Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.     

A techno-economic comparison of power systems for autonomousunderwater vehicles

This paper compares lead-acid batteries, sodium-sulfur batteries, solid polymer fuel cells and closed-cycle diesel engines for autonomous underwater vehicle (AUV) applications. The service is described in terms of a parametric mission and life cycle. A generic AUV is used as a basis for comparison. Power systems are evaluated by two criteria: (1) submerged endurance capability and (2) life cycle cost. This study determines categories of service for which each power system is preferred. The solid polymer fuel cell can provide greater submerged endurance than other power systems examined. For extremely long duration AUV missions, the fuel cell is the required system, indicating a possible market niche for today's fuel cell technology. Considering cost projections for each power system, the results also show that the SPFC can become cost-competitive with conventional technologies, particularly for services characterized by high levels of utilization     

Metamorphic evolution of exhumed middle to lower crustal rocks in the Mojave Extensional Belt, southern California, USA

The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H₂O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H₂O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H₂O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.     

Multiple-source localization using GPS technology and receivedarrival time structure analysis in an air-deployed system

An efficient and robust method has been developed to locate multiple impulsive sources in an ocean environment. Global position system (GPS) receivers were installed on sonobuoys to obtain their locations within a few meters of accuracy. A sonobuoy field was deployed in a ring-type pattern. Charges were then set off at arbitrary locations within the ring, High-resolution plots were used to obtain direct path and/or first bottom bounce arrivals on each buoy. A model grid of arrival times was constructed, corresponding to the dimensions of the buoy field. A ray model previously developed here at the Applied Research Laboratories at the University of Texas at Austin (ARL:UT) was used to obtain model travel times. The minimum value of the least-square-type error between the real arrival times and the modeled travel times resulted in an unambiguous location of the source, within the limits of the grid spacing chosen. This value was calculated by picking one receiver as the reference and then summing the timing errors of the remaining receivers relative to the reference. Successive iterations with finer grid spacings result in source localization within the accuracy of the buoy locations. The localization routine was extended by allowing permutations of the pulse arrivals on each buoy to account for multiple sources closely separated in time and/or space. An automated correlation technique is presented as an alternative to the leading edge-detection method used here for obtaining relative arrival times. Two proof-of-concept experiments were performed and some results of data obtained at Lake Travis and the Gulf of Mexico are presented     

Recurrent Red-tides in the Southampton Water Estuary Caused by the Phototrophic CiliateMesodinium rubrum

In the Southampton Water estuary (southern England, U.K.), red-tides caused by the planktonic, phototrophic ciliateMesodinium rubrum(=Myrionecta rubra) occur during most summers and sometimes in autumn. These events were investigated in detail between 1985 and 1987 and were characterized by levels of chlorophylla(chl a) of over 100 μg l⁻¹, cell numbers ofM. rubrumof over 1×10³ ml⁻¹, oxygen saturations of around 150%, and depleted numbers of macrozooplankton. Initiation of red-water did not appear to be triggered by irradiance or nutrients, but coincided with an increase in temperature and water column stability. This enhanced stability was promoted by increased surface to bottom gradients of both temperature and salinity, and by reduced mixing during neap tides. Development of red-water was accompanied by removal of most of the dissolved NH⁺₄from the water column, whereas some NO⁻₃persisted, presumably maintained by freshwater input. NO⁻₃and NH⁺₄gradually returned to pre-bloom concentrations as the red-water declined in late summer. Maximal biomass ofM. rubrumappeared to be limited by irradiance, and self-shading probably imposed an upper limit of around 300 mg chl a m⁻²within the water column. At the observed levels of chl a, irradiance values within the population maximum between 1 and 3 m depth were only just of the order (≈15 μmol photons m⁻² s⁻¹) required to balance estimated respiratory demands. Oxygen concentration became undersaturated during the late bloom phase, with minimal values of 20–30% saturation recorded in deeper waters; however, despite this and reduced numbers of macrozooplankton, direct deleterious effects on other organisms were not observed.     

Transient phenomena in the energetic behind-the-limb solar flare of september 29, 1989

The powerful cosmic ray flare of Sept. 29, 1989 occurred behind the limb and was observed over a wide spectral range. The analysis of optical, radio, and other relevant data suggest two phases of energy release. After an impulsive phase a prolonged post eruption energy release occurred in an extended region of the corona following the eruption of a large coronal mass ejection (CME). This phase is responsible for numerous coronal and interplanetary phenomena including the ground-level increase of cosmic rays.     

High-temperature geothermal reservoir possibilities in Hungary

Theoretical studies have shown the possibility of high-temperature ('high enthalpy') geothermal reservoirs in the pre-Tertiary rocks at 4–5 km depth range within the Pannonian Basin. This expectation was proven by the hotwater/steam blowout of Fábiánsebestyén-4 borehole (16.12.85–31.1.86). Exploration efforts carried out during 1987–88 in the broad vicinity of the borehole proved that reservoirs of this type can be found with the combination of seismic reflection, silica-thermometry and magnetotelluric sounding methods. Deliberate prospection should be continued in all suitable areas within the basin, since high enthalpy reservoirs promise profitable operation of geothermal power stations.     

Trace-element contents and cathodoluminescence of “trapiche” rubies from Mong Hsu, Myanmar (Burma): geological significance

Summary ?Mong Hsu rubies of the “trapiche” type are sporadically seen in the gem market. However, they have never been described in the field. The study of the nature of solid inclusions, the variation of trace-element contents, as well as the cathodoluminescence behaviour of six “trapiche” rubies permit the conclusion that these rubies crystallised in the same geological environment (marble-type deposit) as the normal rubies from Mong Hsu: (1) Cr and V are the main chromophorous elements in both ruby types; they act, together with Ti, as activators or quenchers for cathodoluminescence; (2) calcite, dolomite, rutile, mica, diaspore, apatite, chlorite, and feldspar are solid inclusions found in both ruby types; (3) the presence of bastn?site in trapiche ruby and fluorite in non-trapiche ruby indicates the circulation of F-bearing fluids during ruby deposition; (4) the distribution of trace-element contents in the crystal is similar for both ruby types. In the Cr₂O₃ vs. Fe₂O₃ and Cr₂O₃ vs. Fe₂O₃/TiO₂ diagrams, the population fields of Mong Hsu “trapiche” and non-“trapiche” rubies overlap. They are distinct from those of rubies and sapphires hosted in basalts from South-east Asia. Received October 30, 2001; revised version accepted March 25, 2002     

On the resonant spin flavor precession of the neutrino in the sun

This work deals with the possible solution of the solar neutrino problem in the framework of the resonant neutrino spin-flavor precession scenario. The event rate results from the solar neutrino experiments as well as the recoil electron energy spectrum from SuperKamiokande are used to constrain the free parameters of the neutrino in this model (Δm² and μ_ν). We consider two kinds of magnetic profiles inside the sun. For both cases, a static and a twisting field are discussed.