Estimation of hydroxyl radical concentrations in the marine atmospheric boundary layer using a reactive atmospheric tracer

Hydroxyl radical (OH) concentrations in the atmospheric boundary layer over a number of remote ocean locations are calculated from the measured diurnal variation in atmospheric dimethylsulfide (DMS). By using averaged DMS data sets from extended periods, the calculation yields OH concentrations averaged over periods from several days to weeks. These average OH concentrations range from 7×10⁵ to 2.9×10⁶ molecules cm^-3, corresponding to midday maxima of 3 to 12×10⁶ molecules cm^-3. The lowest values correspond to studies with the lowest light intensity (Antarctic summer and South Atlantic winter), and the highest values to regions with probable anthropogenic influence. In addition to the long term averages, daily average OH levels can be calculated for most days in a two week period from a cruise in the tropical eastern Pacific. These calculations are in good argeement with global average OH levels derived from other tracers, and are consistent with model OH calculations when allowance is made for variation in ambient ozone levels between the studies. Estimates of gas exchange made from the diurnal variation of DMS suggest that either the gas exchange coefficient of DMS or the boundary layer mixing depth may have been overestimated in past analyses.     

Cryogenic Drilling: A New Drilling Method for Environmental Remediation

Cryogenic drilling is a technique developed at the University of California (UC), Berkeley, for drilling in unstable sediments of environmental monitoring, for characterizing, and for remediation wells, The method uses standard air rotary drilling techniques, but with cold nitrogen rather than ambient air as the circulating fluid in order to freeze and stabilize the borehole wall. Several laboratory and full-scale field tests have been performed. A.52-foot-deep (16 m) soil boring and 24 foot (7 m) monitoring well have been drilled as part of the Lawrence Berkeley Laboratory Site Characterization Project. Continued testing and refinement of the equipment and operational method are in progress. The method has been proposed for use as part of the Department of Energy (DOE) weapons site cleanup at locations with unstable sediments such as Hanford, Sandia, and Idaho National Engineering Laboratory (INEL).     

A search for flow structure in columnar basalt using magnetic anisotropy measurements

Summary Evidence for flow structure within hexagonal columns of basalt has been sought, using measurements of the anisotropy of magnetic susceptibility. The observed magnetic grain alignment indicates that the flow was essentially uniform and horizontal across the hexagons which were sampled. The flow probably occurred during emplacement of the lava; there is no evidence of convection within the hexagons, either from the degree of grain alignment or its orientation.     

Comparison of ship's heading determined from an array of GPS antennas with heading from conventional gyrocompass measurements

An Ashtech GPS 3DF, a commercially available system for measuring ship's heading from an array of GPS antennas, was installed on RRS Discovery in August 1992. Data were collected during 8 days of ship trials, including periods in port and while on station or steaming. Headings from the GPS system have been compared with headings from the ship's gyrocompass, and residuals calculated. While in port, residuals had a standard deviation of 0.066°, suggesting satisfactory performance by both instruments. While at sea, time-averaged residuals varied with a range of nearly 3°, most of which is attributed to systematic errors in the ship's gyro. After correcting the gyro using 10-min averages of the GPS minus gyro headings, the residual GPS minus gyro differences had a standard deviation of 0.17°. This represents a likely limit on the use of GPS heading data to improve conventional gyro measurements.     

Geology and biology of Oceanographer submarine Canyon

We investigated Oceanographer Canyon, which is on the southeastern margin of Georges Bank, during a series of fourteen dives in the “Alvin” and “Nekton Gamma” submersibles. We have integrated our observations with the results of previous geological and biological studies of Georges Bank and its submarine canyons. Fossiliferous sedimentary rocks collected from outcrops in Oceanographer Canyon indicate that the Cretaceous—Tertiary boundary is at 950 m below sea level at about 40°16′N where at least 300 m of Upper Cretaceous strata are exposed; Santonian beds are more than 100 m thick and are the oldest rocks collected from the canyon. Quaternary silty clay, deposited most probably during the late Wisconsin Glaciation, veneers the canyon walls in many places, and lithologically similar strata are present beneath the adjacent outer shelf and slope. Where exposed, the Quaternary clay is commonly burrowed by benthic organisms that cause extensive erosion of the canyon walls, especially in the depth zone (100–1300 m) inhabited by red crabs (Geryon) and/or jonah crabs (Cancer). Bioerosion is minimal on high, near-vertical cliffs of sedimentary rock, in areas of continual sediment movement, and where the sea floor is paved by gravel. A thin layer of rippled, unconsolidated silt and sand is commonly present on the canyon walls and in the axis; ripple orientation is most commonly transverse to the canyon axis and slip-faces point downcanyon. Shelf sediments are transported from Georges Bank over the eastern rim and into Oceanographer Canyon by the southwest drift and storm currents; tidal currents and internal waves move the sediment downcanyon along the walls and axis. Large erratic boulders and gravel pavements on the eastern rim are ice-rafted glacial debris of probable late Wisconsinan age; modern submarine currents prevent burial of the gravel deposits. The dominant canyon megafauna segregates naturally into three faunal depth zones (133–299 m; 300–1099 m; 1100–1860 m) that correlate with similar zones previously established for the continental slope epibenthos. Faunal diversity is highest on gravelly sea floors at shallow and middle depths. The benthic fauna and the fishes derive both food and shelter by burrowing into the sea floor. In contrast to the nearby outer shelf and upper slope, Oceanographer Canyon has not been extensively exploited by the fishing industry, and the canyon ecosystem probably is relatively unaltered.     

Beringia as an Ice Age genetic museum

Thousands of Late Pleistocene remains are found in sites throughout Beringia. These specimens comprise an Ice Age genetic museum, and the DNA contained within them provide a means to observe evolutionary processes within populations over geologically significant time scales. Phylogenetic analyses can identify the taxonomic positions of extinct species and provide estimates of speciation dates. Geographic and temporal divisions apparent in the genetic data can be related to ecological change, human impacts, and possible landscape mosaics in Beringia. The application of ancient DNA techniques to traditional paleontological studies provides a new perspective to long-standing questions regarding the paleoenvironment and diversity of Late Pleistocene Beringia.     

Oxygen isotope evidence for the origin of enriched mantle beneath the mid-Atlantic ridge

Geochemical variations in mid-ocean ridge basalts have been attributed to differing proportions of compositionally distinct mantle components in their sources, some of which may be recycled crust. Oxygen isotopes are strongly fractionated by near-surface interactions of rocks with the hydrosphere, and thus provide a tracer of near-surface materials that have been recycled into the mantle. We present here oxygen isotope analyses of basaltic glasses from the mid-Atlantic ridge south of and across the Azores platform. Variations in δ¹⁸O in these samples are subtle (range of 0.47‰) and may partly reflect shallow fractional crystallization; we present a method to correct for these effects. Relatively high fractionation-corrected δ¹⁸O in these samples is associated with geochemical indices of enrichment, including high La/Sm, Ce/Pb, and ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd. Our results suggest two first-order conclusions about these enriched materials: (1) they are derived (directly or indirectly) from recycled upper oceanic crustal rocks and/or sediments; and (2) these materials are present in the north Atlantic MORB sources in abundances of less than 10% (average 2–5%). Modeling of variations of δ¹⁸O with other geochemical variables further indicates that the enriched component is not derived from incorporation of sediment or bulk altered oceanic crust, from metasomatism of the mantle by hydrous or carbonate-rich fluids, or from partial melting of subducted sediment. Instead, the data appear to require a model in which the enriched component is depleted mantle that has been metasomatized by small-degree partial melts of subducted, dehydrated, altered oceanic crust. The age of this partial melting is broadly constrained to 250 Ma. Reconstructed plate motions suggest that the enriched component in the north Atlantic mantle may have originated by subduction along the western margin of Pangea.     

Crustal development in the Agnew region,Western Australia,as shown by Rb/Sr isotopic and geochemical studies

Rb/Sr geochronology on a folded greenstone-granitoid complex in the Agnew area, Western Australia, yields four distinct ages of igneous activity that conform with stratigraphic and intrusive relationships. They are (using $\text{λ}{}^{87}\text{Rb}\text{= 1.42 · 10}{}^{\mathrm{?11}}\text{a}{}^{\mathrm{?1}}$, NBS 70A = 522 ppm Rb and 65.3 ppm Sr):

     

450.

Trace metal concentrations in offshore,deep-water seaweeds in the western North Atlantic ocean     

James R. Sears  Kenneth J. Pecci  Richard A. Cooper 《Marine pollution bulletin》1985,16(8):325-328

Ambient, natural levels of selected heavy metals were assayed from deep, offshore populations of attached seaweeds from 1980 through 1983 from Pigeon Hill, 37 km from the nearest shoreline in the Gulf of Maine, and from Block Island, 23 km from the nearest mainland in Rhode Island Sound. Concentration levels of barium, cadmium, chromium, copper, mercury, lead and zinc were low when compared with concentration values published for a variety of seaweeds from the eastern and western North Atlantic. Values from Pigeon Hill and Block Island provide baseline data for long term monitoring of a relatively pristine, offshore, benthic community in the western North Atlantic.     

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	Ma	87Sr/86Sr initial (IR)
(1) Differentiated gabbro-granophyre from a stratigraphically old (Kathleen Valley) greenstone sequence	$\text{> 2718 ± 50}$	$\text{0.7007 ± 0.0004}$
(2) Voluminous tonalite, the Lawlers Tonalite	$\text{2652 ± 20}$	$\text{0.70152 ± 0.00012}$
	$\text{2576 ± 14}$	$\text{0.70218 ± 0.00021}$
(3) A less voluminous leucogranite, and a large complex pegmatite cutting the Perseverance nickel orebody	$\text{2588 ± 18}$	$\text{0.7624 ± 0.0068}$
(4) Aplitic leucotonalite (very minor volumes but widespread)	$\text{2474 ± 14}$	$\text{0.70193 ± 0.00012}$

Trace metal concentrations in offshore,deep-water seaweeds in the western North Atlantic ocean

Ambient, natural levels of selected heavy metals were assayed from deep, offshore populations of attached seaweeds from 1980 through 1983 from Pigeon Hill, 37 km from the nearest shoreline in the Gulf of Maine, and from Block Island, 23 km from the nearest mainland in Rhode Island Sound. Concentration levels of barium, cadmium, chromium, copper, mercury, lead and zinc were low when compared with concentration values published for a variety of seaweeds from the eastern and western North Atlantic. Values from Pigeon Hill and Block Island provide baseline data for long term monitoring of a relatively pristine, offshore, benthic community in the western North Atlantic.