Sulfur in peridotites and gabbros at Lost City (30°N, MAR): Implications for hydrothermal alteration and microbial activity during serpentinization

Variations in sulfur mineralogy and chemistry of serpentinized peridotites and gabbros beneath the Lost City Hydrothermal Field at the southern face of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) were examined to better understand serpentinization and alteration processes and to study fluid fluxes, redox conditions, and the influence of microbial activity in this active, peridotite-hosted hydrothermal system. The serpentinized peridotites are characterized by low total sulfur contents and high bulk δ³⁴S values close to seawater composition. Low concentrations of ³⁴S-enriched sulfide phases and the predominance of sulfate with seawater-like δ³⁴S values indicate oxidation, loss of sulfide minerals and incorporation of seawater sulfate into the serpentinites. The predominance of pyrite in both serpentinites and gabbros indicates relatively high fO₂ conditions during progressive serpentinization and alteration, which likely result from high fluid fluxes during hydrothermal circulation and evolution of the Lost City system from temperatures of ∼250 to 150 °C. Sulfate and sulfide minerals in samples from near the base of hydrothermal carbonate towers at Lost City show δ³⁴S values that reflect the influence of microbial activity. Our study highlights the variations in sulfur chemistry of serpentinized peridotites in different marine environments and the influence of long-lived, moderate temperature peridotite-hosted hydrothermal system and high seawater fluxes on the global sulfur cycle.     

Der Tagesgang von Temperatur und Luftfeuchtigkeit in San Salvador

Zusammenfassung Der Tagesgang von Temperatur und Luftfeuchtigkeit in San Salvador zeigt deutliche jahreszeitliche Verschiedenheiten, die wesentlich durch Strahlungsgenuss, Sonnenauf- und Untergangszeiten und ein tageszeitliches mittelräumiges Windsystem bestimmt ist.

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Summary The daily variation of air temperature and humidity shows clear seasonal differences, which are essentially determined by incoming radiation, sunrise and sunset and a diurnal meso-scale wind system.

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Resumen El transcurso diurno de la temperatura y de la humedad del ambiente en San Salvador demuestra netamente diferencias segun la estación del año, las cuales se deben a las condiciones de radiación, salida y puesta del sol y un sistema diurno de viento.

     

Metabolism of perylene by monooxygenases of the skin and liver of Ambystoma tigrinum

The prevalence of dermal neoplasia among neotenic tiger salamanders (Ambystoma tigrinum) collected from the Reese Air Force Base sewage lagoon far exceeded that among salamanders from nearby uncontaminated lagoons. Perylene was the predominant pglycyclic aromatic hydrocarbon contaminant in this lagoon. Perylene was shown to be a substrate for monooxygenases in skin and liver homogenates and formed DNA-binding metabolites. Perylene exposure appeared to augment subsequent perylene metabolism by dermal enzymes but it was not a strong inducer of hepatic monooxygenases. Aroclor 1254 induced benzo(a)pyrene and perylene metabolism by both skin and liver enzymes. However, perylene apparently was not activated by salamander enzymes, as suggested by its lack of in vitro mutagenicity and failure to induce tumors.     

Submerged cylinder wave energy device: theory and experiment

Linearized water wave theory is used to show that a submerged long circular cylinder suitably constrained by springs and dampers to make small harmonic oscillations, can be extremely efficient in absorbing the energy in an incident regular wave whose crests are parallel to the axis of the cylinder. Experimental results are described which confirm the theory for small amplitude waves and which suggest that the device can still be fairly efficient in waves of moderate amplitude.     

Seasonally Hypersaline Estuaries in Mediterranean-climate Regions

Data collected in three Californian estuaries indicate that hypersaline conditions exist during the dry summers typical of a Mediterranean climate. The generalised seasonal and longitudinal hydrographic structures are described and explained. It is argued that this seasonal hypersalinity is common and that it represents a major class of estuaries. The observed accumulation of salt indicates surprisingly long residence times in small basins which have free exchange with the ocean. This semi-isolation of the inner basin leads to a large build-up or severe depletion of nutrients, pollutants and plankton in these systems. Of concern are the trends to increase pollutant loading in the same systems that are experiencing an increase in residence times owing to freshwater extraction in the watershed.     

Wave transmission and reflection characteristics of a rigid surface and submerged horizontal plate

The wave transmission and reflection characteristics of a rigidly fixed surface and submerged horizontal plate were investigated experimentally in detail for a wide range of incident wave steepnesses and for different depths of submerge of the plate in deep water conditions in regular water wave fields. The experiments were conducted at the Ocean Engineering Centre, Indian Institute of Technology, Madras, India, in a wave flume 10 m long, 0.3 m wide and in a constant water depth of 0.8 m. The horizontal plate is 0.22 m thick and 1.2 m in length, covering the enrire width of the flume. From the present investigation, it is found that for a rigid surface plate, the coefficient of transmission is a minimum and the coefficient of reflection is a maximum, but the maximum value of the coefficient of energy loss occurs for plates submerged closer to the still-water level (SWL) and not for the surface plate. It is also found that the value of the coefficient of reflection increases with the increase in the value of the Reddy-Neelamani (RN) number, the ratio of horizontal water particle excursion at the bottom of the plate in its absence to the length of the plate. The coefficient of transmission is found to decrease rapidly with increase in the value of RN number up to 0.1. The wave transmission is only 5% for RN from 0.1 to 0.2. It is also found that for RN number greater than 0.04, the minimum energy dissipation is consistently about 60% of the incident wave energy.     

A residual analysis method for quantitative comparison of spatial data from the Iceland-Faeroes Front

A spatial statistical method has been developed from the well-known Kriging technique in geostatistics, as a way of providing quantitative comparison between a pair of spatial data sets, and a measure for such a comparison. This residual analysis method is applied to oceanographic data in order to compare Iceland-Faeroes Front (IFF) model predictions against appropriate field observations, with an aim to assess the IFF model performance and its prediction accuracy. The method is also used to evaluate the model-generated dynamical variability within the model predictions, as well as the natural variability within the frontal observations. From the results, it has been found that the IFF model is highly robust, and gives better predictions at depth 150–350 m than elsewhere. Within such a depth (i.e. 250–350 m), there is also evidence to suggest that the main frontal region is most active above the IF Ridge. The natural variability obtained from the observations appears to be comparable to the model-generated dynamical variability after 20 days of integration, indicating a certain degree of accuracy in the model predictions. The method reported in this paper could also be extended for further use in model data assimilation. Thus, the work not only demonstrates how spatial statistics can be applied to oceanographic data, but also opens up new statistical tools for data handling in ocean modelling.     

A statistical analysis of non-linear random waves

A statistical analysis of unidirectional non-linear random waves is presented which is based on second-order random wave theory. The analysis technique is similar to a method which is available for the statistical analysis of a two-term Volterra series. It is shown that the statistical problem can be reduced to that of finding the eigenvalues and eigenvectors of two real symmetric matrices, from which the cumulants, the characteristic function, and the probability density function of the surface elevation can be found. Various numerical examples are considered, and the possibility of extending the technique to deal with spreading seas is discussed.