Incorporation,distribution and fate of saturated petroleum hydrocarbons in sediments from a controlled marine ecosystem

A simulation of a chronic input of petroleum into an estuarine environment was investigated using the facilities at the Marine Ecosystems Research Laboratory at the University of Rhode Island. An oil-water dispersion of No. 2 fuel oil was added to the system (twice weekly for 24 weeks) and the saturated hydrocarbons from this oil were measured in suspended material and sediments. After the initial chronic oil addition, trace amounts of hydrocarbons were detected in the sediments within two weeks, but substantial accumulation was not detected for approximately 135 days. The oil appeared to enter the sediment via the suspended material, with most of the saturated hydrocarbons associated with smaller size sediment particles (< 45 μm to > 0·3 μm). With time, the fuel oil saturated hydrocarbons in the sediments were mixed to a depth of 3 to 4 cm. Although only 12% of the total saturated hydrocarbons added to the system were found in the sediments, these hydrocarbons appear to be relatively stable and were still detectable in these sediments for at least six months after the last oil addition.     

Chasing a 'loose and baggy monster': almshouses and the geography of charity

This paper goes some way towards redressing the lack of geographical literature on charity through exploring the geography of the British domestic charitable sector. The size and geography of the third sector is outlined, followed by an analysis of how almshouses can be understood as inherently geographical and deeply embedded in local social networks of inclusion as well as exclusion.     

Relationship between the seismicity and geologic structure of the Blanco Transform Fault Zone

Morphologic studies of an oceanic transform, the Blanco Transform Fault Zone (BTFZ), have shown it to consist of a series of extensional basins that offset the major strike-slip faults. The largest of the extensional basins, the Cascadia Depression, effectively divides the transform into a northwest segment, composed of several relatively short strike-slip faults, and a southeast segment dominated by fewer, longer faults. The regional seismicity distribution (m _b 4.0) and frequency-magnitude relationships (b-values) of the BTFZ show that the largest magnitude events are located on the southeast segment. Furthermore, estimates of the cumulative seismic moment release and seismic moment release rate along the southeast segment are significantly greater than that of the northwest segment. These observations suggest that slip along the southeast segment is accommodated by a greater number of large magnitude earthquakes. Comparison of the seismic moment rate, derived from empirical estimates, with the seismic moment rate determined from plate motion constraints suggests a difference in the seismic coupling strength between the segments. This difference in coupling may partially explain the disparity in earthquake size distribution. However, the results appear to confirm the relation between earthquake size and fault length, observed along continental strike-slip faults, for this oceanic transform.     

Descriptive Analysis and Classification of Benthic Communities in Some Mediterranean Coastal Lagoons (Central Italy)

Abstract. Benthic samples were taken seasonally at 32 stations in five coastal lagoons of Central Italy (Fogliano, Monaci, Caprolace, Fondi, and Lungo) during a two-year period (1982–1984). Composition and distribution of benthic populations in each lagoon as well as seasonal trends of species richness, density, diversity, and redundancy are presented and discussed.
The faunal differentiation appeared to be mainly due to the different degree of water exchange, both with marine and continental systems.     

Recent and Late Holocene environments on the southeastern shelf of the Laptev Sea as inferred from microfossil data

The study of diatoms and benthic foraminifers from the southeastern shelf of the Laptev Sea shows that their most diverse and abundant recent assemblages populate the peripheral underwater part of the Lena River delta representing the marginal filter of the sea. This area is characterized by an intense interaction between the fresh waters of the Siberian rivers and the basin seawater, the Atlantic one included. Local Late Holocene (～last 2300 years) environments reflect the main regional and global paleoclimatic changes, the Medieval Warm Period (～600–1100 years B.P.) and the Little Ice Age (～100–600 years B.P.) inclusive. In addition, the composition and distribution of planktonic foraminifers implies a strong influence of the Atlantic water during the Holocene optimum ～5100–6200 years B.P.     

The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules

A study of the oxidation states of metals in selected Pacific ferromanganese nodules by x-ray photoelectron spectroscopy (XPS) indicates the presence of Co(III), Pb(II), Pb(IV), Fe(III) and Ti(IV). These findings are based on measurements of core electron binding energies and an evaluation of the core electron shake-up satellite features.     

Sub-surface dynamics and eruptive styles of maars in the Colli Albani Volcanic District, Central Italy

Eruptive scenarios associated with the possible reactivation of maar-forming events in the Quaternary, ultrapotassic Colli Albani Volcanic District (CAVD) provides implications for volcanic hazard assessment in the densely populated area near Rome. Based on detailed stratigraphy, grain size, componentry, ash morphoscopy and petro-chemical analyses of maar eruption products, along with textural analysis of cored juvenile clasts, we attempt to reconstruct the eruptive dynamics of the Prata Porci and Albano maars, as related to pre- and syn-eruptive interactions between trachybasaltic to K-foiditic feeder magmas and carbonate–silicoclastic and subvolcanic country rocks. Magma volumes in the order of 0.5–3.1 × 10⁸ m³ were erupted during the monogenetic Prata Porci maar activity and the three eruptive cycles of the Albano multiple maar, originating loose to strongly lithified, wet and dry pyroclastic surge deposits, Strombolian scoria fall horizons and lithic-rich explosion breccias. These deposits contain a wide range of accessory and accidental lithic clasts, with significant vertical stratigraphic variations in the lithic types and abundances. The two maar study cases hold a record of repeated transitions between magmatic (i.e, Strombolian fallout) and hydromagmatic (wet and dry pyroclastic surges) activity styles. Evidence of phreatic explosions, a common precursor of explosive volcanic activity, is only found at the base of the Prata Porci eruptive succession. The quantitative evaluation of the proportions of the different eruptive styles in the stratigraphic record of the two maars, based on magma vs. lithic volume estimates, reveals a prevailing magmatic character in terms of erupted magma volumes despite the hydromagmatic footprint. Different degrees of explosive magma–water interaction were apparently controlled by the different hydrogeological and geological–structural settings. In the Prata Porci case, shifts in the depth of magma fragmentation are proposed to have accompanied eruption style changes. In the Albano case, a deeply dissected geothermal aquifer in peri-caldera setting and variable mass eruption rates were the main controlling factors of repeated shifts in the eruptive style. Finally, textural evidence from cored juvenile clasts and analytical modeling of melt–solid heat transfer indicate that the interacting substrate in the Prata Porci case was at low, uniform temperature (~ 100 °C) as compared to the highly variable temperatures (up to 700–800 °C) inferred for the geothermal system beneath Albano.