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91.
M. Narayanasamy D. Dhanasekaran G. Vinothini N. Thajuddin 《International Journal of Environmental Science and Technology》2018,15(1):119-132
Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes. 相似文献
92.
An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions. 相似文献
93.
The sodian stellerite (a zeolite) occurs as lustrous white or slightly pink, easily cleavable lamellae, filling cavities and fractures in an acid lava (andesite or rhyolite) in the cliff below S. Efisio Tower, near Capo Pula, Cagliari, Sardegna, Italy. The principal forms present are {010}, {011}, {111}. Single crystal photographs show an orthorhombic symmetry and Ammm (or Ammm) space group. An indexed X-ray diffraction powder pattern is provided. Unit cell dimensions, chemical formula, density, optical properties and thermal behaviour are given. 相似文献
94.
Investigations in a newly constructed subsea road tunnel in the Iddefjord granite at Hvaler and test-pumping of boreholes on land indicate that a topographic or geophysical anomaly is no guarantee of a substantially transmissive fracture zone. Many prominent fracture zones appear to have depressed transmissivity due to secondary swelling-clay mineral infillings. No current geophysical technique can adequately distinguish these zones from transmissive ones. Given that siting of boreholes on the basis of geology alone can be unreliable, hydrogeologists should concentrate on quantifying the chances of a successful boring, and optimizing those chances by sensible location, favourable borehole orientation and use of artificial enhancement techniques. 相似文献
95.
A Model of Magmatic Crystallization 总被引:2,自引:0,他引:2
A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined mineralsmagnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions. 相似文献
96.
Use of Rhodamine water tracer in the marshland upwelling system 总被引:1,自引:0,他引:1
Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS. 相似文献
97.
D. H. W. Hutton 《Geological Journal》1979,14(1):171-178
The structural relationships of several intrusive sheets belonging to the extensive metadolerite suite of the Appin (lower) Dalradian rocks of the Creeslough area, northwest Donegal, Ireland have been examined. It is concluded that, relative to the regional chronology of deformation of the enclosing metasediments, sheet emplacement has occurred: pre-D2; syn-D2; between D2 and D3; and syn-D3. The height of activity came in the post-D2, pre-D3 interval and coincided with the peak of regional metamorphism in the area. These relationships in Donegal are compared with those of the pretectonic basic rocks of the southwest Highlands and models are discussed. 相似文献
98.
—The paper presents results of experiments designed to measure the actual dynamic magnification of the Wiechert 1000 kg horizontal seismometer when excited by seismic waves. This is accomplished by comparing 51 digital records of seismic events recorded by the Wiechert and a well calibrated reference seismometer. The results obtained indicate that the magnification of the Wiechert seismometer is influenced by the interaction of its mass and frame, especially for high frequencies. This interaction has been modeled by considering a system of two coupled pendulums, yielding a theoretical dynamic magnification curve which exhibits main features of the observed magnification. The dis crepancy between the nominal and the actual response of the Wiechert seismograph may lead to errors in studies involving spectral analyses of recorded seismograms, and to overestimation of local earth quake magnitudes. 相似文献
99.
D. E. Roberts 《Geological Journal》1983,18(1):43-52
A section of hornfelsed Skiddaw Slate adjacent to the margin of the Grainsgill Greisen is described and chemical analyses of the various rock types presented. The results confirm that hydrothermal fluids liberated K and Na from the granite to produce the greisen. This gave rise to K metasomatism of the adjacent hornfels and to retrogressive metamorphism over a radius of 200m from the intrusion. Na leached from the hornfels near the intrusion and that liberated during the formation of the greisen are probably the sources of the Na in the brines recorded in fluid inclusions within the nearby quartz-tungsten veins. 相似文献
100.
The seismic ground motion of a test area in the eastern district of Naples is computed with a hybrid technique based on the mode summation and the finite difference methods. This technique allows us the realistic modelling of source and propagation effects, including local soil conditions. In the modelling, we consider the 1980 Irpinia earthquake, a good example of strong shaking for the area of Naples, which is located about 90 km from the epicenter.The detailed geological setting is reconstructed from a large number of drillings. The sub-soil is mainly formed by alluvial (ash, stratified sand and peat) and pyroclastic materials overlying a pyroclastic rock (yellow neapolitan tuff), representing the neapolitan bedrock. The detailed information available on mechanical properties of the sub-soil and its geometry warrants the application of the sophisticated hybrid technique.As expected, the sedimentary cover causes an increase of the signal's amplitudes and duration. If thin peat layers are present, the amplification effects are reduced, and the peak ground accelerations are similar to those observed for the bedrock model. This can be explained by the backscattering of wave energy at such layers, that tend to seismically decouple the upper from the lower part of the structure.For SH-waves, the influence of the variations of the S-wave velocities on the spectral amplification is studied, by considering locally measured velocities and values determined from near-by down-hole measurements. The comparison between the computed spectral amplifications confirms the key role of an accurate determination of the seismic velocities of the different layers.The comparison performed between a realistic 2-D seismic response and a standard 1-D response, based on the vertical propagation of waves in a plane layered structure, shows considerable difference, from which it is evident that serious caution must be taken in the modelling of expected ground motion at a specific site. 相似文献