Correction of tree ring stable carbon isotope chronologies for changes in the carbon dioxide content of the atmosphere

Tree-ring stable carbon isotope ratios (δ¹³C) often display a decline over the industrial period (post-AD1850) that is only partly explained by changes in the isotopic ratio of carbon dioxide (CO₂) and may represent a response to increased atmospheric concentrations of CO₂ (ca). If this is not addressed, reconstructions using long tree-ring stable isotope chronologies calibrated using the modern period, for which meteorological records are available, may be compromised. We propose a correction procedure that attempts to calculate the δ¹³C values that would have been obtained under pre-industrial conditions. The correction procedure uses nonlinear (loess) regression but the magnitude of the adjustment made is restricted by two logical constraints based on the physiological response of trees: first, that a unit increase in ca cannot result in more than the same unit increase in the internal concentration of CO₂ (ci), and second, that increases in water-use efficiency as a result of an increase in ca are limited to maintaining a constant ci/ca ratio. The first constraint allows retention of a falling trend in δ¹³C, which exceeds that which could logically be attributed to a passive response to rising ca. The second constraint ensures that any increase in δ¹³C, reflecting a change in water-use efficiency beyond maintenance of a constant ci/ca, is not removed. The procedure is tested using ‘pseudoproxies’, to demonstrate the effect of the correction on time-series with different shapes, and data from three sites in Finland and Norway. Two of the time-series retain a significant trend after correction, and in all three cases the correction improves the correlation with local meteorological measurements.     

Time scales and length scales in magma flow pathways and the origin of magmatic Ni–Cu–PGE ore deposits

Ore forming processes involve the redistribution of heat, mass and momentum by a wide range of processes operating at different time and length scales. The fastest process at any given length scale tends to be the dominant control. Applying this principle to the array of physical processes that operate within magma flow pathways leads to some key insights into the origins of magmatic Ni–Cu–PGE sulfide ore deposits. A high proportion of mineralised systems, including those in the super-giant Noril'sk-Talnakh camp, are formed in small conduit intrusions where assimilation of country rock has played a major role. Evidence of this process is reflected in the common association of sulfides with vari-textured contaminated host rocks containing xenoliths in varying stages of assimilation. Direct incorporation of S-bearing country rock xenoliths is likely to be the dominant mechanism for generating sulfide liquids in this setting. However, the processes of melting or dissolving these xenoliths is relatively slow compared with magma flow rates and, depending on xenolith lithology and the composition of the carrier magma, slow compared with settling and accumulation rates. Chemical equilibration between sulfide droplets and silicate magma is slower still, as is the process of dissolving sulfide liquid into initially undersaturated silicate magmas. Much of the transport and deposition of sulfide in the carrier magmas may occur while sulfide is still incorporated in the xenoliths, accounting for the common association of magmatic sulfide-matrix ore breccias and contaminated “taxitic” host rocks. Effective upgrading of so-formed sulfide liquids would require repetitive recycling by processes such as re-entrainment, back flow or gravity flow operating over the lifetime of the magma transport system as a whole. In contrast to mafic-hosted systems, komatiite-hosted ores only rarely show an association with externally-derived xenoliths, an observation which is partially due to the predominant formation of ores in lava flows rather than deep-seated intrusions, but also to the much shorter timescales of key component systems in hotter, less viscous magmas. Nonetheless, multiple cycles of deposition and entrainment are necessary to account for the metal contents of komatiite-hosted sulfides. More generally, the time and length scale approach introduced here may be of value in understanding other igneous processes as well as non-magmatic mineral systems.     

Soil conditions in damaged North Queensland mangroves

Selected physical, chemical, and biological characteristics of soils in mechanically damaged North Queensland mangrove forests were examined and compared with undisturbed controls. Soils in nine forests were tested in a factorial sampling programme designed to examine effects of (i) severity of mechanical damage to forests (severely damaged: trees removed and soils disrupted by bulldozing; versus damaged: trees felled no bulldozing; versus controls: trees and soils undisturbed), (ii) soil depth, (iii) forests (10s–100s km apart), and (iv) sites within forests (10s–100s m apart). Characteristics examined were soil compaction, grain size, pH, percent by weight of total C, N, P, K, S, and Fe and the density of crab burrows. Three of the 10 variables examined: total N, total P, and density of crab holes, decreased with mechanical damage to forests. The loss of potentially-limiting nutrients and of an important bioturbator at severely damaged sites suggests the need for further experimental investigation of soil characteristics with respect to natural regeneration and efforts of mangrove restoration.     

Reference Minerals for the Microanalysis of Light Elements

The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens.     

Interdecadal variability over the North Pacific in a multi-century climate simulation

Interdecadal variability in the North Pacific region is investigated in a 500-y control integration of the Hamburg ECHAM+LSG coupled ocean-atmosphere general circulation model. The spectrum is predominantly red, but a significant peak with a period of about 18 y is detected in the spectrum of sea surface temperature (SST). This peak is shown to be associated with an irregular oscillation that involves both the model ocean and atmosphere. The SST, sea-level pressure, and geopotential height at 500 hPa all undergo a primarily standing oscillation with an extensive monopole structure centered near the date line. The surface anticyclone is situated to the northeast of the warm SST anomaly, and there is a small westward tilt with height; temporal changes are approximately in phase. The anomalous surface heat flux accompanying the warm phase of SST is primarily out of the ocean, but is compensated by anomalous warm advection by surface currents, allowing the SST anomaly to persist. Oceanic thermocline anomalies propagate northward in the western Pacific, and lag the atmosphere indicating a disequilibrium with the atmosphere; sub-surface thermal advection appears to play an important role. A comparison is made between the model's 18-y oscillation and oscillatory components identified in an analysis of the GISST observational SST dataset, which have periods of approximately 6 and roughly 30 y.     

The origins of rare earths in metalliferous sediments of the Troodos Massif. Cyprus

The ferromanganoan umbers which overlie the uppermost pillow lavas of the Troodos Massif, Cyprus, are strongly enriched in REE relative to normal pelagic clays. Together, the umbers, related ferruginous sediments, and the ochres which are associated with massive cupriferous sulphides located within the lavas, all show light REE enrichment. There is a marked negative Ce anomaly which is characteristic of seawater. Field and chemical data suggest that the REE were incorporated into ferruginous precipitates derived from deep leaching of tholeiitic lavas by seawater. All the metalliferous sediments can be interpreted as related events in the evolution of the Troodos ocean ridge. In contrast, REE patterns of bentonitic clays above the umbers indicate a predominantly continental derivation.     

Variations in shock deformation at the Slate Islands impact structure,Lake Superior,Canada

A progressive change in the level of shock deformation is documented in autochthonous rocks from the central uplift of the Slate Islands impact structure, Lake Superior. Correlation of these observations, which are based mainly on the relative frequency of planar features of specific crystallographic orientation in quartz, with experimental data is used to estimate the average shock pressures recorded in the samples studied. Recorded pressures range from 5.8 to 15.3 GPa and generally increase towards the proposed shock centre. Variations in the shock response of quartz of different grain size and texture are observed within and between samples. It is apparent that large interlocking quartz grains in eyes record approximately 15–20% higher levels of shock deformation than small grains in mosaics or large isolated phenocrysts. These variations in shock deformation are attributed to the effect of shock wave reverberations between grains and length of shock pulse duration within grains.Comparison of the Slate Islands data with similar observations at the larger Charlevoix impact structure indicates that the rate of change of recorded shock pressure with distance is greater at the Slate Islands structure. This is interpreted as due to variations in the strain rates and/or the rate of shock wave attenuation with radial distance between impact structures of different size.Contribution from Earth Physics Branch No. 626     

THE STATUS OF GEOGRAPHY IN GRADUATE URBAN AFFAIRS PROGRAMS

Literature on the theoretical foundations of urban affairs emphasizes that the field is interdisciplinary in nature. The urban perspectives of the traditional social sciences, which include geography, should each constitute a significant component within an urban affairs program. However, the results of a recent survey indicate that geography is not represented in graduate urban affairs programs nearly to the extent of the other social sciences. The discrepancies between the interdisciplinary claims of the theoretical literature and the survey results are demonstrated in this article, followed by several hypotheses regarding possible causes of this situation.