Effects of water-borne copper on metallothionein and lipid peroxidation in the marine amphipod Gammarus locusta

The aim of the current work was to determine over 10 days the effects of water-borne exposure of the marine amphipod Gammarus locusta to 4 microgCu l(-1) on the metallothionein (MT; measured by differential pulse polarography) protection system and lipid peroxidation (LP: thiobarbituric acid-reactive malondialdehyde equivalents) as a measure of oxidative damage. MT levels in exposed animals increased significantly at day 2 (36% > control; P < 0.001) and remained high at days 6 and 10 (55 and 38%, respectively, P < 0.001). The maximum level of MT at day 6 coincided with the highest Cu body-burden. LP increased within I day of exposure, indicative of Cu as an oxidative stressor. However, in contrast to MT, the highest LP level was seen at day 4 (68% > control, P < 0.001) before returning to control values by day 6, indicating a protective role of MT against the pro-oxidant effects of Cu.     

Olivine in ultramafic lamprophyres: chemistry,crystallisation, and melt sources of Siberian Pre- and post-trap aillikites

We studied olivines from the Devonian pre-trap (the Ilbokich occurrence) and the Triassic post-trap (the Chadobets occurrence) carbonate-rich ultramafic lamprophyres (UMLs) in the southwestern portion of the Siberian craton. On the basis of detailed investigations of major, minor, and trace-element distributions, we have reconstructed the main processes that control the origins of these olivines. These include fractional crystallisation from melt, assimilation, and fractional crystallisation processes with orthopyroxene assimilation, melt-reaction diffusive re-equilibration, alkali enrichment, and CO₂ degassing of the melt. Furthermore, we inferred the composition of the sources of the primary UML melt and their possible correlations with proto-kimberlitic melts, as well as the influence of the Triassic Siberian plume on the composition of the lithospheric mantle. The main differences between olivines from the Ilbokich and the Chadobets aillikites were that the olivines from the former had more magnesium-rich cores (Mg# = 89.2?±?0.2), had Mg- and Cr-rich transition zones (Mg# = 89.7?±?0.2 and 300–500 ppm Cr), had lower Ni (up to 3100 ppm) and Li (1.4–1.5 ppm), and had higher B (0.8–2.6 ppm) contents, all at higher Fo values (90–86), relative to the olivines from the latter (Mg# = 88–75; 200–300 ppm Cr; up to 3400 ppm Ni; 1.4–2.4 ppm Li; 0.4–2.2 ppm B). The Siberian aillikite sources contained a significant amount of metasomatic material. Phlogopite-rich MARID-type veins provided the likely metasomatic component in the pre-trap Devonian Ilbokich aillikite source, whereas the Triassic Chadobets aillikitic post-trap melts were derived from a source with a significant carbonate component. A comparison of UML olivines with olivines from the pre-trap and post-trap Siberian kimberlites shows a striking similarity. This suggests that the carbonate component in the aillikitic source could have been produced by evolved kimberlite melts. The differences in the lithospheric metasomatic component that contributed to pre-trap and post-trap aillikitic melts can be interpreted as reflections of the thermal impact of the Siberian Traps, which reduced phlogopite-bearing metasomes within the southwestern Siberian sub-continental lithospheric mantle.     

A cost–benefit appraisal of coastal managed realignment policy

European coasts are coming under increasing threat as a result of climate change from erosion and flooding. While coastal defences such as sea walls have been constructed since Roman times to protect human settlements from the sea, it is now increasingly recognised that these defences are unsustainable. The security provided by ‘hard’ engineered defences has encouraged development on the coast, and the defences themselves have led to the loss of intertidal habitat and the natural protection it provides.An alternative to maintaining ‘hard’ defences (hold-the-line) to protect land from increasing sea levels is managed realignment, where the engineered defences are deliberately breached. By allowing the coastline to recede to a new line of defence further inland, intertidal habitat is created providing natural protection from flooding and erosion.The study evaluates the economic efficiency—using cost–benefit analysis—of various managed realignment scenarios compared to a strategy of holding-the-line within the Humber estuary in North-east England. The results of this analysis show that managed realignment can be more economically efficient than holding-the-line over a sufficiently long time period—generally greater than 25 years. Sensitivity analysis demonstrates that results are more sensitive to the amount and value of intertidal habitat generated than they are to the amount and value of carbon stored by this habitat. Cost–benefit analysis is viewed as one component of a wider policy appraisal process within integrated coastal management.     

A calibration system for superconducting gravimeters

A new method for the calibration of a superconducting gravity meter is described, in which a 273 Kg annular mass is placed around the meter and is moved up and down. The geometry of the apparatus is easy to model and the accuracy in the computation of the gravity variation induced by the mass, 6.7µgal, is limited only by the accuracy in the knowledge of value of the gravitational constant. Measurements done in 91 and 92 for the calibration of the instrument GWR-T015 are described. The calibration factor has been determined with a precision of about 0.3%.     

Evidence for long-term asymmetries in the Earth's magnetic field and possible implications for dynamo theories

Paleomagnetic data indicate that there is a north-south asymmetry in the time-averaged magnetic field and that there are small but significant differences between the normal and reverse polarity states. The geographical variation is most likely due to spatial variation in the boundary conditions at the core-mantle interface. The difference in the magnetic fields of the reverse and normal polarity states can be modeled in terms of a “standing field”. The paleomagnetic data are insufficient to determine whether or not this “standing field” is of core origin. However, consideration of mechanisms, including thermoelectric currents, indicates that there probably are important differences in core processes between the two polarity states. At first glance this interpretation is difficult to reconcile with the fact that the magnetic induction equation is antisymmetric with respect to the magnetic field. A way around this problem is the possibility that only certain transitions are allowed between acceptable eigenstates in dynamo models of the Earth's magnetic field.     

Zum Umweltverhalten von Fluortensiden. Teil 3: Reinigung der industriellen Abwässer

Four fluorotensides which are used mainly industrially are investigated with respect to their removability from waters. Since, in general, fluorotensides are difficult to remove or not at all removable biochemically, the effects of chemical or physicochemical treatment processes are tested. As the results represented in pictures and tables show, different modes of behaviour can be recognized with respect to the respective purification effect for the investigated fluorotensides, partly among them. Flocculation with Al- and Fe-salts as well as chlorination and ozonization show only partial effects. But all the investigated fluorotensides can be adsorptively eliminated by means of powder or granular active charcoal and adsorbent resin Wofatit EA₆₀.     

Petrogenesis of Cenezoic volcanic rocks from the Aegean island arc

The Aegean volcanic arc formed in response to northeasterly subduction of the Mediterranean sea floor beneath the Aegean Sea. The active arc lies over 250 km from the Hellenic Trench in a region which has suffered considerable extension and subsidence since the mid-Tertiary. Suites of samples from the different volcanic centres making up the arc have been studied geochemically in order to assess lateral variations and to constrain the contribution of crustal contamination and sediment subduction in their petrogenesis.Lavas from all the major volcanic centres exhibit typical calc-alkaline major-element characteristics, and show enrichment in light REE and LIL elements but low contents of HFS elements. The enrichment in light REE is greater in the eastern (Nisyros, Kos) and western (Milos, Poros, Methana, Aegina) sectors of the arc (Ce_n/Yb_n=4) than in the central Santorini sector (Ce_n/Yb_n=2). All lavas have significant negative Eu anomalies and many have slight negative Ce anomalies. Less coherence is observed in the abundances and ratios of the other LIL elements, compared with the REE, along the island chain.Whereas the effects of crystal fractionation are evident in the trace-element patterns of lavas from individual islands, and are particularly well marked for Santorini, it is clear that there are consistent differences in trace-element abundances and ratios in the lavas of the various islands which reflect compositional differences in the mantle source and/or in melting conditions. Lavas from the eastern and western sectors have much higher levels of Ba and Sr but relatively lower Th, K and Rb than those from Santorini. Although some geochemical features could be explained through involvement of a component of subducted sediment in the source regions of the volcanoes, other element abundances and ratios indicate that this component must be very small. Detailed consideration of the inter-island geochemical variations suggests a complex make-up of the underlying lithosphere, resulting from a long history of subduction. In the region of Santorini, where crustal stretching is greatest, the underlying asthenosphere may be involved in magma production.     

Breaking Criteria for Regular Waves on Gentle Slopes

Nelson pointed out that the wave breaking criterion(H/d)_b for gentle slopes(i<1/100),inwhich H is the wave height and d is the water depth at the breaking point,is smaller than that for beachslopes of i>1/100),i.e.,the value of(H/d)_b for gentle slopes may be smaller than 0.6.Goda indicatedthat the wave breaking criterion given by himself is a result based on theoretical study,so it should be alsocorrect and can be used for gentle beaches,i.e.,the value of(H/d)_b for gentle slopes may be still largerthan 0.7.By use of high order nonlinear wave theory,this problem is analyzed in this study and the reasonwhy there is a large difference between different studies is explained.Moreover,the bottom energy loss dur-ing wave propagation is considered and the critical slope for the absence of wave breaking is also analyzed.     

Atmospheric temperature sounding with the Fourier spectrometer

Preliminary results of a space experiment using the IKFS-2 infrared sounder (Meteor-M2 satellite) showed high-quality of measurements of spectra of the outgoing thermal radiation of the atmosphere–surface system and the adequacy of developed IR radiation atmospheric models in the 15-μm carbon gas absorption band used to recover the vertical profiles of the atmospheric temperature. Outgoing radiation spectra measured by IKFS-2 instruments make it possible to restore vertical temperature profiles with errors close to 1K in most of the 0–30 km high-altitude region, except for the lower troposphere and altitudes above 30 km, where these errors are close to 2–3K.