Himalayan magmatism and porphyry copper–molybdenum mineralization in the Yulong ore belt, East Tibet

Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 10⁶ tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002     

Quaternary stratigraphy of the buried valleys of the lower Red Deer River,Alberta, Canada

The Quaternary fills of the buried valleys of southern Alberta and Saskatchewan have provided a wealth of information for the reconstruction of the glacial-interglacial record of the western plains of Canada, and this paper reports on the previously unstudied stratigraphy of the buried Calgary Valley and its former tributaries in the lower Red Deer River area. We attempt to differentiate Empress Group sediments, which potentially relate to pre-glacial, interglacial/ interstadial and post-glacial lake and river deposition, using sedimentology, stratigraphy and palaeoecology. Twenty-nine stratigraphical logs indicate that Empress Group sediments have infilled a considerably large area of badlands and tributary coulees that once drained into the Calgary Valley, located 15 km to the north of Dinosaur Provincial Park. Radiocarbon dates of 52.4 ka, 27.4 ka and > 42.4 ka and glacially modified quartz grains suggest that at least some of the valley fills date to interglacial or interstadial periods and may be mid-Wisconsinan in age. However, outcrops of an older till overlying other valley fills suggest that the buried valleys were only partially excavated during interglacials/interstadials and that older (even pre-glacial) sediments could have survived. Subglacial channels, recognisable on air photographs, largely coincide with buried valley positions due to the preferential excavation of the Quaternary sediment by meltwater and are filled with post-glacial lake sediment from which a radiocarbon date of 16 ka BP was obtained. Pre-glacial and glacial/post-glacial Empress Group sediments are lithologically indistinct but cover a large time span in southern Alberta.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

Field,petrophysical and carbon isotope studies on the Lapland Granulite Belt: implications for deep continental crust

The Palaeoproterozoic Lapland Granulite Belt is a seismically reflective and electrically conductive sequence of deep crustal (6–9 kbar) rocks in the northern Fennoscandian Shield. It is composed of garnet-sillimanite gneisses (khondalites) and pyroxene granulites (enderbites) which in certain thrust sheets form about 500 m thick interlayers. The structure was formed by the intrusion of intermediate to basic magmas into turbiditic sedimentary rocks under granulite facies metamorphism accompanied by shearing of the deep crust about 1.93–1.90 Gyr ago (Gal. Granulites were upthrust 1.90–1.87 Ga and the belt was divided by crustal scale duplexing into four structural units whose layered structure was preserved. The thrust structures are recognized by the repetition of lithological ensembles and by discordant structural patterns well distinguishable in airborne magnetic and electromagnetic data. Thrusting gave rise to clockwise pressure-temperature evolution of the belt. However, some basic rocks possibly record an isobaric cooling path. The low bulk resistivity of the belt (200–1000 Ωm) is caused by interconnected graphite and subordinate sulphides in shear zones. On the basis of carbon isotope ratios this graphite is derived mostly from sedimentary organic carbon. The seismic reflectivity of the belt may be caused by velocity and density differences between pyroxene granulites and khondalites, as well as by shear zones.     

Metamorphic decarbonation, silicate weathering and the long-term carbon cycle

The seawater ⁸⁷Sr/⁸⁶Sr curve implies a 50–100 Myr episodicity in weathering rate which requires a corresponding variation in CO₂ degassing from the solid earth to the atmosphere. It is proposed that this is caused by orogenesis, which both produces CO₂ as a result of metamorphic decarbonation reactions, and consumes extra CO₂ as a consequence of erosion-enhanced weathering. Global climate on the geological time-scale is therefore contTolled by the difference between the relatively large and variable orogenic-moderated degassing and weathering CO₂ fluxes.     

Obtaining basic simulation data for a heterogeneous field with stratified marine soils

Thinly stratified sedimentary deposits in a heterogeneous field were investigated to obtain basic physical data for the simulation of water flow. A procedure is described which translates a thinly stratified soil profile into a number of functional layers using functional hydrological properties. A functional layer is defined as a combination of one or more soil horizons and should (i) be recognizable during a soil survey using an auger and (ii) show significantly different functional hydrological properties when compared with another functional layer. This procedure gave three easily recognizable functional layers. Sets of hydrological characteristics of these three functional layers were obtained by physical measurements of the soil and by estimation, using textural data for classification into a standard Dutch series. The performance of several combinations of these sets was tested by comparing simulated and measured soil matric potentials for seven plots during one year. The best simulation results were obtained if measured soil hydraulic characteristics were used for relatively homogeneous functional layers and if the soil hydraulic characteristics were estimated at each location for the most heterogeneous layer.     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996