Space weathering of small Koronis family members

The space weathering process and its implications for the relationships between S- and Q-type asteroids and ordinary chondrite meteorites is an often debated topic in asteroid science. Q-type asteroids have been shown to display the best spectral match to ordinary chondrites (McFadden, L.A., Gaffey, M.J., McCord, T.B. [1985]. Science 229, 160–163). While the Q-types and ordinary chondrites share some spectral features with S-type asteroids, the S-types have significantly redder spectral slopes than the Q-types in visible and near-infrared wavelengths. This reddening of spectral slope is attributed to the effects of space weathering on the observed surface composition. The analysis by Binzel et al. (Binzel, R.P., Rivkin, A.S., Stuart, J.S., Harris, A.W., Bus, S.J., Burbine, T.H. [2004]. Icarus 170, 259–294) provided a missing link between the Q- and S-type bodies in near-Earth space by showing a reddening of spectral slope in objects from 0.1 to 5 km that corresponded to a transition from Q-type to S-type asteroid spectra, implying that size, and therefore surface age, is related to the relationship between S- and Q-types. The existence of Q-type asteroids in the main-belt was not confirmed until Mothé-Diniz and Nesvorny (Mothé-Diniz, T., Nesvorny, D. [2008]. Astron. Astrophys. 486, L9–L12) found them in young S-type clusters. The young age of these families suggest that the unweathered surface could date to the formation of the family. This leads to the question of whether older S-type main-belt families can contain Q-type objects and display evidence of a transition from Q- to S-type. To answer this question we have carried out a photometric survey of the Koronis family using the Kitt Peak 2.1 m telescope. This provides a unique opportunity to compare the effects of the space weathering process on potentially ordinary chondrite-like bodies within a population of identical initial conditions. We find a trend in spectral slope for objects 1–5 km that shows the transition from Q- to S-type in the main-belt. This data set will prove crucial to our understanding of the space weathering process and its relevant timescales.     

Soft x-ray emitting regions in the solar corona

The soft X-ray emission of the solar corona is investigated by comparison of the signals of several broad band photometers carried on the Solrad 9 satellite, and sensitive to the region 0.5–20 Å. Temperature from 1.5 × 10⁶ to 25 × 10⁶ K have been measured with emission measure N _e ² dV ranging between 10⁵⁰ cm^–3 to 10⁴⁷ cm^–3.By means of the observational data and assuming magnetic confinement and hydrostatic equilibrium, the model of an active region is investigated. For temperatures larger than 10⁷K the emission is due to flare activity and two sets of emission measure are observed which appear to be related to the evolution of flares.     

Geochemical evidence of the 8.2 ka event and other Holocene environmental changes recorded in paleolagoon sediments,southeastern Brazil

The paleoclimatic record of Juréia Paleolagoon, coastal southeastern Brazil, includes cyclic and gradual changes with different intensities and frequencies through geological time, and it is controlled by astronomical, geophysical, and geological phenomena. These variations are not due to one single cause, but they result from the interaction of several factors, which act at different temporal and spatial scales. Here, we describe paleoenvironmental evidence regarding climatic and sea level changes from the last 9400 cal yr BP at the Juréia Paleolagoon — one of the main groups of protected South Atlantic ecosystems. Geochemical evidences were used to identify anomalies from multi-proxy analyses of a paleolagoon sediment core. The anomalies of centennial scale were correlated to climate and transgression–regression cycles from the Holocene period. Decadal scale anomalous oscillations in the Quaternary paleolagoon sediments occur between 9400 and 7500 cal yr BP, correlated with long- and short-term natural events, which generated high sedimentation rates, mainly between 8385 and 8375 cal yr BP (10 cm/yr). Our results suggest that a modern-day short-duration North Atlantic climatic event, such as the 8.2 ka event, could affect the environmental equilibrium in South America and intensify the South American Summer Monsoon.     

Paleoweathering features in the Sergi Formation (Jurassic-Cretaceous), northeastern Brazil,and implications for hydrocarbon exploration

Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).     

Pliocene and late Pleistocene (MIS 5e) decapod crustaceans from Santa Maria Island (Azores Archipelago: Central Atlantic): systematics,palaeoecology and palaeobiogeography

The presence of decapod crustaceans in the Pliocene and Pleistocene (MIS 5e) fossil record of Santa Maria Island (Azores Archipelago) is herein reviewed. Our study raises the number of fossil decapods from this island from one species to 10 taxa (three for the Pliocene and seven for the Last Interglacial). Four of these 10 taxa are reported for the first time in the fossil record, worldwide. A new species of a mud shrimp is also described (Upogebia azorensis n. sp.). Our study suggests that the Plio–Pleistocene decapod assemblages of the Azores did not differ significantly from modern ones, being dominated by species that are today widespread across the Webbnesia ecoregion, the Mediterranean Sea, and the eastern Atlantic shores, including the Azores. As far as can be judged from the limited fossil record, apparently no tropical crab species with a Cabo Verdean/Senegalese provenance reached the Azores during windows of opportunity associated with Glacial Termination 2 or with the initial setting of the Last Interglacial period. This contribution increases the total number of marine taxa reported for the Pliocene and Pleistocene outcrops of Santa Maria Island to 218 and 155, respectively, highlighting the scientific relevance of its palaeontological heritage.     

Weakening climatic signal since mid-20th century in European larch tree-ring chronologies at different altitudes from the Adamello-Presanella Massif (Italian Alps)

Tree rings from temperature-limited environments are highly sensitive climate proxies, widely used to reconstruct past climate parameters for periods prior to the availability of instrumental data and to analyse the effect of recent global warming on tree growth. An analysis of the climatic signal in five high-elevation tree-ring width chronologies of European larch (Larix decidua Mill.) from the tops of five different glacial valleys in the Italian Central Alps revealed that they contain a strong summer-temperature signal and that tree-ring growth is especially influenced by June temperatures. However, a moving correlation function analysis revealed a recent loss of the June temperature signal in the tree-ring chronologies. This signal reduction primarily involves the two lowest-altitude chronologies. It is probable that the observed increasing importance of late-summer temperature for tree-ring growth over the past 50 yr is an effect of the lengthening growing season and of the variations in the climate/tree-ring relationship over time. All the chronologies considered, especially those at the highest altitudes, show an increasing negative influence of June precipitation on tree-ring growth. The climatic signal recorded in tree-ring chronologies from the Italian Central Alps varies over time and is also differentially influenced by climatic parameters according to site elevation.     

Surveying the Townscape of Roman Ammaia in Portugal: An Integrated Geoarchaeological Investigation of the Forum Area

Geoarchaeological research, integrating traditional excavations, and ground truthing with intensive geophysical surveys, aerial photography, and GIS‐based data processing, has revealed the full intramural plan of the abandoned Roman city of Ammaia in central Portugal. Although this multidisciplinary effort also focussed on understanding the town/territory relationships and the system of resource exploitation, this paper presents the most important results from fieldwork in the central monumental area of the town, the Roman Forum. Here, excavations, geomorphological survey, and an array of geophysical methods illuminate the long history of the site, from the first settlement and monument‐building phases in early Imperial times, to the ongoing post‐abandonment processes. This paper discusses some of the benefits of compiling these complementary data sets and proposes the use of a wide array of approaches in order to achieve full understanding of the complex topography and evolution of a classical urban site. It further demonstrates the need for effective stratigraphical control and geomorphological analysis of crucial areas revealed by high‐quality geophysics.     

On the OH initiated oxidation of C2-C5 aliphatic aldehydes in the presence of mineral aerosols

Clay particles are present in large quantities in mineral dust of atmospheric aerosols, and their interaction with organic species may influence atmospheric reactions and the prediction of environmental risks. However, the kinetics and mechanisms of adsorption and reaction of atmospheric volatile organic compounds on aerosol surfaces are not well understood.In this work, quantum chemical methods are used to study the adsorption of C2-C5 aliphatic aldehydes on silicate clusters active sites, and their subsequent reaction with OH radicals. It is shown that adsorption may occur in two different ways, and that the adsorption complex structure determines the subsequent path of its reaction with OH. The initial step in the OH reaction with acetaldehyde occurs according to the same mechanism as in the gas phase, i.e., the aldehydic hydrogen abstraction. Starting from propanal, another abstraction channel becomes increasingly important, involving mainly the abstraction of a β-hydrogen of the aliphatic chain. In the presence of a silica monomer model surface, the reaction rate of aldehydes with OH free-radicals is smaller than in the gas phase. Furthermore silicates are good sinks for trapping these aldehydes. Thus, our results may have implications in the study of tropospheric chemistry and cosmochemistry.