Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Sodian stellerite from Capo Pula,Sardegna

The sodian stellerite (a zeolite) occurs as lustrous white or slightly pink, easily cleavable lamellae, filling cavities and fractures in an acid lava (andesite or rhyolite) in the cliff below S. Efisio Tower, near Capo Pula, Cagliari, Sardegna, Italy. The principal forms present are {010}, {011}, {111}. Single crystal photographs show an orthorhombic symmetry and Ammm (or Ammm) space group. An indexed X-ray diffraction powder pattern is provided. Unit cell dimensions, chemical formula, density, optical properties and thermal behaviour are given.     

Groundwater Resources In Hard Rock; Experiences from The Hvaler Study,Southeastern Norway

Investigations in a newly constructed subsea road tunnel in the Iddefjord granite at Hvaler and test-pumping of boreholes on land indicate that a topographic or geophysical anomaly is no guarantee of a substantially transmissive fracture zone. Many prominent fracture zones appear to have depressed transmissivity due to secondary swelling-clay mineral infillings. No current geophysical technique can adequately distinguish these zones from transmissive ones. Given that siting of boreholes on the basis of geology alone can be unreliable, hydrogeologists should concentrate on quantifying the chances of a successful boring, and optimizing those chances by sensible location, favourable borehole orientation and use of artificial enhancement techniques.     

A Model of Magmatic Crystallization

A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined minerals—magnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions.     

Polarized Radiation in Relativistic Cosmology

A method to solve the general-relativistic equation of radiative transfer for polarized light incorporating elastic COMPTON scattering is discussed. The method is based on an expansion in spin-o and spin-2 spherical harmonics.     

Metadolerite age relationships in the Dalradian of northwest Donegal,Ireland and their orogenic significance

The structural relationships of several intrusive sheets belonging to the extensive metadolerite suite of the Appin (lower) Dalradian rocks of the Creeslough area, northwest Donegal, Ireland have been examined. It is concluded that, relative to the regional chronology of deformation of the enclosing metasediments, sheet emplacement has occurred: pre-D2; syn-D2; between D2 and D3; and syn-D3. The height of activity came in the post-D2, pre-D3 interval and coincided with the peak of regional metamorphism in the area. These relationships in Donegal are compared with those of the pretectonic basic rocks of the southwest Highlands and models are discussed.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...