Estimation of petrol and diesel adulteration with kerosene and assessment of usefulness of selected automobile fuel quality test parameters

Kerosene is common adulterant utilized for mixing with diesel. Five fuel-adulterant mixtures in different proportions by volume were prepared and individually tested for density and kinematic viscosity. The mixtures were administered to six light cargo vehicles and the tail pipe exhaust emission was tested for opacity value. No appreciable density variation at different levels of adulteration was observed. Density was within the prescribed value even at higher adulteration. Considerable decrease in kinematic viscosity, a departure from prescribed viscosity, was noted at higher adulteration level. The percent opacity value decreased sharply even at small level of adulteration. The probable amount of kerosene present as an adulterant in diesel dispensed at filling stations in Kathmandu city ranged between 35% and 50%. The observations suggest density test is not a good indicator of diesel adulteration. Kinematic viscosity and opacity value are useful diesel adulteration test parameters. Existing diesel adulteration warrants initiation of strict compliance regulation.     

An innovative priming system - emulsion-based booster

The mineral industry is leading towards a technology driven optimization process. Drilling and blasting are such unit operations in a mine, which can alter the balance sheet of the mine if not planned properly. The development, improvement and utilization of innovative technologies in terms of blast monitoring instruments and explosives technology are important for cost effectiveness and safety of mineral industries.

The ever-growing demand for minerals has compelled the industry to adopt large opencast projects using heavy equipment. This has necessitated use of a few hundred tonnes of explosives in each blast. The bulk delivered fourth generation explosives have solved the problem of explosive loading to a large extent as it provides improved safety in manufacturing, transportation and handling. Bulk delivered emulsion is non-explosive until gasification is complete and a large quantity of explosive can be transported and loaded into blast holes efficiently and with safety. The priming of bulk delivered explosives in Indian mines uses the conventional PETN/TNT-based boosters. The conventional booster possesses safety problems in terms of handling and use, so Indian Explosives Ltd has developed an emulsion-based booster (Powergel Boost).

This paper explores the potential of an emulsion-based booster used as a primer to initiate bulk delivered emulsion explosives used in mines. An attempt has been made at a comparative study between the conventional booster and the emulsion-based booster in terms of the initiation process developed and their capability of developing and maintaining a stable detonation process in the column explosives. The study has been conducted using a continuous velocity of detonation (VOD) measuring instrument, the VODMate two channel system manufactured by Instantel Inc. of Canada. During this study three blasts were monitored. In each blast two holes were selected for study, the first hole was initiated using a conventional booster while the other one used an emulsion-based booster. The findings of the study advocates that the emulsion-based booster is capable of the efficient priming of bulk delivered column explosive with a stable detonation process in the column.     

Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.     

Urban development and flooding in Houston Texas, inferences from remote sensing data using neural network technique

The effects of urban development on the natural ecosystem and its link to the increased flooding in Houston, Texas were evaluated. Houston is suitable for this type of analysis due to its 1.95 million population, large geographic area and fast growth rate. Using neural network techniques, four Landsat Thematic Mapper images were grouped into five land use classes for the period 1984 to 2003: vegetation, bare ground, water, concrete and asphalt. Results show that asphalt and concrete increased 21% in the time period 1984–1994, 39% in 1994–2000 and 114%, from 2000 to 2003, while vegetation suffered an overall decrease. When change detection data are compared with runoff ratio data, a relationship between increased runoff and urban development is apparent, which indicates increased chances of flooding. Initial results of this work are made available to the public in GIS format via internet using Arc Internet Map Server (ArcIMS) at .     

GPS monitoring of vertical ground motion in northern Ardenne–Eifel: five campaigns (1999–2003) of the HARD project

We present the HARD project of GPS monitoring of vertical ground motion in NE Ardenne and Eifel (western Europe). Its main purposes are to get a better insight into the present-day rates of vertical ground motion in intraplate settings and to identify the various causes of these motions. Since 1999, we have carried out yearly campaigns of simultaneous GPS measurements at 12 sites situated so as to sample the different tectonic subunits of the study area and especially to record potential displacements across the seismogenic Hockai fault zone. Five campaigns (1999–2003) have been processed currently. Key issues of the data processing with the Gamit software are discussed and first results are presented. Though temporally consistent in many cases, the obtained vertical motion rates are spatially highly variable. They are also much too high (several mm/year) to support a tectonic interpretation, and a long-term influence of groundwater level variations is proposed to account for the observed motions. This influence should be distinguished from seasonal variations and from inter-survey variations linked to the varying degree of soil and subsoil drying off during the successive spring surveys.     

Post-Collisional Transition from Subduction- to Intraplate-type Magmatism in the Westernmost Mediterranean: Evidence for Continental-Edge Delamination of Subcontinental Lithosphere

Post-collisional magmatism in the southern Iberian and northwesternAfrican continental margins contains important clues for theunderstanding of a possible causal connection between movementsin the Earth's upper mantle, the uplift of continental lithosphereand the origin of circum-Mediterranean igneous activity. Systematicgeochemical and geochronological studies (major and trace element,Sr–Nd–Pb-isotope analysis and laser ⁴⁰Ar/³⁹Ar-agedating) on igneous rocks provide constraints for understandingthe post-collisional history of the southern Iberian and northwesternAfrican continental margins. Two groups of magmatic rocks canbe distinguished: (1) an Upper Miocene to Lower Pliocene (8·2–4·8Ma), Si–K-rich group including high-K (calc-alkaline)and shoshonitic series rocks; (2) an Upper Miocene to Pleistocene(6·3–0·65 Ma), Si-poor, Na-rich group includingbasanites and alkali basalts to hawaiites and tephrites. Maficsamples from the Si–K-rich group generally show geochemicalaffinities with volcanic rocks from active subduction zones(e.g. Izu–Bonin and Aeolian island arcs), whereas maficsamples from the Si-poor, Na-rich group are geochemically similarto lavas found in intraplate volcanic settings derived fromsub-lithospheric mantle sources (e.g. Canary Islands). The transitionfrom Si-rich (subduction-related) to Si-poor (intraplate-type)magmatism between 6·3 Ma (first alkali basalt) and 4·8Ma (latest shoshonite) can be observed both on a regional scaleand in individual volcanic systems. Si–K-rich and Si-poorigneous rocks from the continental margins of southern Iberiaand northwestern Africa are, respectively, proposed to havebeen derived from metasomatized subcontinental lithosphere andsub-lithospheric mantle that was contaminated with plume material.A three-dimensional geodynamic model for the westernmost Mediterraneanis presented in which subduction of oceanic lithosphere is inferredto have caused continental-edge delamination of subcontinentallithosphere associated with upwelling of plume-contaminatedsub-lithospheric mantle and lithospheric uplift. This processmay operate worldwide in areas where subduction-related andintraplate-type magmatism are spatially and temporally associated. KEY WORDS: post-collisional magmatism; Mediterranean-style back-arc basins; subduction; delamination; uplift of marine gateways     

Origin of Exceptionally Abundant Phonolites on Ua Pou Island (Marquesas, French Polynesia): Partial Melting of Basanites Followed by Crustal Contamination

On the basis of the first systematic mapping of Ua Pou, longknown for its exceptionally abundant phonolites, we estimatethat these rocks cover 65% of the surface of the island whereasmafic lavas cover 27% and intermediate ones 8%. The silica-undersaturatedsuite was erupted in a restricted time span (2·9–2·35Myr), following the emplacement of tholeiites derived from ayoung HIMU-type source at c. 4 Ma. Primitive basanites, derivedfrom a heterogeneous mantle source with a dominant EM II + HIMUsignature, represent likely parental magmas. The series is characterizedby a Daly gap defined by a lack of phonotephrites. We considerthat the most likely model for the origin of evolved lavas ispartial melting at depth of primitive basanites, leaving anamphibole-rich residuum and producing tephriphonolitic magmas.These tephriphonolitic magmas may have evolved by closed-systemfractional crystallization towards Group A phonolites. Threeother groups of phonolites could have been derived from tephriphonoliticmagmas by open-system fractional crystallization processes,characterized respectively by seawater contamination (GroupB), assimilation of nepheline syenite-type materials (GroupC) and extreme fractionation coupled with assimilation of theunderlying oceanic crust (Group D). The prominence of evolvedlavas is a consequence of their origin from partial meltingof mafic precursors followed by crustal contamination. KEY WORDS: Marquesas; French Polynesia; phonolite; partial melting; contamination     

Effects of pressure on aqueous chemical equilibria at subzero temperatures with applications to Europa

Pressure plays a critical role in controlling aqueous geochemical processes in deep oceans and deep ice. The putative ocean of Europa could have pressures of 1200 bars or higher on the seafloor, a pressure not dissimilar to the deepest ocean basin on Earth (the Mariana Trench at 1100 bars of pressure). At such high pressures, chemical thermodynamic relations need to explicitly consider pressure. A number of papers have addressed the role of pressure on equilibrium constants, activity coefficients, and the activity of water. None of these models deal, however, with processes at subzero temperatures, which may be important in cold environments on Earth and other planetary bodies. The objectives of this work were to (1) incorporate a pressure dependence into an existing geochemical model parameterized for subzero temperatures (FREZCHEM), (2) validate the model, and (3) simulate pressure-dependent processes on Europa. As part of objective 1, we examined two models for quantifying the volumetric properties of liquid water at subzero temperatures: one model is based on the measured properties of supercooled water, and the other model is based on the properties of liquid water in equilibrium with ice.The relative effect of pressure on solution properties falls in the order: equilibrium constants(K) > activity coefficients (γ) > activity of water (a_w). The errors (%) in our model associated with these properties, however, fall in the order: γ > K > a_w. The transposition between K and γ is due to a more accurate model for estimating K than for estimating γ. Only activity coefficients are likely to be significantly in error. However, even in this case, the errors are likely to be only in the range of 2 to 5% up to 1000 bars of pressure. Evidence based on the pressure/temperature melting of ice and salt solution densities argue in favor of the equilibrium water model, which depends on extrapolations, for characterizing the properties of liquid water in electrolyte solutions at subzero temperatures, rather than the supercooled water model. Model-derived estimates of mixed salt solution densities and chemical equilibria as a function of pressure are in reasonably good agreement with experimental measurements.To demonstrate the usefulness of this low-temperature, high-pressure model, we examined two hypothetical cases for Europa. Case 1 dealt with the ice cover of Europa, where we asked the question: How far above the putative ocean in the ice layer could we expect to find thermodynamically stable brine pockets that could serve as habitats for life? For a hypothetical nonconvecting 20 km icy shell, this potential life zone only extends 2.8 km into the icy shell before the eutectic is reached. For the case of a nonconvecting icy shell, the cold surface of Europa precludes stable aqueous phases (habitats for life) anywhere near the surface. Case 2 compared chemical equilibria at 1 bar (based on previous work) with a more realistic 1460 bars of pressure at the base of a 100 km Europan ocean. A pressure of 1460 bars, compared to 1 bar, caused a 12 K decrease in the temperature at which ice first formed and a 11 K increase in the temperature at which MgSO₄·12H₂O first formed. Remarkably, there was only a 1.2 K decrease in the eutectic temperatures between 1 and 1460 bars of pressure. Chemical systems and their response to pressure depend, ultimately, on the volumetric properties of individual constituents, which makes every system response highly individualistic.     

Accurate measurement of silver isotopic compositions in geological materials including low Pd/Ag meteorites

Very precise silver (Ag) isotopic compositions have been determined for a number of terrestrial rocks, and high and low Pd/Ag meteorites by utilizing multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). The meteorites include primitive chondrites, the Group IAB iron meteorites Canyon Diablo and Toluca, and the Group IIIAB iron meteorite Grant. Silver isotopic measurements are primarily of interest because ¹⁰⁷Ag was produced by decay of the short-lived radionuclide ¹⁰⁷Pd during the formation of the solar system and hence the Pd-Ag chronometer has set constraints on the timing of early planetesimal formation. A 2σ precision of ±0.05‰ can be obtained for analyses of standard solutions when Ag isotopic ratios are normalized to Pd, to correct for instrumental mass discrimination, and to bracketing standards. Caution must be exercised when making Ag isotopic measurements because isotopic artifacts can be generated in the laboratory and during mass spectrometry. The external reproducibility for geological samples based on replicate analyses of rocks is ±0.2‰ (2σ).All chondrites analyzed have similar Ag isotopic compositions that do not differ significantly (>0.3‰) from the ‘terrestrial’ value of the NIST SRM 978a Ag isotope standard. Hence, they show no evidence of excess ¹⁰⁷Ag derived from ¹⁰⁷Pd decay or, of stable Ag isotope fractionation associated with volatile element depletion within the accretion disk or from parent body metamorphism. The Group IAB iron meteorite samples analyzed show evidence of complex behavior and disturbance of Ag isotope systematics. Therefore, care must be taken when using this group of iron meteorites to obtain chronological information based on the Pd-Ag decay scheme.