Correlation of trace elements with hydrocarbon microseepage

Direct correlation have been observed between certain trace element and hydrocarbon anomalies in the near subsurface soils of Vindhyan basin, India. This relationship with hydrocarbon is very useful in hydrocarbon exploration. 52 soil samples from Vindhyan basin were collected from a depth of 2.5m. All the soil samples were analyzed for light hydrocarbon, isotope and trace element concentrations. The adsorbed light gaseous hydrocarbon analyses show the presence of methane (8–328 ppb), ethane (0–27 ppb) and propane (0–11 ppb) respectively and these values indicate the presence of hydrocarbon micro-seepage in the study area. The carbon isotopic values determined for methane and ethane for these soil samples are (?26.41 to ?47.70 ‰ PDB) and (?20.07 to ?35.30 ‰ PDB) respectively and they are thermogenic in nature. The trace element concentrations of nickel (33–220 ppm), vanadium (72–226 ppm), copper (20–131 ppm), chromium (94–205 ppm), zinc (66–561 ppm) and cobalt (9–39 ppm) have higher than the normal concentrations in soils. Trace element concentrations are used to plot with the data obtained from light gaseous hydrocarbon concentrations and carbon isotopic values of soil samples of the Vindhyan basin. Trace element anomalies have been observed around the hydrocarbon anomalies in the study area.     

Old, Low-Mass, Metal-Rich (SMR) Stars

The authors of this paper try to disentangle the many problems arisen from a new enlarged sample of nearby low-mass,metal-rich-stars. These stars have reliable absolute magnitudes, deduced from Hipparcos parallaxes, precise bolometric corrections, effective temperatures and metal abundances from high resolution detailed spectroscopic analyses. Their ages have been derived from a grid of isochrones calculated with up to date physics. The main goal of this paper is to determine the ages of the slightly evolved SMR stars. Among those with well determinated ages about 80% of them have intermediate ages of (2 to 5 Gyr), but only 20% have ages of 8 Gyr or more. Nevertheless, the existence of very old metal-rich stars is confirmed. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Holocene record of climate change,fire ecology and human activity from montane Flat Top Bog,Maui

A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology     

Strontium and oxygen isotope evidence relating to the petrogenesis of the Kangerdlugssuaq alkaline instrusion,East Greenland

The Kangerdlugssuaq intrusion, East Greenland, consists of quartzsyenites, syenites, pulaskites and foyaites. The age and petrogenesis of the intrusion has been investigated by strontium and oxygen isotope analyses of the major rock types (and some separated minerals) and the surrounding country rocks. Crystallization and rapid cooling of the intrusion close to 50 m.y. ago is indicated by concordance of an Rb-Sr mineral isochron (49.9±1.0 m.y.) and an Rb-Sr whole-rock isochron (50.0±1.9 m.y.) with previously published mineral dates. The feldspathoid-bearing rocks of the intrusion, which were the last to crystallize, have uniformly depleted oxygen (¹⁸O = +3.9, SMOW) and homogeneous initial ⁸⁷Sr/⁸⁶Sr ratios (0.70450±7). This is ascribed to equilibration of the magma prior to the crystallization of these rocks with about 10% by weight of meteoric ground water. The concommittant increase of to about 1 Kb (the lithostatic load pressure) would depress the liquidus surfaces in the system Ne-Ks-Qz by about 200 ° C, allowing the magma to evolve continuously down temperature from oversatuated to undersaturated compositions. The chemical mechanism responsible for this trend has not been uniquely identified, but probably involved reduction of SiO₂ content in an open system. The outer, quartz-normative, rocks of the intrusion have ¹⁸O values ranging up to +5.5 and initial ⁸⁷Sr/⁸⁶Sr ratios ranging up to 0.7095. This is due to interaction of the solid rocks, down to temperatures approaching 500 ° C, with ground water which had been enriched in ¹⁸O and ⁸⁷Sr by previous exchange with the Precambrian country rocks. Minimum water/rock ratios are lower than in certain other known cases of interaction in the North Atlantic Tertiary Igneous Province.     

Performance‐based design using structural optimization

A new methodology for seismic design is proposed based on structural optimization with performance‐based constraints. Performance‐based criteria are introduced for the seismic design of new buildings. These criteria are derived from the National Guidelines for Seismic Rehabilitation of Buildings (Reference [19], Federal Emergency Management Agency (FEMA), ‘NHERP Guidelines for seismic rehabilitation of buildings’, Report Nos 273 and 274, Washington, DC, 1997) for retrofitting existing structures. The proposed design methodology takes into account the non‐linear behaviour of the structure. The goal is to incorporate in the design the actual performance levels of the structure, i.e. how much reserve capacity the structure has in an earthquake of a given magnitude. The optimal design of the structure minimizes the structural cost subjected to performance constraints on plastic rotations of beams and columns, as well as behavioural constraints for reinforced concrete frames. Uncertainties in the structural period and in the earthquake excitation are taken into account using convex models. The optimization routine incorporates a non‐linear analysis program and the procedure is automated. The proposed methodology leads to a structural design for which the levels of reliability (performance levels) are assumed to be quantifiable. Furthermore, the entire behaviour of the structure well into the non‐linear range is investigated in the design process. Copyright © 2000 John Wiley & Sons, Ltd.     

Faunas from the upper silurian (upper ludlovian) in the ludlow-much wenlock district,England

Faunal lists for 17 sections in the Overton Formation are presented. Faunal diversity appears to increase towards the formations base while faunal dominance appears to increase towards its top.     

Experiments on numerical modeling of intense convection

Results of numerical simulations using the WRF-ARW nonhydrostatic model are presented for eight episodes of intense convection over European Russia in the summer of 2007. The calculations were performed on four nested grids with horizontal grid meshes of 27, 9, 3, and 1 km. Convection was parametrized on the first two grids and explicitly resolved on the other two. It has been found that simulations on finer grids with explicit calculation of convective flows make it possible to reproduce heavy rainfalls and strong-wind zones in the areas of intense convection. A preliminary verification of the short-range predictions of convective systems shows that the maximum 12-h precipitation totals and the maximum winds at 10 m are close, in the order of magnitude, to the observed values. Prediction of convection centers is the weakest point. Difficulties in the model verification associated with the absence of data with high space-time resolution are discussed.     

Deposition of trace substances via cloud interception on a coniferous forest at Kleiner Feldberg

A resistance model to calculate the deposition of cloud droplets on a coniferous forest and some improved parameterizations of the indispensable input parameters are described. The deposition model is adapted to the coniferous forest at the Kleiner Feldberg site and verified by the data of a drip water monitoring station below the forest canopy. The measurements of liqud water content, wind speed and trace substance compounds in cloud water of the Ground-based Cloud Experiment (GCE) at Kleiner Feldberg in 1990 are used to calculate the cloud water deposition fluxes and the deposition of trace substances via cloud water interception. The calculated deposition of trace substances via cloud water interceptions is three to six times higher than via rain during the experiment. On a long term data basis the yearly amount of cloud water deposition is 180 mm year^–1 at Kleiner Feldberg site (840 m a.s.l.) while the precipitation amount is 1030 mm year^–1. Due to higher trace substance concentrations in cloud water compared to rain the ionic deposition via cloud water interception and via precipitation were assessed to be of comparable magnitude.     

Accretion tectonics and crustal structure in Alaska

The entire width of the North American Cordillera in Alaska is made up of “suspect terranes”. Pre-Late Cretaceous paleogeography is poorly constrained and the ultimate origins of the many fragments which make up the state are unclear. The Prince William and Chugach terranes accreted since Late Cretaceous time and represent the collapse of much of the northeast Pacific Ocean swept into what today is southern Alaska. Greater Wrangellia, a composite terrane now dispersed into fragments scattered from Idaho to southern Alaska, apparently accreted into Alaska in Late Cretaceous time crushing an enormous deep-marine flysch basin on its inboard side. Most of interior eastern Alaska is the Yukon Tanana terrane, a very large entirely fault-bounded metamorphic-plutonic assemblage covering thousands of square kilometers in Canada as well as Alaska. The original stratigraphy and relationship to North America of the Yukon-Tanana terrane are both obscure. A collapsed Mesozoic flysch basin, similar to the one inboard of Wrangellia, lies along the northern margin. Much of Arctic Alaska was apparently a vast expanse of upper Paleozoic to Early Mesozoic deep marine sediments and mafic volcanic and plutonic rocks now scattered widely as large telescoped sheets and Klippen thrust over the Ruby geanticline and the Brooks Range, and probably underlying the Yukon-Koyukuk basin and the Yukon flats. The Brooks Range itself is a stack of north vergent nappes, the telescoping of which began in Early Cretaceous time. Despite compelling evidence for thousands of kilometers of relative displacement between the accreted terranes, and large amounts of telescoping, translation, and rotation since accretion, the resulting new continental crust added to North America in Alaska carries few obvious signatures that allow application of currently popular simple plate tectonic models. Intraplate telescoping and strike-slip translations, delamination at mid-crustal levels, and large-scale lithospheric wedging were important processes in northern Cordilleran tectonic evolution.