The Misis–Andırın Complex: a Mid-Tertiary melange related to late-stage subduction of the Southern Neotethys in S Turkey

The Mid-Tertiary (Mid-Eocene to earliest Miocene) Misis–Andırın Complex documents tectonic-sedimentary processes affecting the northerly, active margin of the South Tethys (Neotethys) in the easternmost Mediterranean region. Each of three orogenic segments, Misis (in the SW), Andırın (central) and Engizek (in the NE) represent parts of an originally continuous active continental margin. A structurally lower Volcanic-Sedimentary Unit includes Late Cretaceous arc-related extrusives and their Lower Tertiary pelagic cover. This unit is interpreted as an Early Tertiary remnant of the Mesozoic South Tethys. The overlying melange unit is dominated by tectonically brecciated blocks (>100 m across) of Mesozoic neritic limestone that were derived from the Tauride carbonate platform to the north, together with accreted ophiolitic material. The melange matrix comprises polymict debris flows, high- to low-density turbidites and minor hemipelagic sediments.The Misis–Andırın Complex is interpreted as an accretionary prism related to the latest stages of northward subduction of the South Tethys and diachronous continental collision of the Tauride (Eurasian) and Arabian (African) plates during Mid-Eocene to earliest Miocene time. Slivers of Upper Cretaceous oceanic crust and its Early Tertiary pelagic cover were accreted, while blocks of Mesozoic platform carbonates slid from the overriding plate. Tectonic mixing and sedimentary recycling took place within a trench. Subduction culminated in large-scale collapse of the overriding (northern) margin and foundering of vast blocks of neritic carbonate into the trench. A possible cause was rapid roll back of dense downgoing Mesozoic oceanic crust, such that the accretionary wedge taper was extended leading to gravity collapse. Melange formation was terminated by underthrusting of the Arabian plate from the south during earliest Miocene time.Collision was diachronous. In the east (Engizek Range and SE Anatolia) collision generated a Lower Miocene flexural basin infilled with turbidites and a flexural bulge to the south. Miocene turbiditic sediments also covered the former accretionary prism. Further west (Misis Range) the easternmost Mediterranean remained in a pre-collisional setting with northward underthrusting (incipient subduction) along the Cyprus arc. The Lower Miocene basins to the north (Misis and Adana) indicate an extensional (to transtensional) setting. The NE–SW linking segment (Andırın) probably originated as a Mesozoic palaeogeographic offset of the Tauride margin. This was reactivated by strike-slip (and transtension) during Later Tertiary diachronous collision. Related to on-going plate convergence the former accretionary wedge (upper plate) was thrust over the Lower Miocene turbiditic basins in Mid–Late Miocene time. The Plio-Quaternary was dominated by left-lateral strike-slip along the East Anatolian transform fault and also along fault strands cutting the Misis–Andırın Complex.     

Mobilization and attenuation of heavy metals within a nickel mine tailings impoundment near Sudbury, Ontario, Canada

 The oxidation and the subsequent dissolution of sulfide minerals within the Copper Cliff tailings area have led to the release of heavy metals such as Fe, Ni, and Co to the tailings pore water. Dissolved concentrations in excess of 10 g/l Fe and 2.2 g/l Ni have been detected within the shallow pore water of the tailings, with increasing depth these concentrations decrease to or near analytical detection limits. Geochemical modelling of the pore-water chemistry suggests that pH-buffering reactions are occurring within the shallow oxidized zones, and that secondary phases are precipitating at or near the underlying hardpan and transition zones. Mineralogical study of the tailings confirmed the presence of goethite, jarosite, gypsum, native sulfur, and a vermiculite-type clay mineral. Goethite, jarosite, and native sulfur form alteration rims and pseudo-morphs of the sulfide minerals. Interstitial cements, composed of goethite, jarosite, and gypsum, locally bind the tailings particles, forming hardpan layers. Microprobe analyses of the goethite indicate that it contains up to 0.6 weight % Ni, suggesting that the goethite is a repository for Ni. Other sinks detected for heavy metals include jarosite and a vemiculite-type clay mineral which locally contains up to 1.6 weight % Ni. To estimate the mass and distribution of heavy metals associated with the secondary phases within the shallow tailings, a series of chemical extractions was completed. The experimental design permitted four fractions of the tailings to be evaluated independently. These four fractions consisted of a water-soluble, an acid-leachable, and a reducible fraction, as well as the whole-rock total. Twenty-five percent of the total mass of heavy metals was removed in the acid-leaching experiments, and 100% of the same components were removed in the reduction experiments. The data suggest that precipitation/coprecipitation reactions are providing an effective sink for most of the heavy metals released by sulfide mineral oxidation. In light of these results, potential decommissioning strategies should be evaluated with the recognition that changing the geochemical conditions may alter the stability of the secondary phases within the shallow tailings. Received: 9 April 1997 · Accepted: 21 July 1997     

Clausthalite in coal

A lead selenide mineral, tentatively identified as clausthalite (PbSe) based on optical microscopy, scanning electron microscopy with energy-dispersive X-ray (EDAX), electron microprobe, and scanning proton microprobe (SPM), has been described in a number of coals. While clausthalite has been mentioned as a possible source of Se in coal, it is present in such small quantities and sizes, that the mineral identification has not been absolutely confirmed. The mineral specimens examined in this study would contribute, not only to the Pb and Se concentrations in the coal, but also, in at least one case, to Hg concentrations.     

Midlatitude ocean–atmosphere interaction in an idealized coupled model

Interannual-to-interdecadal ocean-atmosphere interaction in midlatitudes is studied using an idealized coupled model consisting of eddy resolving two-layer quasi-geostrophic oceanic and atmospheric components with a simple diagnostic oceanic mixed layer. The model solutions exhibit structure and variability that resemble qualitatively some aspects of the observed climate variability over the North Atlantic. The atmospheric climatology is characterized by a zonally modulated jet. The single-basin ocean climatology consists of a midlatitude double jet that represents the Gulf Stream and Labrador currents, which are parts of the subtropical and subpolar gyres, respectively. The leading mode of the atmospheric low-frequency variability consists predominantly of meridional displacements of the zonal jet, with a local maximum over the ocean. The first basin-scale mode of sea-surface temperature has a red power spectrum, is largely of one polarity and bears qualitative similarities with the observed interdecadal mode identified by Kushnir. A warm sea-surface temperature anomaly is accompanied by anomalously low atmospheric pressure, an intensified model Gulf Stream and a weakened Labrador current. This mode is found not to be affected significantly by oceanic coupling. In the western part of the basin, this sea-surface temperature pattern is shown to be forced by the slowest components of the surface-wind anomaly through a delayed modulation of the baroclinic time-dependent boundary currents which advect mean SST, with synchronous variations in the two oceanic jets. The response in the east is found to be dominated by local atmospheric forcing. Basin-scale intrinsic oceanic variability consists of a damped oceanic oscillatory mode in the baroclinic flow field that is excited by the atmospheric noise. Its period is around 5.5 years, but it has a negligible influence on the evolution of sea-surface temperature. Important for this mode's excitation is the meridional position of the atmospheric center of action relative to the ocean gyres.     

Biomorphological scaling laws from convectively accelerated streams

Worldwide convectively accelerated streams flowing in downstream-narrowing river sections show that riverbed vegetation growing on alluvial sediment bars gradually disappears, forming a front beyond which vegetation is absent. We revise a recently proposed analytical model able to predict the expected longitudinal position of the vegetation front. The model was developed considering the steady state approximation of 1-D ecomorphodynamics equations. While the model was tested against flume experiments, its extension and application to the field is not trivial as it requires the definition of proper scaling laws governing the observed phenomenon. In this work, we present a procedure to calculate vegetation parameters and flow magnitude governing the equilibrium at the reach scale between hydromorphological and biological components in rivers with converging boundaries. We collected from worldwide rivers data of section topography, hydrogeomorphological and riparian vegetation characteristics to perform a statistical analysis aimed to validate the proposed procedure. Results are presented in the form of scaling laws correlating biological parameters of growth and decay from different vegetation species to flood return period and duration, respectively. Such relationships demonstrate the existence of underlying selective processes determining the riparian vegetation both in terms of species and cover. We interpret the selection of vegetation species from ecomorphodynamic processes occurring in convectively accelerated streams as the orchestrated dynamic action of flow, sediment and vegetation characteristics. © 2019 John Wiley & Sons, Ltd.     

From drought to flood: A water balance analysis of the Tuolumne River basin during extreme conditions (2015–2017)

The degree to which the hydrologic water balance in a snow-dominated headwater catchment is affected by annual climate variations is difficult to quantify, primarily due to uncertainties in measuring precipitation inputs and evapotranspiration (ET) losses. Over a recent three-year period, the snowpack in California's Sierra Nevada fluctuated from the lightest in recorded history (2015) to historically heaviest (2017), with a relatively average year in between (2016). This large dynamic range in climatic conditions presents a unique opportunity to investigate correlations between annual water availability and runoff in a snow-dominated catchment. Here, we estimate ET using a water balance approach where the water inputs to the system are spatially constrained using a combination of remote sensing, physically based modelling, and in-situ observations. For all 3 years of this study, the NASA Airborne Snow Observatory (ASO) combined periodic high-resolution snow depths from airborne Lidar with snow density estimates from an energy and mass balance model to produce spatial estimates of snow water equivalent over the Tuolumne headwater catchment at 50-m resolution. Using observed reservoir inflow at the basin outlet and the well-quantified snowmelt model results that benefit from periodic ASO snow depth updates, we estimate annual ET, runoff efficiency (RE), and the associated uncertainty across these three dissimilar water years. Throughout the study period, estimated annual ET magnitudes remained steady (222 mm in 2015, 151 mm in 2016, and 299 mm in 2017) relative to the large differences in basin input precipitation (547 mm in 2015, 1,060 mm in 2016, and 2,211 mm in 2017). These values compare well with independent satellite-derived ET estimates and previously published studies in this basin. Results reveal that ET in the Tuolumne does not scale linearly with the amount of available water to the basin, and that RE primarily depends on total annual snowfall proportion of precipitation.