Dating Gondwanan continental crust at the Rio Grande Rise,South Atlantic

Crystalline continental rocks and associated crust‐contaminated basaltic rocks were unexpectedly dredged on the crest and at seamounts of the Rio Grande Rise, South Atlantic. Zircon U–Pb ages of one gabbro (ca. 2,200 Ma) and four granitoids (between ca. 1,430–480 Ma) indicate that the breakup of SW Gondwana left behind continental fragments of dominantly African age. These rocks may have been incorporated into the oceanic lithosphere by complex processes including rifting and interaction of the Tristan‐Gough mantle plume with hyperextended continental margins. Until ca. 80–70 Ma, the Rio Grande Rise and an old portion of the Walvis Ridge formed a conjugate pair of aseismic ridges, and the Tristan‐Gough plume was positioned at the Mid‐Atlantic Ridge. The finding of continental rock fragments in one of these conjugate pairs opens new perspectives on the mechanisms of continental break‐up, the nature of this conjugate pair, and the geodynamic evolution of rifted Gondwana margins in the South Atlantic.     

NGC 6404 and 6583: two neglected intermediate-age open clusters located in the Galactic Centre direction

We report on VI charge-coupled device photometry of two fields centred in the region of the open clusters NGC 6404 and 6583 down to   V = 22.0  . So far these clusters have never been studied, and we provide for the first time estimates of their fundamental parameters, namely, radial extent, age, distance and reddening. We find that the radius of NGC 6404 is 2.0 arcmin, as previously proposed, while the radius of NGC 6583 is 1.0 arcmin, significantly lower than previous estimates. Both clusters turn out to be of intermediate age (0.5–1.0 Gyr old), and located inside the solar ring, at a Galactocentric distance of about 6.5 kpc. These results make these objects very interesting targets for spectroscopic follow-up to measure their metallicity. In fact, they might allow us to enlarge by more than 1 kpc the baseline of the radial abundance gradient in the Galactic disc towards the Galactic Centre direction. This baseline is currently rather narrow especially for clusters of this age.     

High-Frequency Response of the Atmospheric Electric Potential Gradient Under Strong and Dry Boundary-Layer Convection

The spectral response of atmospheric electric potential gradient gives important information about phenomena affecting this gradient at characteristic time scales ranging from years (e.g., solar modulation) to fractions of a second (e.g., turbulence). While long-term time scales have been exhaustively explored, short-term scales have received less attention. At such frequencies, space-charge transport inside the planetary boundary layer becomes a sizeable contribution to the potential gradient variability. For the first time, co-located (Évora, Portugal) measurements of boundary-layer backscatter profiles and the 100-Hz potential gradient are reported. Five campaign days are analyzed, providing evidence for a relation between high-frequency response of the potential gradient and strong dry convection.     

Additional Samples: Where They Should Be Located

Information for mine planning requires to be close spaced, if compared to the grid used for exploration and resource assessment. The additional samples collected during quasimining usually are located in the same pattern of the original diamond drillholes net but closer spaced. This procedure is not the best in mathematical sense for selecting a location. The impact of an additional information to reduce the uncertainty about the parameter been modeled is not the same everywhere within the deposit. Some locations are more sensitive in reducing the local and global uncertainty than others. This study introduces a methodology to select additional sample locations based on stochastic simulation. The procedure takes into account data variability and their spatial location. Multiple equally probable models representing a geological attribute are generated via geostatistical simulation. These models share basically the same histogram and the same variogram obtained from the original data set. At each block belonging to the model a value is obtained from the n simulations and their combination allows one to access local variability. Variability is measured using an uncertainty index proposed. This index was used to map zones of high variability. A value extracted from a given simulation is added to the original data set from a zone identified as erratic in the previous maps. The process of adding samples and simulation is repeated and the benefit of the additional sample is evaluated. The benefit in terms of uncertainty reduction is measure locally and globally. The procedure showed to be robust and theoretically sound, mapping zones where the additional information is most beneficial. A case study in a coal mine using coal seam thickness illustrates the method.     

Water determination in iron oxyhydroxides and iron ores by Karl Fischer titration

Protohematite (Fe_2?x/3(OH) _x O_3?x 1 ≤ x < 0.5) and hydrohematite (Fe_2?x/3(OH) _x O_3?x 0.5 ≤ x < 0) are iron-defective phases containing hydroxyl groups in their structures. These species were described in prior studies mainly with the aid of X-ray diffraction and Infrared spectroscopy. The existence of these phases in soils might have influence in redox processes, and they were considered as a possible water reservoir in Martian soils. In this study, we have used for the first time the Karl Fischer titration method to determine the amount of water released after heating several synthetic samples of goethite, hematite and natural iron ores at 105, 400, 600 and 900 °C. It was found that heating at 105 °C did not remove all moisture from the samples, and higher temperatures were necessary to completely remove all the absorbed water. The water contents determined at 400, 600 and 900 °C were found to be the same within the experimental errors, suggesting the inexistence of both protohematite and hydrohematite in the investigated samples. Therefore, the above-mentioned effects of these phases in soils might have to be reevaluated.     

Water quality in New Zealand rivers: current state and trends

River water quality, particularly in lowland catchments, is a matter of concern to the New Zealand public. We assessed river water quality and biological state and trends using data from more than 900 monitoring sites. Parallel state and trend analyses were carried out using all sites and a subset of lowland river sites. Median water-quality state in urban and pastoral land-cover classes was poorer than in exotic forest and natural land-cover classes, and lowland sites in the urban and pastoral classes had the poorest water quality. Nutrient and Escherichia coli concentrations increased and visual clarity and Macroinvertebrate Community Index scores decreased as proportions of catchments in high-intensity agricultural and urban land cover increased. Ten-year trends (2004–2013) indicated recent improvements in ammoniacal nitrogen, dissolved reactive phosphorus and total phosphorus in the pastoral and urban classes, possibly reflecting improved land management. In contrast, trends in nitrate-nitrogen in the exotic forest and cool-dry/pastoral classes indicated worsening conditions.