Crystal fractionation and partial melting in the petrogenesis of a Proterozoic high-MgO volcanic suite,Ungava, Québec

There is little concensus on the relative importance of crystal fractionation and differential partial melting to the chemical diversity observed within most types of volcanic suites. A resolution to this controversy is best sought in suites containing high MgO lavas such as the Chukotat volcanics of the Proterozoic Cape Smith foldbelt, Ungava, Quebec. The succession of this volcanic suite consists of repetitive sequences, each beginning with olivine-phyric basalt (19-12 wt% MgO), grading upwards to pyroxene-phyric basalt (12-8 wt% MgO) and then, in later sequences, to plagioclase-phyric basalt (7-4 wt% MgO). Only the olivine-phyric basalts have compositions capable of equilibrating with the upper mantle and are believed to represent parental magmas for the suite. The pyroxene-phyric and plagioclase-phyric basalts represent magmas derived from these parents by the crystal fractionation of olivine, with minor chromite, clinopyroxene and plagioclase. The order of extrusion in each volcanic sequence is interpreted to reflect a density effect in which successively lighter, more evolved magmas are erupted as hydrostatic pressure wanes. The pyroxene-phyric basalts appear to have evolved at high levels in the active part of the conduit system as the eruption of their parents was in progress. The plagioclase-phyric basalts may represent residual liquids expelled from isolated reservoirs along the crust-mantle interface during the late stages of volcanic activity.A positive correlation between FeO and MgO in the early, most basic olivine-phyric basalts is interpreted to reflect progressive adiabatic partial melting in the upper mantle. Although this complicates the chemistry, it is not a significant factor in the compositional diversification of the volcanic suite. The preservation of such compositional melting effects, however, suggests that the most basic olivine-phyric basalts represent primitive magmas. The trace element characteristics of these magmas, and their derivatives, indicate that the mantle source for the Chukotat volcanics had experienced a previous melting event.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Estimation of the effect of protective piers on wind wave parameters in the Sevastopol Bay

An effectiveness of the storm wave attenuation by protective piers in the Sevastopol Bay of the Black Sea is studied on the basis of numerical simulation using the SWAN spectral model. Analyzed are the parameters of waves generated by winds of four main directions as well as by the southern cyclone during the storm on November 11, 2007. It is obtained that waves from the northwest part of the Black Sea penetrate most intensively into the Sevastopol Bay in case of western wind and, to a lesser degree, in case of northern and southern winds. A protective effect of the piers is observed in the west part of the bay only and the wave attenuation near the southern coast is more significant than near the northern one. The area of the southern coast directly behind the southern pier is completely protected from the storm waves and, as moving away from the pier, the danger of intensive wave effect on the coast is kept.     

Origin of a unique impact-melt rock—the L-chondrite Ramsdorf

Abstract— We have studied a unique impact-melt rock, the Ramsdorf L chondrite, using optical and scanning microscopy and electron microprobe analysis. Ramsdorf contains not only clast-poor impact melt (Begemann and Wlotzka, 1969) but also a chondritic portion (>60 g) with what appears at low magnification to be a normal, well-defined chondritic texture. However, detailed studies at high magnification show that >90 vol% of the crystals in the chondritic portion were largely melted by the impact: the chondrules lack normal microtextures and are ghosts of the original features. The only relics from the precursor chondrules are olivine crystals, which have the highest melting temperature (～1620 °C). Pyroxene-rich chondrules were so extensively melted that no phenocrysts were preserved and the melt crystallized in situ before significant mixing with exterior olivine-rich melts. Fine-grained pyroxene chondrule ghosts have sharper boundaries with the matrix than porphyritic olivine and pyroxene chondrule ghosts, probably because pyroxene-rich melts are significantly more viscous. Complex textures that formed by injection of melt along cracks and fractures in relic olivines suggest that the chondritic portion of Ramsdorf formed directly from petrologic type 3–4 material by strong shock. We infer that Ramsdorf was largely melted by shock pressures of ～75–90 GPa and that chondrule ghosts and relic olivine phenocrysts were locally preserved by rapid cooling. Quenching was not due to the addition of cold clasts into the melt but to heterogeneous shock heating that only caused internal melting of large olivines and pyroxenes. Ramsdorf appears to be one of the most heavily shocked meteorites that has retained some trace of its original texture.     

Modelling of local velocity anomalies: a cookbook

The determination of small-scale velocity anomalies (from tens to a few hundreds of metres) is a major problem in seismic exploration. The impact of such anomalies on a structural interpretation can be dramatic and conventional techniques such as tomographic inversion or migration velocity analysis are powerless to resolve the ambiguity between structural and velocity origins of anomalies. We propose an alternative approach based on stochastic modelling of numerous anomalies until a set of models is found which can explain the real data. This technique attempts to include as much a priori geological information as possible. It aims at providing the interpreter with a set of velocity anomalies which could possibly be responsible for the structural response. The interpreter can then choose one or several preferred models and pursue a more sophisticated analysis. The class of retained models are all equivalent in terms of data and therefore represent the uncertainty in the model space. The procedure emulates the real processing sequence using a simplified scheme. Essentially, the technique consists of five steps: 1 Interpretation of a structural anomaly in terms of a velocity anomaly with its possible variations in terms of position, size and amplitude. 2 Drawing a model by choosing the parameters of the anomaly within the acceptable range. 3 Modelling the traveltimes in this model and producing the imaging of the reflected interface. 4 Comparing the synthetic data with the real data and keeping the model if it lies within the data uncertainty range. 5 Iterate from step 2. In order to avoid the high computational cost inherent in using statistical determinations, simplistic assumptions have been made: ? The anomaly is embedded in a homogeneous medium: we assume that the refraction and the time shift due to the anomaly have a first-order effect compared with ray bending in the intermediate layers. ? We model only the zero-offset rays and therefore we restrict ourselves to structural problems. ? We simulate time migration and so address only models of limited structural complexity. These approximations are justified in a synthetic model which includes strong lateral velocity variations, by comparing the result of a full processing sequence (prestack modelling, stack and depth migration) with the simplified processing. This model is then used in a blind test on the inversion scheme.     

Response of a porous seabed around breakwater heads

The evaluation of wave-induced pore pressures and effective stresses in a porous seabed near a breakwater head is important for coastal engineers involved in the design of marine structures. Most previous studies have been limited to two-dimensional (2D) or three-dimensional (3D) cases in front of a breakwater. In this study, we focus on the problem near breakwater heads that consists of incident, reflected and diffracted waves. Both wave-induced oscillatory and residual liquefactions will be considered in our new models. The mistake in the previous work [Jeng, D.-S., 1996. Wave-induced liquefaction potential at the tip of a breakwater. Applied Ocean Research 18(5), 229–241] for oscillatory mechanism is corrected, while a new 3D boundary value problem describing residual mechanism is established. A parametric study is conducted to investigate the influences of several wave and soil parameters on wave-induced oscillatory and residual liquefactions around breakwater heads.     

Formation of copper—iron sulfide minerals during corrosion of artifacts and possible implications for pseudogilding

Adherent films of the gold-colored metal sulfides pyrite (FeS₂), pyrrhotite (Fe_1−xS), and chalcopyrite (CuFeS₂) are known to exist on metallic and nonmetallic artifacts of Classic times. Consideration of the action of bacterial consortia containing sulfate reducing bacteria (SRB) during microbiologically influenced corrosion (MIC) and analyses of appropriate trajectories on Eh-pH stability diagrams indicate that these films can be understood either as a result of natural processes over archaeological times or of deliberate pseudogilding. Methods of discriminating natural sulfide deposition from pseudogilding are suggested. © 1993 John Wiley & Sons, Inc.     

Coupled changes in sand grain size and sand transport driven by changes in the upstream supply of sand in the Colorado River: Relative importance of changes in bed-sand grain size and bed-sand area

Sand transport in the Colorado River in Marble and Grand canyons was naturally limited by the upstream supply of sand. Prior to the 1963 closure of Glen Canyon Dam, the river exhibited the following four effects of sand supply limitation: (1) hysteresis in sediment concentration, (2) hysteresis in sediment grain size coupled to the hysteresis in sediment concentration, (3) production of inversely graded flood deposits, and (4) development or modification of a lag between the time of a flood peak and the time of either maximum or minimum (depending on reach geometry) bed elevation. Construction and operation of the dam has enhanced the degree to which the first two of these four effects are evident, and has not affected the degree to which the last two effects of sand supply limitation are evident in the Colorado River in Marble and Grand canyons. The first three of the effects involve coupled changes in suspended-sand concentration and grain size that are controlled by changes in the upstream supply of sand. During tributary floods, sand on the bed of the Colorado River fines; this causes the suspended sand to fine and the suspended-sand concentration to increase, even when the discharge of water remains constant. Subsequently, the bed is winnowed of finer sand, the suspended sand coarsens, and the suspended-sand concentration decreases independently of discharge. Also associated with these changes in sand supply are changes in the fraction of the bed that is covered by sand. Thus, suspended-sand concentration in the Colorado River is likely regulated by both changes in the bed-sand grain size and changes in the bed-sand area. A physically based flow and suspended-sediment transport model is developed, tested, and applied to data from the Colorado River to evaluate the relative importance of changes in the bed-sand grain size and changes in the bed-sand area in regulating suspended-sand concentration. Although the model was developed using approximations for steady, uniform flow, and other simplifications that are not met in the Colorado River, the results nevertheless support the idea that changes in bed-sand grain size are much more important than changes in bed-sand area in regulating the concentration of suspended sand.     

Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.