定数值模拟试验。结果表明,ψ场和ω场的三维配置与切变线的演变过程相当一致,说明用三维基流中二维非线性对称不稳定可能能较好地描述SI在切变线东伸南移过程中所起的作用。     

上海热浪与健康监测预警系统

用1989～1998年上海逐日4次气象观测资料,应用美国特拉华大学的SSC天气分类方法确定逐日天气类型,形成了10年逐日天气类型日历。并通过天气类型与死亡率的对比分析,确定MT+类型是上海地区形成热浪的“侵人型”气团,是具有最高死亡率的天气类型。采用逐步回归方法建立了MT+类型下因受热浪侵袭而超正常死亡数的回归方程。在此基础上建立了上海热浪与健康监测预警系统。通过1999年气象和死亡实况资料检验,系统对热浪及因此引起的死亡具有较好的监测和预警效果。