Ultra-high pressure metamorphic rocks in the Dabie-Su-Lu region, China: Their formation and exhumation

Abstract Based on petrological, structural, geological and geochronological research, the authors summarize the progress of ultra-high pressure (UHP) metamorphic rock study since 1989 by Chinese geoscientists and foreign geoscientists in the Dabie-Su-Lu region. The authors introduce and discuss a two-stage exhumation process for the UHP metamorphic rocks that have various lithologies; eclogite, ultramafics, jadeitic quartzite, gneiss, schist and marble. The metamorphic history of UHP metamorphic rocks is divided into three stages, that is, the pre-eclogite stage, coesite eclogite stage, and retrograde stage. Prior to UHP metamorphism, the ultramafics had a high temperature environment assemblage of mantle and others had blueschist facies assemblages. The granulite facies assemblages, which have recorded a temperature increase event with decompression, have developed locally in the Weihai basaltic rocks. Isotopic ages show a long range from > 700 Ma to 200 Ma. The diversity in protoliths of UHP metamorphic rocks may be related to the variation of isotopic ages older than 400 Ma. The Sm-Nd dating of ~ 220 Ma could reflect the initial exhumation stage after the peak UHP metamorphism in relation to the collision between the Sino-Korean and Yangtze blocks and subsequent events. Petrological and structural evidence imply a two-stage exhumation process. During the initial exhumation, the UHP metamorphic rocks were sheared and squeezed up in a high P/T regime. In the second exhumation stage the UHP metamorphic rocks were uplifted and eventually exposed with middle crustal rocks.     

Ultrahigh-pressure garnet lherzolite from Chijiadian, Rongcheng County, in the Su-Lu region of eastern China

Abstract Petrological studies of a serpentinized garnet lherzolite body in Rongcheng of the Su-Lu region of eastern China revealed unusually high pressure. Spinel lherzolite probably in a subducting slab was transformed to garnet lherzolite at mantle depth. During exhumation, they were subsequently subjected to the granulite and then amphibolite overprinting and a phase of serpentinization. The peak P–T conditions of the garnet lherzolite estimated after detailed analysis of the metamorphic texture are 4–5 GPa and 820°C or 5–6 GPa and 780°C, depending on the chosen geothermobarometers. The lower dP/dT of the garnet lherzolite can be interpreted as the results of subduction of an old (say 100 Ma older than the time of collision) and cold, slab underneath the margin of the Sino–Korean craton.     

在砂土液化的危险性评价中确定性与不确定性方法的应用研究

地震导致的砂土液化具有很大的随机性。据此 ,提出了评价砂土液化危险性的确定性与不确定性两种方法。确定性方法是以液化指数为变量的多因子判别分析方法 ,不确定性方法是概率分析法 ,即用概率密度函数判断砂土液化灾害的期望损失值。     

我国东部新生代玄武岩岩石化学的一些探讨

新生代是地球上玄武质岩浆的主要活动期。在我国东部,新生代玄武岩分布也极广泛,由北往南自大兴安岭、松辽盆地经华北、苏闽浙至台湾、海南岛以及近海大陆架均有不同程度的出露。时间上从老第三纪至史期均有玄武岩喷发活动。     

Lg Coda Q and its Relation to the Geology and Tectonics of the Middle East

—Regional seismograms were collected to image the lateral variations of Lg coda Q at 1 Hz (Q ₀?) and its frequency dependence <(eta)> in the Middle East using a back-projection method. The data include 124 vertical-component traces recorded at 10 stations during the period 1986–1996. The resulting images reveal lateral variations in both Q ₀ and <eta>. In the Turkish and Iranian Plateaus, a highly deformed and tectonically active region, Q ₀ ranges between about 150 and 300, with the lowest values occurring in western Anatolia where extremely high heat flow has been measured. The low Q ₀ values found in this region agree with those found in other tectonically active regions of the world. Throughout most of the Arabian Peninsula, a relatively stable region, Q ₀ varies between 350 and 450, being highest in the shield area and lowest in the eastern basins. All values are considerably lower than those found in most other stable regions. Low Q values throughout the Middle East may be caused by interstitial fluids that have migrated to the crust from the upper mantle, where they were probably generated by hydrothermal reactions at elevated temperatures known to occur there. Low Q ₀ values (about 250) are also found in the Oman folded zone, a region with thick sedimentary deposits. <eta> varies inversely with Q ₀ throughout most of the Middle East, with lower values (0.4–0.5) in the Arabian Peninsula and higher values (0.6–0.8) in Iran and Turkey. Q ₀ and <eta> are both low in the Oman folded zone and western Anatolia.     

Seismic Velocity and Q Structure of the Middle Eastern Crust and Upper Mantle from Surface-wave Dispersion and Attenuation

—Observed velocities and attenuation of fundamental-mode Rayleigh waves in the period range 7–82 sec were inverted for shear-wave velocity and shear-wave Q structure in the Middle East using a two-station method. Additional information on Q structure variation within each region was obtained by studying amplitude spectra of fundamental-mode and higher-mode Rayleigh waves. We obtained models for the Turkish and Iranian Plateaus (Region 1), areas surrounding and including the Black and Caspian Seas (Region 2), and the Arabian Peninsula (Region 3). The effect of continent-ocean boundaries and mixed paths in Region 2 may lead to unrealistic features in the models obtained there. At lower crustal and upper-mantle depths, shear velocities are similar in all three regions. Shear velocities vary significantly in the uppermost 10 km of the crust, being 3.21, 2.85, and 3.39 km/s for Regions 1, 2, and 3, respectively. Q models obtained from an inversion of interstation attenuation data show that crustal shear-wave Q is highest in Region 3 and lowest in Region 1. Q’s for the upper 10 km of the crust are 63, 71, and 201 for Regions 1, 2, and 3, respectively. Crustal Q’s at 30 km depth for the three regions are about 51, 71, and 134. The lower crustal Q values contrast sharply with results from stable continental regions where shear-wave Q may reach one thousand or more. These low values may indicate that fluids reside in faults, cracks, and permeable rock at lower crustal, as well as upper crustal depths due to convergence and intense deformation at all depths in the Middle Eastern crust.     

Lg Coda Q and its Relation to the Structure and Evolution of Continents: A Global Perspective

—Tomographic maps of Lg coda Q (Q ^c _Lg) variation are now available for nearly the entire African, Eurasian, South American, and Australian continents, as well as for the United States. Q ^c _Lg at 1 Hz (Q ₀) varies from less than 200 to more than 1000 and Q ^c _Lg frequency dependence (<eta>) varies between 0.0 and nearly 1.0. Q ₀ appears to increase in proportion to the length of time that has elapsed since the most recent major episode of tectonic or orogenic activity in any region. A plot of Q ₀ versus time since that activity indicates that a single Q ₀-time relation approximates most mean Q ₀ values. Those that deviate most from the trend lay in Australia, the Arabian Peninsula, and the East African rift. The increase in Q ₀ with time may be due to a continual increase in crustal shear wave Q (Q ) caused by the loss of crustal fluids and reduction of crustal permeability following tectonic or orogenic activity. Extrapolated values of Q ^c _Lg at 5 Hz (using Q ₀ and <eta> values measured at 1 Hz and assuming that <eta> is constant in all regions between 1 and 5 Hz) show a similar percentage-wise increase with times that has elapsed since the most recent activity. Other factors that can reduce Q ₀ in continental regions include thick accumulations of sediment (especially sandstone and shale of Mesozoic age and younger), severe velocity gradients at the crust-mantle transition and, possibly, lateral variations in the depth, thickness, and severity of those gradients. Severe and large increases of Q in the mid-crust of some regions can cause relatively large values of <eta>, even if the frequency dependence of Q is small.     

11-deoxyheloside A的合成

首次完成天然胆甾烷型皂苷11-deoxyheloside A的合成。在相转移催化的条件下,葡萄糖溴苷1与膦酸单乙酯2反应以69%的收率得到葡萄糖膦酸酯供体3;以胆甾烷苷元4为原料,经Luche还原和乙酰化反应以及三氟甲磺酸负载硅胶脱除TBDPS基团得到胆甾烷二醇10;在金催化剂的作用下,胆甾二醇10与葡萄糖膦酸酯供体3进行糖苷化反应,然后脱除酰基保护基以97%的产率完成11-deoxyheloside A的合成。     

鄂尔多斯盆地西峰地区延长组烃源岩两环烷烃分布特征及其生源

鄂尔多斯盆地西南部西峰地区三叠系延长组烃源岩检出丰富的两环烷烃,主要为C12~C14和C15、C16两组两环烷烃。其相对丰度表现出3种源岩模式:1以低碳数两环烷烃为主,出现于长71和长81段非烃源岩;2两组两环烷烃都很丰富,出现于长73段富有机质烃源岩;3以高碳数两环烷烃为主,主要发现于长73段烃源岩,也见于长72和长81段。尽管长7段热演化程度基本一致,但补身烷异构化指数变化明显,表明补身烷重排不仅受热演化的影响,而且受有机质来源和沉积环境的控制。延长组烃源岩具有明显的高补身烷优势,反映了烃源岩的还原性沉积环境。烃源岩高丰度C15、C16两环烷烃的检出则指示该地区晚三叠世发育淡水湖泊。葡萄藻不仅是该地区中生界石油的重要母质来源,而且可能是这些两环类标志物的直接生源。