Anelasticity of the crust and upper mantle beneath north and central India from the inversion of observed Love and Rayleigh wave attenuation data

The fundamental mode Love and Rayleigh waves generated by earthquakes occurring in Kashmir, Nepal Himalaya, northeast India and Burma and recorded at Hyderabad, New Delhi and Kodaikanal seismic stations are analysed. Love and Rayleigh wave attenuation coefficients are obtained at time periods of 15–100 seconds, using the spectral amplitude of these waves for 23 different paths along northern (across Burma to New Delhi) and central (across Kashmir, Nepal Himalaya and northeast India to Hyderabad and Kodaikanal) India. Love wave attenuation coefficients are found to vary from 0.0003 to 0.0022 km^–1 for northern India and 0.00003 km^–1 to 0.00016 km^–1 for central India. Similarly, Rayleigh wave attenuation coefficients vary from 0.0002 km^–1 to 0.0016 km^–1 for northern India and 0.00001 km^–1 to 0.0009 km^–1 for central India. Backus and Gilbert inversion theory is applied to these surface wave attenuation data to obtainQ ^–1 models for the crust and uppermost mantle beneath northern and central India. Inversion of Love and Rayleigh wave attenuation data shows a highly attenuating zone centred at a depth of 20–80 km with lowQ for northern India. Similarly, inversion of Love and Rayleigh wave attenuation data shows a high attenuation zone below a depth of 100 km. The inferred lowQ value at mid-crustal depth (high attenuating zone) in the model for northern India can be by underthrusting of the Indian plate beneath the Eurasian plate which has caused a low velocity zone at this shallow depth. The gradual increase ofQ ^–1 from shallow to deeper depth shows that the lithosphere-asthenosphere boundary is not sharply defined beneath central India, but rather it represents a gradual transformation, which starts beneath the uppermost mantle. The lithospheric thickness is 100 km beneath central India and below that the asthenosphere shows higher attenuation, a factor of about two greater than that in the lithosphere. The very lowQ can be explained by changes in the chemical constitution taking place in the uppermost mantle.     

Na-rich carbonate inclusions in perovskite and calzirtite from the Guli intrusive Ca-carbonatite,polar Siberia

Carbonate phases, some rich in Na₂O and comparatively rich in SrO and BaO, occur as inclusions in perovskite and calzirtite (Ca₂Zr₅Ti₂O₁₆) in the carbonatite of the Guli complex, Siberia. This is the first record of alkali carbonates, akin to nyerereite [Na₂Ca(CO₃)₂], in plutonic igneous rocks. The inclusion populations suggest that the parental magma of the complex was Ca-rich but developed Na-rich differentiates during the latest stages. This points to the dominant calcic carbonatites of the complex not being derivatives of alkali-rich parental carbonatites. These alkali-rich carbonate inclusions (and rare inclusions of djerfisherite) have been preserved due to the resistance of perovskite and calzirtite to processes of leaching, hydrothermal alteration and weathering.     

High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle

Synthetic spinel harzburgite and lherzolite assemblages were equilibrated between 1040 and 1300° C and 0.3 to 2.7 GPa, under controlled oxygen fugacity (f _{O 2}). f _{O 2} was buffered with conventional and open double-capsule techniques, using the Fe−FeO, WC-WO₂-C, Ni−NiO, and Fe₃O₄−Fe₂O₃ buffers, and graphite, olivine, and PdAg alloys as sample containers. Experiments were carried out in a piston-cylinder apparatus under fluid-excess conditions. Within the P-T-X range of the experiments, the redox ratio Fe³⁺/ΣFe in spinel is a linear function of f _{O 2} (0.02 at IW, 0.1 at WCO, 0.25 at NNO, and 0.75 at MH). It is independent of temperature at given Δlog(f _{O 2}), but decreases slightly with increasing Cr content in spinel. The Fe³⁺/ΣFe ratio falls with increasing pressure at given Δlog(f _{O 2}), consistent with a pressure correction based on partial molar volume data. At a specific temperature, degree of melting and bulk composition, the Cr/(Cr+Al) ratio of a spinel rises with increasing f _{O 2}. A linear least-squares fit to the experimental data gives the semi-empirical oxygen barometer in terms of divergence from the fayalite-magnetite-quartz (FMQ) buffer:

An Example of Island-Arc Petrogenesis: Geochemistry and Petrology of the Southern Luzon Arc, Philippines

Volcanism throughout the Luzon arc is associated with eastwardsubduction of the South China Sea floor along the Manila Trench.The southern section of the arc, the focus of this study, extendsfrom the Lingayen-Dingalan fault to the small islands just southof Luzon. Two segments appear to exist along this section ofthe arc the northern Bataan and southern Mindoro segments whichare separated by the Macolod Corridor. The volcanic rocks have typical arc phenocryst mineralogies:olivine, clinopyroxene, plagioclase, and titanomagnetite inthe most mafic rocks and clinopyroxene, plagioclase, orthopyroxene,titanomagnetite, ? amphibole in the more felsic samples. Complexzoning, sieve textures, and decoupling of incompatible traceelements suggest that processes such as assimilation have takenplace. The rocks from the study area range from basalts to rhyolitesand show typical calc-alkaline features. The rocks of the MacolodCorridor and Mindoro segment are particularly enriched in largeion lithophile elements (LILE), light rare earth elements (LREE),and radiogenic Sr compared with the Bataan segment. The datafall within the mantle array on Sr-Nd isotopic diagrams andgrade toward higher Sr and lower Nd isotopic values from northto south. A likely source for the volcanics of this study is either amid-ocean ridge basalt (MORB)-type mantle that undergoes higherdegrees of partial melting than regions involved in MORB generationor a previously depleted source. We suggest that the high fieldstrength element (HFSE) anomalies have been derived throughdifferential element partitioning during fluid transport fromthe subducted lithosphere to the mantle wedge. Continental crustal material seems to play a significant roleparticularly in the Macolod Corridor and the Mindoro segment,based on the high LILE, La/Sm ratios, radiogenic Sr isotopes,and ¹⁸O values. The Macolod Corridor and the Mindoro segmenthave undergone source contamination by crustal material fromthe North Palawan-Mindoro crustal block either during the collisionof this block with the Manila Trench or by subduction of sedimentsrich in this crustal material. A similar component has alsobeen detected in the Bataan segment but in minor amounts. Thetrace element and isotopic differences between the northernand southern sections of the arc are interpreted in terms ofvariable composition (i. e., variable amounts of a crustal componentintroduced from the Palawan-Mindoro crustal terrain) of themetasomatic fluids released into the source.     

The effect of bulk rock composition on the stability of amphibole in the upper mantle: Implications for solidus positions and mantle metasomatism

Summary The stability of pargasitic amphibole in the upper mantle is a function of water content and bulk rock composition, and under water-undersaturated conditions, the stability of amphibole controls the solidus position. Experiments in the system Tinaquillo peridotite +0.2% H₂O, a refractory peridotite under water-undersaturated conditions, show that amphibole is stable to 1030°C and 26 kb. In contrast, pargasitic amphibole is stable to 1150°C and 30 kb in Hawaiian pyrolite, a more fertile peridotite composition. This indicates that under water-undersaturated conditions, the most fertile part of a crystallizing mantle diapir with an inhomogeneous composition will solidify first while a more refractory component will contain an alkali-rich melt which will have the ability to metasomatize adjacent regions. The relative stabilities of amphibole in refractory and fertile bulk compositions may result in increasing rather than diminishing chemical contrasts in high temperature lherzolite, i.e. a process of metamorphic differentiation. Ti, Fe, Al and Na metasomatism can therefore be considered a normal occurrence associated with the upward migration and solidification of an H₂O-bearing mantle diapir.

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Der Einfluß der Gesamtgesteins-Zusammensetzung auf die Stabilität von Amphibol im oberen Mantel: Bedeutung für Solidus-Positionen und Mantel-Metasomatose

Zusammenfassung Die Stabilität pargasitischer Amphibole im oberen Mantel ist eine Funktion von Wassergehalt und Gesamtgesteins-Zusammensetzung. Unter wasser-untersättigten Bedingungen, kontrolliert die Stabilität von Amphibol die Solidus-Position. Experimente in dem System Tinaquillo Peridotit +0,2% H₂O, einem refraktären Peridotit unter wasser-untersättigten Bedingungen, zeigen daß Amphibol bis 1030°C und 26 Kb stabil ist. Im Gegensatz dazu ist pargasitische Hornblende in einem Hawaii-Pyrolit, von mehr fertiler Peridotit-Zuammensetzung, bis 1150°C und 30 Kb stabil. Das zeigt, daß bei wasser-untersättigten Bedingungen der am meisten produktive Teil eines kristallisierenden Mantel-Diapirs mit inhomogener Zusammensetzung sich zuerst verfestigen wird, während eine mehr refraktäre Komponente eine alkali-reiche Schmelze enthalten wird, die wiederum die Fähigkeit hat, umliegende Bereiche metasomatisch zu beeinflussen. Die relativen Stabilitäten von Amphibol in refraktären und fertilen Gesamtzusammensetzungen können dazu führen, daß die chemischen Gegensätze in Hochtemperaturlherzoliten eher zunehmen als abnehmen, d. h. ein Prozeß metamorpher Differentiation. Ti, Fe, Al und Na Metasomatose können deshalb als ein verbreiteter Vorgang, der mit der Aufwärtsbewegung und Verfestigung eines H₂O-führenden Mantel-Diapirs assoziiert ist, betrachtet werden.

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With 4 Figures     

An internal variable model for the creep of rocksalt

Summary The creep strain rate of rocksalt, like that of other ductile crystalline materials, can be described by a power law equation of the type ( ) ⁿ , where the active stress is the difference between the total deviatoric applied stress and an internal stress _i . In this paper, the origin and the nature of this internal stress, which develops during inelastic deformation of the material, are discussed. It is shown that this internal stress can serve as an internal (or state) variable in the constitutive model of rocksalt, which reflects the microstructure evolution of the material under the competitive action of hardening and recovery mechanisms.An analysis of experimental data, both our own and those taken from the literature, demonstrates that such a law is able to correctly reproduce rocksalt creep test results in the steady-state domain. The proposed model is in accordance with the macroscopic and microscopic behavior of salt, and with direct measurements of the internal stresses made by others on this material.     

Hawaiian basalt and Icelandic rhyolite: Indicators of differentiation and partial melting

In spite of the voluminous basaltic volcanism on the island of Hawaii, rhyolite is not produced. Iceland, on the other hand, exhibits common rhyolitic volcanism amounting to some 10–12% of its surface rocks. This contrast is investigated using the fundamental igneous processes exhibited by sheet-like Hawaiian lava lakes and Shonkin Sag laccolith in Montana. Highly differentiated, residual melts normally reside within inwardly advancing solidification fronts and are generally inaccessible to eruptive processes. Only when a large initial phenocryst population is present, from which a thick basal cumulate can rapidly form, is it possible to supply highly differentiated melt into the active (i.e., eruptable) portion of the magma chamber. Although there is protracted control of differentiation at Hawaii by settling of olivine, further differentiation occurs within the solidification fronts. Only by repeated transport and holding is it possible to differentiate beyond the critical composition of the leading edge of the solidification front ( 7% MgO and 51.5% SiO₂). Crystal size distributions (CSDs) for Hawaii and Shonkin Sag are used to demonstrate the inferred physical and chemical processes of solidification, including the kinetics of crystallization.A ubiquitous feature of these basaltic bodies is the formation of coarse veins and segregations of refined melt and granophyres within the upper solidification front. It is this fundamental bimodal feature which is the key to understanding Icelandic silicic volcanism.Rhyolites in Iceland occur mainly as a bimodal population with basalts associated with central volcanoes. Rhyolites, granophyres, and felsites are common, with the intrusions often being layered. Ash flows and true granite-like intrusions are rare. The voluminous silicic lavas at Torfajokull central volcano contain disequilibrium phenocryst assemblages. This, and the disagreement in oxygen isotopic values between rhyolites and basalts, reflects extensive partial melting of the heterogeneous basaltic crust of Iceland to produce these rhyolites. Relatively small, chemically distinct, and spatially intimate silicic bodies are formed by concentrating granophyric segregations from earlier cycles of solidification. This process is also reflected in the layered granophyric instrusion of Slaufrudalur in eastern Iceland. Slaufrudalur is an unvented subterranean caldera, equivalent in igneous processes and style to the subaerial Torfajokull caldera.Hawaii is dominated by fractional crystallization due to crystal settling and does not produce rhyolite. Iceland's tectonics allow continual and extensive reprocessing of thin, hot basaltic crust which produces rhyolite by concentrating original silicic segregations and veins and by partially melting intermediate extrusives, which have subsided deep into the crust.

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Zusammenfassung Auf Hawaii treten, trotz intensiven Basalt-Vulkanismusses, keine Rhyolithe auf. Auf Island dagegen ist Rhyolith, mit 10–12% des anstehenden Gesteins, verbreitet. Dieser Kontrast wurde anhand grundlegender magmatischer Prozesse untersucht, wie sie in flachen Lava-Seen Hawaiis und im Shonkin Sag Laccolith Montanas auftreten. Hochdifferenzierte Restschmelzen verbleiben innerhalb langsam nach innen vorrückender Erstarrungsfronten und sind meist unerreichbar für eruptive Prozesse. Nur wenn anfänglich bereits große Mengen von Einsprenglingen vorhanden sind, die rasch am Boden der Magmenkammer akkumulieren, kann eine hochdifferenzierte Schmelze in den aktiven (d.h. eruptiven) Teil der Magmenkammer gelangen. Obwohl auf Hawaii die Differentiation durch die Kristallisation von Olivin anhaltend kontrolliert wird, findet an der Erstarrungsfront weitere Differentiation statt. Nur durch wiederholten Transport und zeitweiliges Verharren ist es möglich, über die kritische Zusammensetzung der vordersten Erstarrungsfront hinaus zu differenzieren (ca. 7% MgO und 51,5% SiO₂). An Kristallgrö-ßenverteilungen (CDS) von Hawaii und Shonkin Sag können die angenommenen physikalischen und chemischen Prozesse der Kristallisation und die Kristallisationskinetik gezeigt werden. Ein weit verbreitetes Merkmal dieser Basaltkörper ist die Bildung grobkristalliner Gänge und Absonderung von stark differenzierten Schmelzen und Granophyren innerhalb der oberen Erstarrungsfront. Diese ausgeprägt bimodale Charakteristik ist der Schlüssel zum Verständnis des sauren isländischen Vulkanismus.Isländische Rhyolithe treten meist in bimodaler Verbreitung mit Basalten in Zusammenhang mit zentralen Vulkanen auf. Rhyolithe, Granophyre und Feisite sind häufig, in oft geschichteten Intrusionen. Ignimbrite und echte Granitintrusionen sind selten. Die großen Mengen SiO₂-reicher Laven am Torfajokull-Zentralvulkan enthalten Ein-sprenglinge, die sich nicht im Gleichgewicht mit der Matrix befinden. Dies, und die unterschiedlichen delta-¹⁸O-Werte von Rhyolithen und Basalten, zeigen, daß ausgeprägtes teilweises Aufschmelzen der heterogenen Basaltkruste von Island zur Produktion dieser Rhyolithe führte. Relativ kleine, nahe benachbarte saure Körper, die aber deutliche Unterschiede in ihrem Chemismus aufweisen, werden gebildet durch die Konzentration granophyrischer Teilschmelzen aus früheren Kristallisationszyklen. Dieser Vorgang wird auch widergespiegelt in der »layered intrusions« von Slaufrudalur in Ostisland. Slaufrudalur ist eine geschlossene unterirdische Kaldera, deren magmatische Prozesse und Baustil der subaerischen Torfajokull-Kaldera entsprechen.Die Prozesse in Hawaii sind dominiert von gravitativer Kristallisationsdifferentiation und es werden keine Rhyolithe produziert. Die isländische Tektonik führt zu kontinuierlicher starker Wiederaufarbeitung von dünner, heißer basaltischer Kruste. Dabei wird, durch die Konzentration ursprünglicher saurer Teilschmelzen und Gänge und durch die teilweise Aufschmelzung intermediärer Intrusiva, die tief in die Kruste abgesunken sind, Rhyolith produziert.

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Résumé En dépit du volcanisme basaltique volumineux des îles Hawaï, il n'y existe pas de rhyolite. En Islande, par contre, le volcanisme rhyolitique est commun et représente 10 à 12% des roches de la surface. Ce contraste est examiné sur la base des processus ignés fondamentaux présentés par les lacs de lave d'Hawaï et le laccolite de Shonkin Sag au Montana. Normalement, les liquides résiduels hautement différenciés résident à l'intérieur des fronts de solidification qui progressent vers l'arrière et sont généralement à l'abri des processus éruptifs. Ce n'est que dans le cas d'une population initiale abondante de phénocristaux, qui se rassemblent dans un cumulat basai épais, que des liquides hautement différenciés peuvent être fournis à la portion active (c'est-à-dire »éruptible«) de la chambre magmatique. A Hawaï, bien que la différenciation soit continuellement régie par la cristallisation d'olivine, la poursuite du processus a lieu à l'intérieur des fronts de solidification. Ce n'est que par la répétition d'actions de transport et de stagnation qu'il est possible de différencier audelà de la composition critique du front de solidification (±7% MgO et 51,5% SiO₂). A partir de la distribution de la taille des cristaux à Hawaï et à Shonkin Sag, on peut déduire les processus physique et chimique de la solidification, y compris la cinétique de la cristallisation.Une particularité courante de ces corps basaltiques est la formation de veines grenues et de ségrégations de liquides très différenciés et de granophyres à l'intérieur du front supérieur de solidification. Cette manifestation bimodale est la clé qui permet de comprendre le volcanisme siliceux islandais.En Islande, les rhyolites constituent d'ordinaire une population bimodale avec les basaltes centraux. Les rhyolites, les granophyres et les felsites sont fréquents, et souvent sous forme d'intrusions litées. Les coulées ardentes et les vraies intrusions de type granitique sont rares. Les volumineuses laves siliceuses du volcan central de Torfajokull contiennent des assemblages de phénocristaux en déséquilibre. Ce fait, ainsi que la non concordance des isotopes de l'oxygène entre rhyolites et basaltes, traduisent, à l'origine de ces rhyolites, une fusion partielle extensive de la croûte basaltique hétérogène d'Islande. Des corps siliceux relativement petits et chimiquement distincts bien que d'emplacements très voisins se sont formés par concentration de fusions partielles granophyriques lors des premiers cycles de solidification. Ce processus s'exprime également dans l'intrusion granophyrique litée de Slaufrudalur, en Islande orientale. Slaufrudalur est une caldeira souterraine fermée, équivalente par son style et son processus igné à la caldeira subaérienne de Torfajokull.A Hawaï, le phénomène dominant est la cristallisation fractionnée gravitative, sans production de rhyolite. La tectonique de l'Islande permet la régénération continue et extensive d'une mince croûte basaltique chaude. Les rhyolites y sont engendrées par la concentration des veines et ségrégations siliceuses originelles et par la fusion partielle de masses extrusives intermédiaires descendues profondément dans la croûte.

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, . , 10–12% . , Shonkin Sag Laccolith Montanas. . , , . , . . ( 7% MgO 51,5% SiO₂). (CDS) Shonkin Sag , , . . . . , , . . , Torfajokull , ., ¹⁸O , . , , , , « » («layered intrusions») Slaufrudalur, . , , Torfajokull. . . , , , .

     

Sublethal abnormalities in embryos of winter flounder,Pseudopleuronectes americanus,from Long Island Sound

Sublethal abnormalities were examined in developing embryos of the winter flounder,Pseudopleuronectes americanus, as part of a study of its early reproductive success in Long Island Sound and two sites in Boston Harbor. These sites represented varying levels of anthropogenic contamination that were possibly affecting reproduction, as ascertained by chromosomal abnormalities and lowered developmental rates in the embryos. Effort was focused on examination of blastula and tail-bund embryos from field-captured females spawned at the laboratory. Abnormalities observed included evidence of cytotoxicity and chromosome damage. Embryos of fish from New Haven were usually the most aberrant, while embryos from other sites, notably Hempstead, Shoreham, and both Boston Harbor stations, showed subtle indications of abnormality.     

Implications of liouville's theorem on the apparent brightness temperatures of solar radio bursts

Liouville's theorem for radiation, of which the generalized étendue is a consequence, implies ² d² d² A = constant along the ray path, where is the refractive index and d² and d² A are the ranges, respectively, of solid angle and of area that define a ray (actually a bundle of rays). Implications of this concept on the propagation of radio waves from the actual to the apparent source in the solar corona (i.e., the scatter image of the true source) are discussed. The implications for sources of fundamental plasma radiation include: (1)The observed solid angle (defining the directivity) and apparent area A of the source are compatible with Liouville's theorem only if the apparent source (the scatter image of the true source) corresponds to the envelope of subsources with a small filling factor f. (2) The brightness temperature T _Bof the actual source is greater than that of the apparent source by f ^-1. (3) For sources of fundamental plasma radiation the factor f is very small ( 10^-2). (4) A long-standing discrepancy between the observed low value of T _B at meter/decameter wavelengths for the quiet Sun and the known coronal temperature may be resolved by noting that the implied coronal temperature is given by T _B f and that the factor f must be significantly less than unity.A brief discussion is included of the relation between Liouville's theorem, the generalized étendue, Milne's laws, occupation numbers, extension in phase, and suppression of emission by a medium with refractive index unequal to unity.