Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Application of cluster analysis to study the relationship between the fine stratification and the background hydrological conditions in the ocean

Cluster analysis is discussed in the context of its application to map various test areas in the sea. By analysing the correspondence of the identified categories to areas with specific hydrological conditions, an attempt is made to relate the types of fine structure to diverse background conditions. With two test areas mapped, a conclusion is made as to the possible application of cluster analysis to this end.Translated by Vladimir A. Puchkin.     

Evaluation of drift current parameters using an analytical model

The paper is concerned with the evaluation of the drift current parameters derived through the use of an analytical model. In this model, effective when stratification is stable and indifferent, the vertical turbulence coefficient profile is prescribed by the power function, and hydrodynamic quantities are prescribed using the external parameters of the problem (wind stress, the Coriolis parameter, and the dimensionless stratification parameter). Model data are compared with the observations of the upper mixed layer in the vicinity of the oceanic Station C, conducted during one year. It is shown that, under the spring-summer-time warming conditions, the model at issue is capable of adequately simulating the upper ocean layer dynamics. Translated by Vladimir A. Puchkin.     

Seasonal course of theT,S-characteristics in the north-eastern Tropical Atlantic

The problem of the seasonal variations of temperature and salinity in the intermediate zone located between the West African and the Gulf of Guinea upwellings is considered. The vertical distribution of the phase-amplitude characteristics of the annual and semi-annual variations is examined in good detail and their parameters are defined from the monthly means using the least-squares fit technique. The contribution of isopycnic advection to the formation of seasonal thermohaline variations is studied.Translated by Vladimir A. Puchkin.     

Determination of characteristics of atmospheric motions from satellite multiwave remote sensing data

A method of determination of atmospheric dynamic characteristics from the data of remote sensing from a geostationary satellite is described. The method is based on the use of inhomogeneities in the concentration field of a conservative additive as tracers and on the application of correlation-extreme algorithms. Unlike the common methods used abroad, this method is able to determine not only the vector field of wind velocity but also the coefficient of turbulent diffusion and vorticity. Results of computations of the fields of the horizontal component of wind velocity and the effective coefficient of horizontal mesoscale turbulent diffusion from the Meteosat-8 SEVIRI water-vapor channel data are presented. It is shown that the average values of the effective coefficient of mesoscale horizontal turbulent diffusion in the areas with a predominantly turbulized air-mass motion are 1.5 times greater than in the areas where a laminar motion dominates. Specific features of the calculated values of the upper-troposphere dynamic characteristics in different stages of the North Atlantic TC Helene (September 2006) are analyzed.     

Differential model of the hydrophysical fields' vertical structure in a stratified tidal flow over a shelf

This paper studies the influence of shelf tidal flows on the structure of surface and near-bottom turbulent boundary layers.Translated by Vladimir A. Puchkin.