The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary

In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme +. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary.     

The macroinfauna of the Galician sandy beaches (NW Spain) affected by the Prestige oil-spill

Eighteen sandy beaches were sampled along the 1659 km of the Galician coast (NW Spain) six months after the Prestige oil-spill to study the impact of the fuel and the clean-up activities on the macroinfauna community. A transect was extended at each beach, from above the drift line to below the swash line at five sampled levels; at each level six 0.05 m2 replicates were taken to a depth of 30 cm and sieved through a 1mm mesh, and the organisms collected and preserved. Results were compared with previous data obtained using the same procedures. The macroinfauna was numerically dominated by the amphipod Pontocrates arenarius, the isopod genus Eurydice, the polychaete Scolelepis squamata, and the amphipod Talitrus saltator. As a result of the Prestige oil-spill and the clean-up activities, beach populations were reduced, with Eurydice and S. squamata as the most affected taxa.     

祁连山东部沙尘暴天气成因及气候规律分析

利用我国沙尘暴多发区 ,甘肃省祁连山东部民勤、武威等 4站建站以来近 5 0a的气象资料 ,详细分析了祁连山东部沙尘暴天气发生的成因 ,造成的危害情况及变化规律 ,指出土地沙漠化和大风是造成沙尘暴的主要原因 ,并提出沙尘暴天气的防御对策。     

Rb-Sr dating of Paleozoic glauconite from the Llano region,central Texas

Glauconite from eight stratigraphic horizons (Cambrian to Pennsylvanian) in the Llano Uplift, central Texas and two Cretaceous glauconites were analyzed by the Rb-Sr method. Only two untreated samples provide ages in agreement with those anticipated from current best estimates of the geologic time scale. With one exception all the other apparent ages fall short of the estimated age of deposition by as much as 22%. Low ages, the pattern customarily observed, are attributed to postdepositional loss of radiogenic ⁸⁷Sr from expandable layers by weathering or during diagenesis.Detailed leaching experiments using a variety of reagents were performed to characterize the behavior of glauconite. The most promising treatment, which we recommend as standard procedure in all future studies, is with ammonium acetate which is able to purge the mineral of loosely-bound Rb and Sr while leaving tightly-bound components intact. After appropriate leach, three other Rb-Sr ages were brought into coincidence with their estimated ages of deposition.In contrast an Upper Cambrian glauconite was found to be extremely resistant to further alteration by chemical attack′, providing an age of 429 ± 17 M yr. Although 17% short of the age of deposition, this age is interpreted as the time of a real event: diagenetic recrystallization induced by burial. Comparison of data from four samples indicates that for Paleozoic glauconite, conditions exist in which the Rb-Sr system is less susceptible to mild disturbance than is the K-Ar system.     

Syntectonic emplacement of the Middle Jurassic Concón Mafic Dike Swarm, Coastal Range, central Chile (33° S)

The Concón Mafic Dike Swarm (CMDS) consists of basaltic to andesitic dikes emplaced into deformed Late Paleozoic granitoids during the development of the Jurassic arc of central Chile. The dikes are divided into an early group of thick dikes (5–12 m) and a late group of thin dikes (0.5–3 m). Two new amphibole ⁴⁰Ar/³⁹Ar dates obtained from undeformed and deformed dikes, constrain the age of emplacement and deformation of the CMDS between 163 and 157 Ma. Based on radiometric ages, field observations, AMS studies and petrographic data, we conclude that the emplacement of the CMDS was syntectonic with the Jurassic arc extension and associated with sinistral displacements along the NW-trending structures that host the CMDS. The common occurrence of already deformed and rotated xenoliths in the dikes indicates that deformation in the granitoids started previously.The early thick dikes and country rocks appear to have been remagnetized during the exhumation of deep-seated coastal rocks in the Early Cretaceous (around 100 Ma). The remanent magnetization in late thin dikes is mainly retained by small amounts of low-Ti magnetite at high temperature and pyrrhotite at low temperature. The magnetization in these dikes appears to be primary in origin. Paleomagnetic results from the thin dikes also indicate that the whole area was tilted  23° to the NNW during cooling of the CMDS.The NNW–SSE extension vectors deduced from the paleomagnetic data and internal fabric of dikes are different with respect to extension direction deduced for the Middle–Late Jurassic of northern Chile, pointing to major heterogeneities along the margin of the overriding plate during the Mesozoic or differences in the mechanisms driving extension during such period.     

The far-UV spectrum of T Tauri stars – I. The relevance of the IUE Newly Extracted Spectra

The far-UV spectrum of the T Tauri stars (TTSs) provides important clues about the structure of the stellar atmospheres, winds and accretion shocks. The IUE ( International Ultraviolet Explorer ) Final Archive contains the most complete data base for such studies. A new extraction system, the IUE Newly Extracted Spectra ( ines ), has been developed to overcome the disadvantages of the extraction system used in the IUE Final Archive, the Signal Weighted Extraction Technique ( swet ). We have compared the ines spectra of the whole sample of TTSs in the far-UV range (1200–2000 Å) with the swet low-resolution spectra available in the IUE Final Archive. Although in most of the cases there is a good agreement between both samples, an important enhancement of the ines line fluxes with respect to the swet line fluxes is reported for particular spectra. The line fluxes are enhanced by as much as a factor of ∼2.5 in some objects, which is significant for variability studies of TTSs because the variations of the UV lines are typically of this order. The emission-measure distributions built to study the atmospheres of these stars are based on the UV emission line fluxes, so the new system is susceptible to introduce changes in these models. Moreover, the non-linear enhancement of the ines line fluxes produces variations in diagnostic line ratios usually taken as temperature and density tracers in late-type stars. These line ratios can vary by as much as a factor of 3 when the ines data are compared with the swet , with the subsequent variation of the physical parameters derived from them.     

Petrographic and geochemical characterization of the granitic rocks of the Araguainha impact crater,Brazil

Petrographic and geochemical data obtained on the Araguainha impact crater (Goiás/Mato Grosso States, Brazil) indicate the existence of several molten products that originated during impact‐induced congruent melting of an alkali‐granite exposed in the inner part of the central uplift of the structure. Although previous studies have described these melts to some extent, there is no detailed discussion on the petrographic and geochemical variability in the granite and its impactogenic derivatives, and therefore, little is known about the geochemical behavior and mobility of trace elements during its fusion in the central part of the Araguainha crater. This paper demonstrates that the preserved granitoid exposed in the core of the structure is a magnesium‐rich granite, similar to postcollisional, A‐type granites, also found in terrains outside the Araguainha crater, in the Brasília orogenic belt. The molten products are texturally distinct and different from the original rock, but have very similar geochemical composition, making it difficult to separate these lithotypes based on concentrations of major and minor elements. This also applies for trace and rare earth elements (REE), thus indicating a high degree of homogenization during impact‐induced congruent melting under high pressure and postshock temperature conditions. Petrographic observations, along with geochemical data, indicate that melting occurs selectively, where some of the elements are transported with the melt. Simultaneously, there is an effective dissolution of the rock (granite), which leads to entrainment of the most resistant solid phases (intact or partially molten minerals) into the melt. Minerals more resistant to melting, such as quartz and oxides, contribute substantially to a chemical balance between the preserved granite and the fusion products generated during the meteoritic impact.