Systematics of the spinel structure type

Systematic trends in the geometry of 149 oxide and 80 sulfide binary and ternary spinels have been examined from the standpoint of ionic radius and electronegativity. The mean ionic radii of the octahedral and tetrahedral cations, taken together, account for 96.9 and 90.5% of the variation in the unit cell parameter, a, of the oxides and sulfides, respectively, with the octahedral cation exerting by far the dominant influence in sulfides. The mean electronegativity of the octahedral cation exerts an additional, but small, influence on the cell edge of the sulfides. The equation a=(8/3√d)d _tet+(8/3)d _oct, where d _tet and d _oct are the tetrahedral and octahedral bond lengths obained from the sum of the ionic radii, accounts for 96.7 and 83.2% of the variation in a in the oxides and sulfides, respectively, again testifying to the applicability of the hard-sphere ionic model in the case of the spinel structure. Comparison of observed and calculated u values for 94 spinels indicates that up to 40% of the experimentally measured anion coordinates may be significantly in error. In addition to these compounds, u values are given for 52 spinels for which no data have previously been determined. Diagrams are presented for the rapid interpretation of the internal consistency of published data and the prediction of the structural parameters of hypothetical or partially studied spinels.     

Retraction: Evaluation of Co‐Digestion at a Commercial Dairy Anaerobic Digester

The above article published online on 16 June 2011 in Wiley Online Library ( http://www.onlinelibrary.wiley.com ), and in Volume 39, pp. 697‐704, has been retracted by agreement between the Editor‐in‐Chief, Prisca Henheik, and Wiley‐VCH Verlag GmbH & Co. KgaA. The retraction has been agreed following an investigation carried out by Washington State University (WSU) which determined that research misconduct had occurred with respect to fabricating experimental data and falsifying data that formed the basis of a section of this article on the part of the corresponding author. Furthermore, WSU determined that the corresponding author did not declare an existing commercial conflict of interest when submitting the paper to the peer‐‐reviewed journal CLEAN ‐ Soil, Air, Water.     

Groundwater-level response to land-use change and the implications for salinity management in the West Moorabool River catchment, Victoria, Australia

The connection between the removal of native vegetation, rising water tables and increasing stream salinity has been established for many catchments across Australia. However, the West Moorabool River in south west Victoria is an example of a catchment where there has been little discernable effect on groundwater levels following land clearing. Over the past 150 years, a significant portion of the catchment has been cleared of dense forest for agricultural development. Historic standing water-level records from 1870–1871 and 1881 are compared with contemporary measurements (1970s to 2007) recorded in the government bore databases. The data show that the earliest recorded groundwater levels are well within the seasonal range of values observed today. By integrating geology and hydrogeology with historical observations of groundwater levels, climate data and land use, the contemporary field observations of stream salinity are linked to the changed water use and shift in rainfall. In contrast to the normally accepted axiom, reafforestation as a management strategy to mitigate the rising salinity in the West Moorabool River catchment would seem inappropriate.     

The evolution of the terrestrial-terminating Irish Sea glacier during the last glaciation

Here we reconstruct the last advance to maximum limits and retreat of the Irish Sea Glacier (ISG), the only land-terminating ice lobe of the western British Irish Ice Sheet. A series of reverse bedrock slopes rendered proglacial lakes endemic, forming time-transgressive moraine- and bedrock-dammed basins that evolved with ice marginal retreat. Combining, for the first time on glacial sediments, optically stimulated luminescence (OSL) bleaching profiles for cobbles with single grain and small aliquot OSL measurements on sands, has produced a coherent chronology from these heterogeneously bleached samples. This chronology constrains what is globally an early build-up of ice during late Marine Isotope Stage 3 and Greenland Stadial (GS) 5, with ice margins reaching south Lancashire by 30 ± 1.2 ka, followed by a 120-km advance at 28.3 ± 1.4 ka reaching its 26.5 ± 1.1 ka maximum extent during GS-3. Early retreat during GS-3 reflects piracy of ice sources shared with the Irish-Sea Ice Stream (ISIS), starving the ISG. With ISG retreat, an opportunistic readvance of Welsh ice during GS-2 rode over the ISG moraines occupying the space vacated, with ice margins oscillating within a substantial glacial over-deepening. Our geomorphological chronosequence shows a glacial system forced by climate but mediated by piracy of ice sources shared with the ISIS, changing flow regimes and fronting environments.     

Falling sphere observations of anisotropic gravity wave motions in the upper stratosphere over Australia

A study of inertial scale gravity wave motions in the region of the atmosphere between 30 and 60 km has been undertaken, using wind and temperature data derived from rocket-borne falling sphere density experiments performed over Woomera, Australia between 1962 nad 1976. The gross features of the wave field compare favorably with those found in similar northern hemispheric studies. Wave propagation is found to be both vertically and horizontally anisotropic. A rotary spectral analysis indicates predominately upgoing wave energy, suggesting that the majority of sources of these waves lie below 30 km. A detailed statistical investigation of the waves, made using the Stokes parameters technique, reveals that phase progression is also highly directional in the horizontal, with a significant zonal component in summer, but with a strong meridional component in winter. Propagation towards the southeast is inferred in summer, with the waves possibly emanating from tropospheric sources in equatorial regions to the north of Australia. The technique also shows that, on average, the waves appear to have mean ellipse eccentricities (=f/) around 0.4–0.45. Indirect estimates of a number of important wave parameters are made. In particular,v andw flux estimates are made over several height intervals. The vertical gradient of density weighted flux implies wave-induced mean flow accelerations of the order 0.1–1 ms^–1day^–1. This suggests that dissipating gravity waves are a significant source of the momentum residuals that are encountered in studies of satellite data from this region.     

The Miocene of Carriacou,the Grenadines,Lesser Antilles

Carriacou is one of the small islands in the Grenadine chain in the southern Lesser Antilles. It preserves two Miocene successions, that on the south coast shallowing upwards and separated by a probable fault from the extensively exposed turbidite sequence, called the Grand Bay Formation, on the east coast. These formations show a range of features beautifully exposed in coastal sections, including unconformities, turbidites and a starfish bed.     

Detection of subsurface archaeological architecture by computer assisted airphoto interpretation

Computer-assisted enhancement of scanned historical airphotos demonstrates successful detection and mapping of subsurface archaeological features. Results show a locally adaptive contrast enhancement filter produced the best resolution of lineaments. Such enhancements can enable reconstruction of protohistoric architecture despite modern construction. The city-state of Idalion is used here as a case study to demonstrate enhancement. Results are confirmed by excavation of Idalion architecture. Idalion was a thriving metropolis during Cypro-Archaic to Roman times, surrounded by a 9.6 km defensive wall. The area within may still contain significant amounts of unmapped architecture. Some of this architecture was mapped previously from aerial photographs using manual interpretation techniques, but never excavated as proof of detection. Guided by enhanced imagery, our excavations confirmed the location of five towers/bastions along the city wall. Enhanced airphotos also revealed a region disturbed by contemporary construction of a water pipeline. Such information is important to archaeologists planning digs, and can be acquired using standard digital image processing techniques. © 1999 John Wiley & Sons, Inc.     

Mechanical shredding of water hyacinth (<Emphasis Type="Italic">Eichhornia crassipes</Emphasis>): Effects on water quality in the Sacramento-San Joaquin River Delta,California

Management actions to control invasive aquatic species can have significant ecosystem-scale effects. We evaluated the water chemistry and nutrient effects of mechanical shredding to control water hyacinth (Eichhornia crassipes) in an agricultural slough and a tidal wetland on the Sacramento-San Joaquin River Delta, California. Shredding was conducted with two types of shredder boats in fall of 2003 and another boat in spring of 2004. Shredding measurably affected water quality, but specific effects varied as a function of shredding site and season. Significant increases were observed for total Kjeldahl nitrogen and total phosphorus for all experiments. Dissolved oxygen effects varied by site, decreasing after shredding at the agricultural slough but increasing at the tidal wetland. The increase in dissolved oxygen likely resulted from tidal incursions from the adjacent river. A year-long time series of dissolved oxygen data indicated a negative relationship between hyacinth abundance and dissolved oxygen concentrations. Hyacinth contained similar tissue concentrations of mercury to underlying sediments, suggesting that plant harvesting could aid mercury remediation efforts. Simple mass calculations indicated that Delta-wide shredding operations could cause between 0.1% and 9.6% increases in the overall abundance of carbon, nitrogen, and phosphorus in the Delta water column. Results suggest that local effects of management actions to control invasive aquatic plants will vary widely as a function of site-specific hydrology, but that estuary-wide effects would be limited.