Tectonic evolution of the Lachlan Fold Belt, southeastern Australia: constraints from coupled numerical models of crustal deformation and surface erosion driven by subduction of the underlying mantle

We have used a coupled thermo-mechanical finite-element (FE) model of crustal deformation driven by mantle/oceanic subduction to demonstrate that the tectonic evolution of the Lachlan Fold Belt (LFB) during the Mid-Palaeozoic (Late Ordovician to Early Carboniferous) can be linked to continuous subduction along a single subduction zone. This contrasts with most models proposed to date which assume that separate subduction zones were active beneath the western, central and eastern sections of the Lachlan Orogen. We demonstrate how the existing data on the structural, volcanic and erosional evolution of the Lachlan Fold Belt can be accounted for by our model. We focus particularly on the timing of fault movement in the various sectors of the orogen. We demonstrate that the presence of the weak basal decollement on which most of the Lachlan Fold Belt is constructed effectively decouples crustal structures from those in the underlying mantle. The patterns of faulting in the upper crust appears therefore to be controlled by lateral strength contrasts inherited from previous orogenic events rather than the location of one or several subduction zones. The model also predicts that the uplift and deep exhumation of the Wagga-Omeo Metamorphic Belt (WOMB) is associated with the advection of this terrane above the subduction point and is the only tectonic event that gives us direct constraints on the location of the subduction zone. We also discuss the implications of our model for the nature of the basement underlying the present-day orogen.     

Kamafugitic diatremes: their textures and field relationships with examples from the Goiás alkaline province, Brazil

Kamafugitic rocks intruded the Precambrian basement and Phanerozoic sediments at the northeast border of the Paraná basin as part of the Late Cretaceous Goiás alkaline province (GAP). Plutonic complexes dominate the north of the province, whereas lavas and pyroclastic rocks prevail in the south. The central GAP is characterized by kamafugitic diatremes, which may crop out continuously for up to 850 m and consist of a central breccia body, surrounded and overlain by lava flows and crosscut by dykes. The breccias contain some special spheroidal juvenile fragments—namely, accretionary and armored lapilli, frozen droplets, spinning droplets, and wrapped fragments—whose textural and mineralogical aspects are described in detail. Irregularly shaped tuff pockets that occur within the breccias contain textures and structures similar to those of subaerial surge deposits and formed in confined, high gas to solid+liquid ratio domains in the conduit. Diatreme emplacement affected the country rock through thermal metamorphism, development of columnar jointing, and formation of peperite-like mixtures. There is no evidence of phreatomagmatic activity in the diatremes, and CO₂, rather than H₂O, seems to have been the major volatile component of the kamafugitic magmas. This finding implies that features such as accretionary lapilli and peperites are not exclusively associated with H₂O-dominated processes.     

The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.     

Provenance of Holocene beach sand in the Western Iberian margin: the use of the Kolmogorov–Smirnov test for the deciphering of sediment recycling in a modern coastal system

Detrital zircons from Holocene beach sand and igneous zircons from the Cretaceous syenite forming Cape Sines (Western Iberian margin) were dated using laser ablation – inductively coupled plasma – mass spectrometry. The U–Pb ages obtained were used for comparison with previous radiometric data from Carboniferous greywacke, Pliocene–Pleistocene sand and Cretaceous syenite forming the sea cliff at Cape Sines and the contiguous coast. New U–Pb dating of igneous morphologically simple and complex zircons from the syenite of the Sines pluton suggests that the history of zircon crystallization was more extensive (ca 87 to 74 Ma), in contrast to the findings of previous geochronology studies (ca 76 to 74 Ma). The U–Pb ages obtained in Holocene sand revealed a wide interval, ranging from the Cretaceous to the Archean, with predominance of Cretaceous (37%), Palaeozoic (35%) and Neoproterozoic (19%) detrital‐zircon ages. The paucity of round to sub‐rounded grains seems to indicate a short transportation history for most of the Cretaceous zircons (ca 95 to 73 Ma) which are more abundant in the beach sand that was sampled south of Cape Sines. Comparative analysis using the Kolmogorov–Smirnov statistical method, analysing sub‐populations separately, suggests that the zircon populations of the Carboniferous and Cretaceous rocks forming the sea cliff were reproduced faithfully in Quaternary sand, indicating sediment recycling. The similarity of the pre‐Cretaceous ages (>ca 280 Ma) of detrital zircons found in Holocene sand, as compared with Carboniferous greywacke and Pliocene–Pleistocene sand, provides support for the hypothesis that detritus was reworked into the beach from older sedimentary rocks exposed along the sea cliff. The largest percentage of Cretaceous zircons (<ca 95 Ma) found in Holocene sand, as compared with Pliocene–Pleistocene sand (secondary recycled source), suggests that the Sines pluton was the one of the primary sources that became progressively more exposed to erosion during Quaternary uplift. This work highlights the application of the Kolmogorov–Smirnov method in comparison of zircon age populations used to identify provenance and sediment recycling in modern and ancient detrital sedimentary sequences.     

Biosorption with autochthonous and allochthonous fungal biomasses for bioremediation and detoxification of landfill leachate

Landfill leachates are not adequately treated in traditional wastewater treatment plants, on account of their problematic peculiarities: i.e., dark colour, high concentration of recalcitrant pollutants and COD, and high toxicity. In this work, 19 biomasses (15 autochthonous and 4 allochthonous) were exploited in biosorption treatment for the remediation of a leachate (influent) and the effluent coming from the biological oxidation with activated sludge and nitrification–denitrification treatment. The effects of the initial pH, the biomass amount, and the medium for the biomass pre-culture were considered. The best configuration was: pH 5, 5 g L^??1 biomass cultivated on STY medium. Eventually, the two most effective biomasses, Cunninghamella bertholletiae MUT 2861 and Aspergillus fumigatus MUT 4050, were used in consecutive 2 h cycles in a batch biosorption experiment. The effectiveness of the treatment decreased in subsequent cycles in terms of decolourisation (31–15%). COD, Cl^?, SO₄^2?, total N, and toxicity were removed mainly in the second cycle of treatment (up to ??36, ??12, ??15, ??17 and ??49%, respectively). The results suggest that the effluent toxicity was basically due to uncoloured substances, which were mainly removed after coloured molecules.     

A spatiotemporal calculus for reasoning about land-use trajectories

Earth observation images are a powerful source of data about changes in our planet. Given the magnitude of global environmental changes taking place, it is important that Earth Science researchers have access to spatiotemporal reasoning tools. One area of particular interest is land-use change. Using data obtained from images, researchers would like to express abstractions such as ‘land abandonment’, ‘forest regrowth’, and ‘agricultural intensification’. These abstractions are specific types of land-use trajectories, defined as multi-year paths from one land cover into another. Given this need, this paper introduces a spatiotemporal calculus for reasoning about land-use trajectories. Using Allen’s interval logic as a basis, we introduce new predicates that express cases of recurrence, conversion and evolution in land-use change. The proposed predicates are sufficient and necessary to express different kinds of land-use trajectories. Users can build expressions that describe how humans modify Earth’s terrestrial surface. In this way, scientists can better understand the environmental and economic effects of land-use change.     

On-the-fly server-based aerial imagery management system

Aerial images are valuable products when dealing with both geospatial and geotemporal analysis. Nowadays, they are widely used for many different purposes and by an extensive public, including private companies, official administrations and individual users. Although in the past few years there has been an increasing interest in showing all kinds of geographical information on the World Wide Web, access to aerial imagery and its dissemination are still difficult and lack flexibility. This paper introduces an aerial imagery management system based on client–server principles, operated so as to allow users quick and efficient queries, processing and management of huge sets of photogrammetric imagery stored on raster servers. It is a novel product that is ready to provide image-based cartographic data available in public and private digital warehouses, facilitating all the required visualisations and queries, as well as geometric and radiometric processing on the fly. This paper shows the design, system architecture and various functionalities of the system in a real-life scenario.     

Use of immunofluorescence technique in cultured fibroblasts from Mediterranean cetaceans as new "in vitro" tool to investigate effects of environmental contaminants

The aim of the present study was to propose the immunofluorescence technique in cultured fibroblasts from Mediterranean cetaceans as a new "in vitro" tool to explore the susceptibility of these marine mammals to different xenobiotic compounds. The cell lines were cultured from integument biopsies of free-ranging and stranded cetaceans (dead within 12h). Using the indirect immunofluorescence assay, we detected endogenous proteins induced by different contaminants. Here we present the method used for qualitative and quantitative evaluation of cytochromes P450 (CYP1A1 and CYP2B) induced by some POPs (DDTs and PCBs) and emerging contaminants (PBDEs) in fibroblast cell cultures of striped dolphin (Stenella coeruleoalba) and bottlenose dolphin (Tursiops truncatus). Immunofluorescence was quantified with a specially designed Olympus macro, DetectIntZ. A major result was the possibility of using this "in vitro" assay to quantify induction of endogenous proteins.