Boron incorporation into mullite

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria     

Fission track dating of volcanic glass shards in marine sediments

The fission track dating method is applied to glass shards from volcanic ash layers in deep sea sediments which have also been dated by other methods. Measured ages for three samples are in excellent agreement with previously determined K-Ar, paleomagnetic and paleontologic ages. The fission track method of dating of glass shards seems to offer itself as a valuable tool for dating marine sediments.     

THE DELINEATION OF THE BEDROCK CONFIGURATION OF PART OF PORT JACKSON,NEW SOUTH WALES,WITH A BOOMER SYSTEM*

A high resolution Boomer system was used to investigate the bedrock configuration of part of Port Jackson, New South Wales. The continuous reflection profiling technique was successful in delineating a channel incised in bedrock under a thickness of up to 60 m. of unconsolidated sediment covered by up to 20 m. of water.     

THE LAUSANNE CONGRESS

The International Society for Photogrammetry held the Xlth International Congress at Lausanne during July 1968. The authors review the activities of five of the seven I.S.P. Commissions.     

THE ANALYTICAL ORIENTATION OF A LUNAR MODEL

An analytical relative orientation of a stereo-pair of photographs was computed in an unusual system of co-ordinates. The disparity in the widely mismatched photographs, their tilts and narrow angles subtended resulted in a rather weak solution from which sections of the lunar surface have been plotted. The results were not good but were better than expected. The main outcome of the work is a, probably unique, demonstration of the versatility of analytical photogrammetry.     

ANALYTICAL AERIAL TRIANGULATION BLOCK ADJUSTMENT; THE DIRECT HEIGHT SOLUTION INCORPORATING TIE-STRIPS

The historical development of analytical aerial triangulation block adjustment is mentioned by way of introduction. The advantages of separating the plan and height adjustments are given and the observation equations of a typical adjustment section are analysed to show that this convenient practice is justified in normal circumstances. The principles of a direct solution of the normal equations suitable for a moderate-sized computer, are explained and developed in detail for the height adjustment. The advantages of tie-strips in the height adjustment are demonstrated and the difficulties which then arise are discussed. An approximate method which overcomes these difficulties is developed. Details of the computer programmes used are given in Appendix B.     

Measurements of radio noise at 0.700 mc and 2.200 mc from a high-altitude rocket probe

Radio noise observations at frequencies of 0·700 Mc and 2·200 Mc were made at altitudes between 3000 and 11,000 km from a Blue Scout Jr. high-altitude rocket probe on 30 July 1963. A steady background flux of (7·5₋₃⁺⁶) × 10⁻¹⁹ W m⁻²)(c/s)⁻¹ at 0·700 Mc and (1·8^+1.0_−0.5 × 10⁻¹⁹ W m⁻² (c/s)⁻¹ at 2·200 Mc was observed. Assuming a galactic origin of the observed fluxes at both frequencies, the averaged sky brightnesses are b(0·700 Mc) = (6₋₃⁺⁵) × 10⁻²⁰ W m⁻² (c/s)⁻¹ sr⁻¹b(2·200 Mc) = (1.4^+1.0_−0.5 × 10⁻²⁰ W m⁻² (c/s)⁻¹ sr⁻¹ The observed brightness at 2·200 Mc is in reasonable agreement with the results of other observers. The apparent brightness at 0·700 Mc is, however, greater than was expected from previous observations. An alternative source of the 0·700 Mc flux in the terrestrial exosphere, as well as characteristics of several noise bursts observed during the flight, is briefly discussed.     

Models of the Southern Oscillation in the 300–100 mb layer and the basis of seasonal forecasting

Summary The geometry of the principal Upper High (near the Indian Occean) in the 300–100 mb layer appears to account for the Southern Oscillation (S.O.), and models of its behaviour are presented. Significant features of these models include the equatorial points of upper convergence (C) and divergence (D), a pressure discontinuity (CNDS) forming «arcs» and an «enclosure» around the high, and, lastly, encircling «crescents» both outside and inside the enclosure. The geography of the seasonal sucession can thus—in a qualitative manner—be interpreted in the light of known wind and contour patterns near the tropopause. With a few general principles, the established empirical rules of long-range forecasting then follow by deduction. The models and the terminology are useful likewise in the interpretation of solar-terrestrial relations and of climatic fluctuations.