Degradation of carbohydrates and lignins in buried woods

Spruce, alder, and oak woods deposited in coastal sediments were characterized versus their modern counterparts by quantification of individual neutral sugars and lignin-derived phenols as well as by scanning electron microscopy, ¹³C NMR, and elemental analysis. The buried spruce wood from a 2500 yr old deposit was unaltered whereas an alder wood from the same horizon and an oak wood from an open ocean sediment were profoundly degraded. Individual sugar and lignin phenol analyses indicate that at least 90 and 98 wt% of the initial total polysaccharides in the buried alder and oak woods, respectively, have been degraded along with 15–25 wt% of the lignin. At least 75% of the degraded biopolymer has been physically lost from these samples. This evidence is supported by the SEM, ¹³C NMR and elemental analyses, all of which indicate selective loss of the carbohydrate moiety. The following order of stability was observed for the major biochemical constituents of both buried hardwoods: vanillyl and $\text{p-}\text{hydroxyl}$ lignin structural units > syringyl lignin structural units > pectin > α-cellulose > hemicellulose. This sequence can be explained by selective preservation of the compound middle lamella regions of the wood cell walls. The magnitude and selectivity of the indicated diagenetic reactions are sufficient to cause major changes in the chemical compositions of wood-rich sedimentary organic mixtures and to provide a potentially large in situ nutrient source.     

The Precambrian—Cambrian boundary: A symposium

Contributions to a symposium of the IUGS Subcommission on Cambrian Stratigraphy at the International Geological Congress in Montreal in 1972 are the basis of this paper which is intended to give guidance to further work of what is now a Working Group on the Precambrian—Cambrian boundary of the International Geological Correlation Programme (UNESCO/IUGS). The proposed principles for the definition of the boundary are based on those accepted by the Commission on Stratigraphy, particularly on stratigraphic classification and on defining the Silurian—Devonian boundary. These matters are discussed by the authors in general terms and by W.B. Harland in terms of procedure. They are illustrated by examples of stratigraphic sequences across the boundary in Siberia given by A.Yu. Rozanov and discussed critically by V.E. Savitsky. New relevant discoveries of Early Cambrian faunas and their stratigraphic setting are reviewed by A. Boudda et al. P.E. Cloud's contribution, published elsewhere, and work in Australia are reviewed by the authors.The conclusions, based not only on the symposium material but also on current opinion, are that no single sequence which could serve as a reference standard for the Precambrian—Cambrian boundary has yet been identified but that many significant ones have been described which will be further examined. While the general limits for the choice of a boundary definition should lie between the horizons with fossils of Ediacaran type and those with diversified trilobite assemblages, a number of “Working Reference Points” exist in that interval which are correlatable horizons of faunal change. These cannot be defined simply as horizons of first appearance.     

Effects of hydrologic variability and remedial actions on first flush and metal loading from streams draining the Silverton caldera, 1992–2014

This study examined water quality in the upper Animas River watershed, a mined watershed that gained notoriety following the 2015 Gold King mine release of acid mine drainage to downstream communities. Water-quality data were used to evaluate trends in metal concentrations and loads over a two-decade period. Selected sites included three sites on tributary streams and one main-stem site on the Animas River downstream from the tributary confluences. During the study period, metal concentrations and loads varied seasonally and annually because of hydrologic variability and remedial actions designed to ameliorate the effects of acid mine drainage. Water-quality data were divided into two periods based on the timing of remedial activities in the watershed. The first period includes active water treatment, surface reclamation and installation of bulkheads in adits; the second period includes the decade following these activities. Water-quality data were used to estimate annual and monthly zinc loads using the Adjusted Maximum Likelihood Method (using LOADEST software) and U.S. Geological Survey streamflow data. This study presents one of the first applications of LOADEST focused on metal loads. Monthly flow-weighted concentrations were analysed using a Mann-Kendall trend test to determine the direction, magnitude, and significance of temporal trends in zinc loading in any given month and using t-test comparisons between the two periods. Zinc loads estimated for the Animas River below the tributaries indicate decreased zinc loading during the rising limb of the hydrograph in the second period, perhaps reflecting a reduction of snowmelt-derived zinc load following surface reclamation activities. In contrast, base-flow zinc loading increased at the main-stem site, perhaps because of the cessation of water treatment in tributary streams. Flow weighting of monthly load estimates yielded increased statistical significance and enabled more nuanced differentiation between the effects of hydrologic variability and remedial activities on zinc loading.     

Damage zone and slip-surface evolution over μm to km scales in high-porosity Navajo sandstone, Utah

Detailed mapping of throw variations and deformation along two km-scale normal faults in the high-porosity Navajo sandstone, Utah, has been used to investigate fault growth in this lithology. The faults consist of one or more through-going, striated, slip-surfaces, accommodating the greater part of the offset surrounded by a damage zone consisting of deformation band clusters and short, unconnected slip-surfaces. In contrast to previous models for deformation in this lithology, we find that the nucleation of slip-surfaces begins where measurable throw is negligible and deformation bands are forming and increasing in number. The microstructure and porosity of deformation bands and slip surfaces are distinct and independent of the amount of offset that they accommodate, i.e. they represent different and yet contemporaneous deformation mechanisms. The point where measurable throw begins to accumulate (the fault tip) is marked by the first through-going connected slip-surface. Increase in throw towards the centre of the fault results in a three-dimensional strain field, producing orthorhombic structural geometries within the damage zone. We find that the total width of the damage zone increases as offset is accumulated. For these faults, the damage zone width is approximately 2.5 times the total fault throw.     

Environmental and socioeconomic dynamics of the Indian Ocean tsunami in Penang,Malaysia

This paper addresses some of the environmental and socioeconomic dimensions of the 2004 Indian Ocean tsunami on Penang, Malaysia. We aim to offer wide access to unique and perishable data, while at the same time providing insight to ongoing debates about hazards, vulnerability and social capital. Our social survey examines some of the dynamics that shaped the tsunami impact, response and recovery process. While in terms of lives lost Penang may not conform to arguments surrounding vulnerable environments, the recovery process is more marked by social disparities in terms of the ability to access resources. Our physical survey records local topography, flow depth and flow direction, and charts the differential impact of the tsunami. Yet measuring hazards is not a straightforward process, and relies on reflexive methodologies and eyewitness accounts.     

Decoding temporal and spatial patterns of fault uplift using transient river long profiles

We present detailed observations of rivers crossing active normal faults in the Central Apennines, Italy, where excellent constraints exist on the temporal and spatial history of fault movement. We demonstrate that rivers with drainage areas > 10 km² and crossing faults that have undergone an increase in throw rate within the last 1 My, have significant long-profile convexities. In contrast, channels that cross faults that have had a constant-slip rate for 3 My have concave-up profiles and have similar concavities and steepness indices to rivers that do not cross any active fault structures. This trend is consistent across the Central Apennines and cannot be explained by appeal to lithology or regional base level change. The data challenge the belief that active faulting must always be reflected in river profiles; instead, the long-profile convexities are best explained as a transient response of the river system to a change in tectonic uplift rate. Moreover, for these rivers we demonstrate that the height of the profile convexity, as measured from the fault, scales with the magnitude of the uplift rate increase on the fault; and we establish that this relationship holds for throw rate variation along strike for the same fault segment, as well as between faults. These findings are shown to be consistent with predictions of channel response to changing uplift rate rates using a detachment-limited fluvial erosion model, and they illustrate that analysis of the magnitude of profile convexities has considerable predictive potential for extracting tectonic information. We also demonstrate that the migration rate of the profile convexities varies from 1.5–10 mm/y, and is a function of the slip rate increase as well as the drainage area. This is consistent with n > 1 for the slope exponent in a classical detachment-limited stream-power erosion law, but could potentially be explained by incorporating an erosion threshold or an explicit role for sediment in enhancing erosion rates. Finally, we show that for rivers in extensional settings, where the response times to tectonic perturbation are long (in this case > 1 My), attempts to extract tectonic uplift rates from normalised steepness indices are likely to be flawed because topographic steady state has not yet been achieved.     

Carbon dynamics of paper,engineered wood products and bamboo in landfills: evidence from reactor studies

Background

There has been growing interest in the development of waste-specific decay factors for estimation of greenhouse gas emissions from landfills in national greenhouse gas inventories. Although engineered wood products (EWPs) and paper represent a substantial component of the solid waste stream, there is limited information available on their carbon dynamics in landfills. The objective of this study was to determine the extent of carbon loss for EWPs and paper products commonly used in Australia. Experiments were conducted under laboratory conditions designed to simulate optimal anaerobic biodegradation in a landfill.

Results

Methane generation rates over incubations of 307–677 days ranged from zero for medium-density fibreboard (MDF) to 326 mL CH₄ g^?1 for copy paper. Carbon losses for particleboard and MDF ranged from 0.7 to 1.6%, consistent with previous estimates. Carbon loss for the exterior wall panel product (2.8%) was consistent with the expected value for blackbutt, the main wood type used in its manufacture. Carbon loss for bamboo (11.4%) was significantly higher than for EWPs. Carbon losses for the three types of copy paper tested ranged from 72.4 to 82.5%, and were significantly higher than for cardboard (27.3–43.8%). Cardboard that had been buried in landfill for 20 years had a carbon loss of 27.3%—indicating that environmental conditions in the landfill did not support complete decomposition of the available carbon. Thus carbon losses for paper products as measured in bioreactors clearly overestimate those in actual landfills. Carbon losses, as estimated by gas generation, were on average lower than those derived by mass balance. The low carbon loss for particleboard and MDF is consistent with carbon loss for Australian wood types described in previous studies. A factor for carbon loss for combined EWPs and wood in landfills in Australia of 1.3% and for paper of 48% is proposed.

Conclusions

The new suggested combined decay factor for wood and EWPs represents a significant reduction from the current factor used in the Australian greenhouse gas inventory; whereas the suggested decay factor for paper is similar to the current decay factor. Our results improve current understanding of the carbon dynamics of harvested wood products, and allow more refined estimates of methane emissions from landfills.

     

Temporal variations in the fractal properties of seismicity in the North Anatolian Fault Zone between 31°E and 41°E

We investigate the nature of temporal variations in the statistical properties of seismicity associated with the North Anatolian Fault Zone between longitudes 31°–41°E during the instrumental period 1900–1992. Temporal variations in the seismicb value and the fractal (correlation) dimensionD _c of earthquake epicenters are examined for earthquakes of magnitudeM _S 4.5, using sliding windows of 100 consecutive events.b varies temporally between 0.6 and 1.0, andD _c between 0.6 and 1.4, both representing significant fluctuations above the errors in measurement technique. A strong negative correlation (r=–0.85) is observed betweenb andD _c , consistent with previous observation of seismicity in Japan and southern California. Major events early in this century (M _S 7) are associated with lowb and highD _c , respectively consistent with greater stress intensity and greater spatial clustering of epicenters—both implying a greater degree of stress concentration at this time.