Terracette morphology and soil properties: A note on a canonical correlation study

Morphological and soil properties of terracettes have been examined using canonical correlation methods. Highly significant statistical relationships have been found linking some members of the soil property set to the morphological properties of the terracettes studied.     

A Methodology for Assessing Landslide Hazard Using Deterministic Stability Models

Deterministic stability models are used to assess the potential for mass movement within Hamilton City, New Zealand using sensitivity analysis for critical environmental variables. Discrete geomorphic zones are recognised on the basis of material properties and slope characteristics; generic slope profiles are derived for each of these zones by averaging slope profiles determined from a Digital Elevation Model. Stability analysis models are used to derive critical failure surfaces for these profiles using measured or estimated material properties, and sensitivity analysis allows the conditions of water table level and seismic acceleration under which the slopes become unstable to be determined. This method is applied to Hamilton City to assess the citywide hazard associated with mass movement. For the slopes studied, conditions of elevated water table alone may initiate failure, but this is seen as unlikely as the materials are well drained. Combinations of water tables above 10% of the slope elevation together with seismic accelerations of approximately 0.2 g (150 year return period) represent likely failure conditions for many slopes. This information provides emergency management planners with estimates of the likely extent of failure in different regions of the city, and hence facilitates identification of lifelines and infrastructure at risk. The method cannot provide site-specific information, but in combination with knowledge of cultural features gives indications of critical locations where detailed engineering assessments are required.     

Pedestal craters on Ganymede

The high-resolution Voyager images of Ganymede show a class of fresh craters 6–89 km in diameter which is distinguished by an ejecta blanket similar to those seen for some types of Martian craters. One hundred and eighty-five were identified and studied for trends with respect to latitude, longitude, and terrain type. No correlation of the ratio of ejecta diameter to crater diameter was found as a function of latitude or longitude, and there is only a suggestion of a trend in this ratio with respect to major terrain types. Central peak frequency is greatest for the smaller crater diameters. Central pit occurrence dominates central peak occurrence at crater diameters ?35 km. We conclude that the ejecta morphology probably results from impact into an icy target. The question of whether atmospheric ejecta-particle drag contributes to ejecta blanket morphologies on planets with an atmospheric cannot be resolved entirely from the Voyager images. The image resolution is insufficient to show diagnostic flow features on the ejecta, if they exist, or to detect evidence of any other ejecta deposits which would lie beyond the pedestal, predicted by some researchers to exist only on bodies with an atmosphere.     

Local community training and education in southern Tanzania—a case study

Local coastal communities are highly dependent upon the marine environment not only for protein but also as a primary source of income. In addition, there are growing economic opportunities offered within the coastal zone. As populations increase in these areas there is an increasing demand on coastal resources. This in turn requires effective management initiatives at regional, national and local levels.The Marine Education and Training Programme in Mtwara, southern Tanzania was a small scale capacity building project that incorporated two elements; a primary schools field day education programme and a marine coastal resources course for fishermen and women from the Mtwara District. The programme ran for a period of 1 year and during that time 14 schools, 198 children, 34 fishermen, 2 women and 14 villages participated. Results from preliminary evaluation indicated that such education is not only welcome by the local government offices, teachers, village chairmen and fishermen as an expansion of the knowledge base, but is also an important and valuable stepping stone for the local communities to become active in issues regarding the management of coastal resources.     

Interpreting nanoscale size-effects in aggregated Fe-oxide suspensions: Reaction of Fe(II) with Goethite

The Fe(II)/Fe(III) redox couple plays an important role in both the subsurface fate and transport of groundwater pollutants and the global cycling of carbon and nitrogen in iron-limited marine environments. Iron oxide particles involved in these redox processes exhibit broad size distributions, and the recent demonstrations of dramatic nanoscale size-effects with various metal oxides has compelled us, as well as many others, to consider whether the rate and extent of Fe(II)/Fe(III) cycling depends upon oxide particle size in natural systems. Here, we investigated the reaction of Fe(II) with three different goethite particle sizes in pH 7.5 suspensions. Acicular goethite rods with primary particle dimensions ranging from 7 by 80 nm to 25 by 670 nm were studied. Similar behavior with respect to Fe(II) sorption, electron transfer and nitrobenzene reduction was observed on a mass-normalized basis despite almost a threefold difference in goethite specific surface areas. Scanning electron microscopy (SEM) images, dynamic light scattering (DLS) and sedimentation measurements all indicated that, at pH 7.5, significant aggregation occurred with all three sizes of goethite particles. SEM images further revealed that nanoscale particles formed dense aggregates on the order of several microns in diameter. The clear formation of particle aggregates in solution raises questions regarding the use of primary particle surface area as a basis for assessing nanoscale size-effects in iron oxide suspensions at circum-neutral pH values. In our case, normalizing the Fe(II) sorption densities and rate constants for nitrobenzene reduction by BET surface area implies that goethite nanoparticles are less reactive than larger particles. We suspect, however, that aggregation is responsible for this observed size-dependence, and argue that BET values should not be used to assess differences in surface site density or intrinsic surface reactivity in aggregated particle suspensions. In order to realistically assess nanoscale size-effects in environmentally relevant systems that are likely to aggregate, new methods are needed to quantify the amount of surface area accessible for sorption and reaction in wet nanoparticle suspensions, rather than assuming that this value is equivalent to the surface area determined from the characterization of dry nanoparticles.