U and Th content in the Central Apennines continental crust: A contribution to the determination of the geo-neutrinos flux at LNGS

The regional contribution to the geo-neutrino signal at Gran Sasso National Laboratory (LNGS) was determined based on a detailed geological, geochemical and geophysical study of the region. U and Th abundances of more than 50 samples representative of the main lithotypes belonging to the Mesozoic and Cenozoic sedimentary cover were analyzed. Sedimentary rocks were grouped into four main “reservoirs” based on similar depositional settings and mineralogy. The initial assumption that similar chemico-physical depositional conditions would lead to comparable U and Th contents, was then confirmed by chemical analyses. Basement rocks do not outcrop in the area. Thus U and Th in the upper and lower crust of Valsugana and Ivrea-Verbano areas were analyzed. Irrespective of magmatic or metamorphic origin lithotypes were subdivided into a mafic and an acid reservoir, with comparable U and Th abundances.Based on geological and geophysical properties, relative abundances of the various reservoirs were calculated and used to obtain the weighted U and Th abundances for each of the three geological layers (sedimentary cover, upper and lower crust). Using the available seismic profile as well as the stratigraphic records from a number of exploration wells, a 3D modeling was developed over an area of 2° × 2° down to the Moho depth, for a total volume of about 1.2 × 10⁶ km³. This model allowed us to determine the volume of the various geological layers and eventually integrate the Th and U contents of the whole crust beneath LNGS.On this base the local contribution to the geo-neutrino flux (S) was calculated and added to the contribution given by the rest of the world, yielding a refined reference model prediction for the geo-neutrino signal in the Borexino detector at LNGS: S(U) = (28.7 ± 3.9) TNU and S(Th) = (7.5 ± 1.0) TNU. An excess over the total flux of about 4 TNU was previously obtained by Mantovani et al. (2004) who calculated, based on general worldwide assumptions, a signal of 40.5 TNU. The considerable thickness of the sedimentary rocks, almost predominantly represented by U- and Th-poor carbonatic rocks in the area near LNGS, is responsible for this difference. Thus the need for detailed integrated geological study is underlined by this work, if the usefulness of the geo-neutrino flux for characterizing the global U and Th distribution within the Earth’s crust, mantle and core is to be realized.     

The sagging deep-seated gravitational movements on the eastern side of Mt. Amiata (Tuscany,Italy)

The eastern side of the Mt. Amiata volcano is affected by a series of deep-seated gravitational slope deformations (DsGSDs). The San Piero and the Podere Mezzavia DsGSDs affect the lower part of the slope. The main escarpments are located on the outer edges of the lava flows, but the landslides mostly affect the pre-volcanic Ligurian Terrains. A deeper movement, possibly exceeding 100 m in thickness, is evidenced by a long trench at the base of the main escarpment that indicates a sagging type movement. This deeper movement is responsible for the activation of a series of superficial rock and mud flows that show evidence of ongoing activity. The most likely location of the sliding surface is the tectonized contact between the Santa Fiora and Argille a Palombini Fms within the Ligurian units, although the superficial landslides prevent our determining with certainty if a clear-cut sliding surface already developed connecting the upper and the lower parts of the slope. These DsGSDs were activated along the flanks of a larger movement that affects the lava flow units cropping out in the middle slope of the volcano. A long main escarpment, secondary escarpments, trenches and borehole data suggest that the thickness could locally exceed 200 m and generate another sagging type movement. Up-slope and up-movement-facing counterscarps indicate the existence of a listric elongated spoon-shaped compound embryonic sliding surface. This sagging, which hosts the towns of Abbadia San Salvatore and Piancastagnaio, appears to be in a quiescent stage, according to preliminary monitoring with a global positioning system (GPS) network. The downcutting of the river network along the softer Pliocene terrains of the Radicofani basin is enhanced by the general uplift of the Apennines and seems to be the major factor in the activation of these DsGSDs.     

Reclamation influence and background geochemistry of neutral saline soils in the Po River Delta Plain (Northern Italy)

Reclaimed neutral saline sulphate soils constitute a large part of the eastern part of Po Plain lowlands, where intensive agricultural activities take place. The knowledge of their geochemical features is essential to develop the best management practices capable to preserve this threatened environment. With this aim, three boreholes were drilled in an agricultural field and a typical reclaimed soil profile has been characterized for major and trace element, pH, electrical conductivity, redox conditions and water-soluble anions and ammonium. Statistical analysis (cluster analysis and principal component analysis) has been used to understand the relationship between elements and grain size. The soil profile is characterized by high salinity and high organic matter contents responsible for high chloride, sulphate, and ammonium concentrations. Heavy metal content is naturally high, since Po Plain sediments are the result of ultramafic rocks erosion; in addition, organic matter tends to concentrate heavy metals by adsorption, mainly in peaty horizons. As a consequence of chemical and zootechnical fertilization, high NO₃ ^? contents have been found in the top soil, thus enhancing the risk of nitrate discharge in the water system, especially in relation to extreme climatic events.     

The contemporaneous emission of low-K and high-K trachybasalts and the role of the NE Rift during the 2002 eruptive event,Mt. Etna,Italy

Mount Etna volcano erupted almost simultaneously on its northeastern and southern flanks between October 27 and November 3, 2002. The eruption on the northeastern flank lasted for 8 days, while on the southern flank it continued for 3 months. The northeastern flank eruption was characterized by the opening of a long eruptive fracture system between 2,900 and 1,900 m.a.s.l. A detailed survey indicates that the fractures’ direction shifted during the opening from N10W (at the NE Crater, 2,900 m) to N45E (at its lowest portion, 1,900 m) and that distinct magma groups were erupted at distinct fracture segments. Based on their petrological features, three distinct groups of rocks have been identified. The first group, high-potassium porphyritic (HKP), is made up of porphyritic lavas with a Porphyritic Index (P.I.) of 20–32 and K₂O content higher than 2 wt%. The second group is represented by lavas and tephra with low modal phenocryst abundance (P.I. < 20) named here oligo-phyric (low-phyric), and K₂O content higher than 2 wt% (HKO, high-potassium oligophyric). The third group, low-potassium oligophyric (LKO), consists of tephra with oligophyric texture (P.I. < 20) but K₂O content < 2 wt%. K-rich magmas (HKP and HKO) are similar to the magma erupted on the southern flank, and geochemical variations within these groups can be accounted for by a variable degree of fractionation from a single parent magma. The K-poor magma (LKO), erupted only in the upper segment of the fracture, cannot be placed on the same liquid line of descent of the HK groups, and it is similar to the magmas that fed the activity of Etna volcano prior to the eruption of 1971. This is the first time since then that a magma of this composition has been documented at Mt. Etna, thus providing a strong indication for the existence of distinct batches of magma whose rise and differentiation are independent from the main conduit system. The evolution of this eruption provides evidence that the NE Rift plays a very active role in the activity of Mt. Etna volcano, and that its extensional tectonics allows the intrusion and residence of magma bodies at various depths, which can therefore differentiate independently from the main open conduit system.     

Late Pleistocene stratigraphy, sedimentology and paleoenvironmental evolution of the Tarija-Padcaya basin (Bolivian Andes)

We illustrate the results of geomorphological, stratigraphical and sedimentological analysis of the Tarija-Padcaya basin, a wide depression in the eastern side of the Bolivian Cordillera. The basin is well known for the rich mammal fauna discovered since the beginning of the 19th century. The sedimentary infilling belongs to the Tolomosa Formation, corresponding to a major synthem subdivided into three main sub-synthems, mostly made of fluvial and alluvial fan sediments locally weathered by paleoalfisols (Ancon Grande sub-synthem), glacial and fluvio-glacial sediments (Puente Phayo sub-synthem) and finally alluvial fan and alluvial plain sediments (San Jacinto sub-synthem). Radiocarbon dating provides a chronology for the last sub-synthem and testifies that the sequence encompasses the Last Interglacial-Glacial cycle and constitutes a good proxy record for Late Pleistocene climatic changes. The occurrence of glacial deposits in the deeper part of the sedimentary filling suggests a major ice advance during MIS 4 and, together with glacial geomorphological evidence, points to further glacial erosion during the Last Glacial Maximum (LGM). The importance of glacial deposition and erosion opens the question of correlation with the events reported in the nearby Altiplano, where glacial deposits have been recognized only along the slopes of the higher volcanoes. In the Altiplano the LGM has been claimed to be characterized by an absence of deposition or deep erosion, due to extreme dryness, but the Tarija record suggests an erosional event of a scale that would imply the occurrence of a large ice cap.     

Petrogenesis and evolution of Mt. Vulture alkaline volcanism (Southern Italy)

Summary The Late Pleistocene Mt. Vulture strato-volcano developed at the intersection of NE-SW and NW-SE lithospheric fault systems, on the easternmost border of the Apennine compressional front overthrust onto the Apulian foreland. The initial phase of the volcanic activity is represented by pyroclastic deposits, including lava blocks, and subordinate eccentric domes, mostly phonolitic in composition. The later stages of activity formed the bulk of the strato-volcano (pyroclastic products and subordinate lavas), mostly tephritic in composition, with minor intercalations of basanite, mela-foidite and melilitite lavas and dikes. Variations in rock and mineral composition suggest that the volumetrically predominant basanite-tephrite (foidite)-phonotephrite-phonolite series can be accounted for by fractional crystallization processes starting from basanitic parental magmas, in agreement with the remarkably constant ⁸⁷Sr/⁸⁶Sr isotopes (0.70586–0.70581). Mass-balance calculations indicate that the variably differentiated magmas may have been produced by removal of wehrlite, clinopyroxenite and syenite cumulates, some of which are occasionally found as cognate xenoliths in the volcanics. Fractionation processes probably developed in multiple-zoned magma chambers, at depths of 3–5 km, corresponding to the tectonic discontinuity between the allochthonous Apennine formations and the underlying Apulian platform. Highly differentiated phonolitic magmas capping the magma chambers and their conduits thus appear to have fed the initial volcanic activity, whereas dominantly tephritic products were erupted in later stages. The least evolved mafic magmas, namely basanites, mela-foidites and melilitites, are characterized by diverse Na/K ratios and critical SiO₂-undersaturation, which indicate their derivation as independent melts generated from distinct, heterogeneously enriched mantle sources and by variable partial melting degrees. Primitive mantle-normalized incompatible element patterns of Vulture mafic lavas invariably share analogies with both orogenic subduction-related magmas (high Low Field Strength Elements/High Field Strength Elements ratios, K, Rb and Th contents and marked Ti and Nb negative anomalies) and alkaline lavas from within-plate and rift settings (high Light Rare Earth Elements, P, Zr, Nb and Na). These geochemical features may be accounted for by magma generation from deep lithospheric mantle sources, enriched in Na-alkali silicate/carbonatite anorogenic components, subsequently affected by orogenic subduction-related K-metasomatism, analogous to that which modified magma sources of the Roman Magmatic Province along the internal Apennine Chain. Received April 12, 2000; revised version accepted June 7, 2001     

Geochemical constraints and uranium potential of the younger granitic rocks in El Maghrbia area,Central Eastern Desert,Egypt

Acta Geochimica - The present work deals with the mineralogy, geochemical behavior and uranium potentiality of the monzogranites of El Maghrbia area, which comprise G. El Maghrbia and G. El Eredyia...     

Intrusion of shoshonitic magmas at shallow crustal depth: <Emphasis Type="Italic">T</Emphasis>–<Emphasis Type="Italic">P</Emphasis> path,H<Subscript>2</Subscript>O estimates,and AFC modeling of the Middle Triassic Predazzo Intrusive Complex (Southern Alps,Italy)

The multi-pulse shoshonitic Predazzo intrusive complex represents an ideal igneous laboratory for investigating the chemical and physical conditions of magma emplacement in a crustal context, since numerical models can be constrained by field evidence. It constitutes the most intriguing remnant of the Middle Triassic magmatic systems of the Dolomitic Area (Southern Alps), preserved by the Alpine tectonics. Predazzo Intrusive Complex comprises silica saturated (pyroxenites/gabbros to syenites), silica undersaturated (gabbros to syenites), and silica oversaturated (granites and syenogranites) rock suites. In this paper, we modeled its emplacement and evolution with a multiple thermo-/oxy-barometric, hygrometric, and EC-AFC approach. At odds with what proposed in literature but according to the field evidence, the emplacement of the Predazzo Intrusive Complex occurred at shallow depth (<?6 km). In this context, the different pulses differed slightly in bulk water content, but shared a common thermal regime, with temperatures between 1000 and 1100 °C and ~?600 °C at low-to-moderate oxidizing conditions (? 0.1 to +?0.7 ΔFMQ). The interaction between the intrusion and the shallow crustal rocks was minimal, with Sr and Nd isotopic compositions indicating an average of 5–6% assimilation of crust. A thermo- and oxy-barometric comparison with the nearby Mt. Monzoni also enabled to speculate about the solidification time of the intrusion, which we infer took place over about 700 ka.     

Petrological evolution of the Middle Triassic Predazzo Intrusive Complex,Italian Alps

The Predazzo Intrusive Complex (PIC), a Ladinian plutonic body located in the Southern Alps (NE Italy), is made up of a 4.5 km³ gabbroic to syenitic and syenogranitic intrusion, basaltic to latitic volcanic products (about 6 km³ in volume) and by an extended dike swarm intruding both intrusive and volcanic rocks. An extensive field survey of the complex, followed by detailed petrographic and geochemical analyses, allowed the identification of three different magmatic units: a Shoshonitic Silica Saturated Unit (SS), 3.1 km³ in volume, a Shoshonitic Silica Undersaturated Unit (SU), 0.3 km³ in volume, and a Granitic Unit (GU), 1.1 km³ in volume. K-affinity, marked Nb and Ti negative anomalies and a strong Pb enrichment are distinctive markers for all PIC lithotypes. A general HFSE (Th, U, Pb), LREE (La, Ce, Pr, Nd) and Na enrichment characterizes the SU suite with respect to the SS series. Mass balance calculations, based on major and trace element whole rock and mineral compositions, have been used to simulate the fractionation process of SS and SU suites, showing (i) the complexity of the evolutionary stages of the PIC and (ii) the analogy between the calculated subtracted solid assemblages and the natural cumulitic lithotypes outcropping in the area. The field relationships between the various portions of the intrusive complex, the volcanic products and the dike swarm define the temporal evolution of the PIC, in which the SS magma batch was followed by the GU and later on by the SU intrusion. The presence, in both eastern and western portions of the complex, of a transitional magmatic contact between the intrusive rocks of the SS suite and the volcanics is not in favour of the hypothesis of a caldera collapse to explain the ring-like shape of the PIC.