Rational approach to the bottom shear stress in tidal planetary boundary layer flow

The friction velocity associated with the maximum bottom shear stress in neutrally stable tidal planetary boundary layer flow is presented. The directions of the bottom shear stresses for the anticlockwise and clockwise rotating components are also presented. The results are obtained by using similarity theory and are given for flow conditions in the rough, smooth and transitional smooth-to-rough turbulent regime. An approximation for the maximum bottom shear stress by disregarding the rotation of the velocity in the boundary layer as the seabed is approached is also presented.     

The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

The behaviour of a Cu(II) ion selective electrode in seawater; copper consumption capacity and copper determinations

Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater.     

Sedimentogenesis in the White Sea: Vertical Fluxes of Suspended Particulate Matter and Absolute Masses of Bottom Sediments

Oceanology - A new approach has been applied to studying marine sedimentation using dispersed sedimentary material in sediment traps compared to the surface layer of bottom sediments. Based on...     

Antarctic Bottom Water Flow through the Eastern Part of the Philip Passage in the Weddell Sea

Oceanology - Measurements of currents and Antarctic Bottom Water properties overflowing the sill from the Weddell to the Scotia Sea are described. The bottom water overflows the sill of one of the...     

Mesoscale Variability of the Ocean in the Northern Part of the Weddell Sea

Oceanology - Results of a mesoscale survey in the Powell Basin in the northern part of the Weddell Sea are analyzed. The survey included 24 CTD casts (6 × 4) with an interval of six nautical...     

Automatic Profiling System for Underice Measurements

The article is devoted to the development of an autonomous profiling system for measuring the aquatic environment under ice. The system moves up and down in the water column along a cable with a load at the lower end, which is lowered into a lane in the ice. The system carrier is designed for transporting an acoustic Doppler current profiler and a salinity, temperature, and pressure probe. The system will be useful for long-term measurements of vertical profiles of the current speed and marine environment parameters, as well as ice draft. The article describes in detail the structure and operation of the system. The hydraulic scheme of the carrier buoyancy system is presented.