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81.
Multi-species reactive transport equations coupled through sorption and sequential first-order reactions are commonly used to model sites contaminated with radioactive wastes, chlorinated solvents and nitrogenous species. Although researchers have been attempting to solve various forms of these reactive transport equations for over 50 years, a general closed-form analytical solution to this problem is not available in the published literature. In Part I of this two-part article, we derive a closed-form analytical solution to this problem for spatially-varying initial conditions. The proposed solution procedure employs a combination of Laplace and linear transform methods to uncouple and solve the system of partial differential equations. Two distinct solutions are derived for Dirichlet and Cauchy boundary conditions each with Bateman-type source terms. We organize and present the final solutions in a common format that represents the solutions to both boundary conditions. In addition, we provide the mathematical concepts for deriving the solution within a generic framework that can be used for solving similar transport problems. 相似文献
82.
Drivers of afforestation in Northern Vietnam: Assessing local variations using geographically weighted regression 总被引:2,自引:0,他引:2
Floriane Clement Didier Orange Meredith Williams Corinne Mulley Michael Epprecht 《Applied geography (Sevenoaks, England)》2009,29(4):561-576
This article identifies drivers of forest transition in a province of Northern Vietnam between 1993 and 2000 by applying geographically weighted regression (GWR) analysis to remotely sensed and statistical data. The regression model highlighted the spatial variation of the relationship between the percentage of land afforested and its proximate causes. Factors identified as having a major impact on afforestation are: the presence or proximity of a wood-processing industry, the distance to highways, and land allocation to households. Whereas the two former variables are in most areas of the province positively correlated with afforestation, an unexpected negative correlation was observed for the latter. The analysis of these results, supported by an in-depth knowledge of the area and of the political context, leads to the conclusion that, during the time period considered, afforestation was largely driven by state organisations on protected state-owned land, and forestry was not a significant component of household economic activities. 相似文献
83.
Threshold of motion and settling velocities of mollusc shell debris: Influence of faunal composition
Alissia Rieux Pierre Weill Dominique Mouaze Clement Poirier Farid Nechenache Laurent Perez Bernadette Tessier 《Sedimentology》2019,66(3):895-916
Bioclastic particles derived from mollusc shell debris can represent a significant fraction of sandy to gravelly sediments in temperate and cool‐water regions with high carbonate productivity. Their reworking and subsequent transport and deposition by waves and currents is highly dependent on the shape and density of the particles. In this study, the hydrodynamic behaviour of shell debris produced by eight mollusc species is investigated for several grain sizes in terms of settling velocity (measurements in a settling tube) and threshold of motion under unidirectional current (flume experiments using an acoustic profiler). Consistent interspecific differences in settling velocity and critical bed shear stress are found, related to differences in shell density, shell structure imaged by scanning electron microscopy and grain shape. Drag coefficients are proposed for each mollusc species, based on an interpolation of settling velocity data. Depending on the shell species, the critical bed shear stress values obtained for bioclastic particles fall within or slightly below empirical envelopes established for siliciclastic particles, despite very low settling velocity values. The results suggest that settling velocity, often used to describe the entrainment of sediment particles through the equivalent diameter, is not a suitable parameter to predict the initiation of motion of shell debris. The influence of the flat shape of bioclastic particles on the initiation of motion under oscillatory flows and during bedload and saltation transport is yet to be elucidated. 相似文献
84.
We review the methodologies used to quantify climate feedbacks in coupled models. The method of radiative kernels is outlined and used to illustrate the dependence of lapse rate, water vapor, surface albedo, and cloud feedbacks on (1) the length of the time average used to define two projected climate states and (2) the time separation between the two climate states. Except for the shortwave component of water vapor feedback, all feedback processes exhibit significant high-frequency variations and intermodel variability of feedback strengths for sub-decadal time averages. It is also found that the uncertainty of lapse rate, water vapor, and cloud feedback decreases with the increase in the time separation. The results suggest that one can substantially reduce the uncertainty of cloud and other feedbacks with the accumulation of accurate, long-term records of satellite observations; however, several decades may be required. 相似文献
85.
86.
Yogesh Kant B. D. Bharath Javed Mallick Clement Atzberger Norman Kerle 《Journal of the Indian Society of Remote Sensing》2009,37(2):201-214
The knowledge of the surface temperature is important to a range of issues and themes in earth sciences central to urban climatology,
global environmental change and human-environment interactions. The study analyses land surface temperature (LST) estimation
using temporal ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) datasets (day time and night time) over
National Capital Territory Delhi using the surface emissivity information at pixel level. The spatial variations of LST over
different land use/land cover (LU/LC) at day time and night time were analysed and relationship between the spatial distribution
of LU/LC and vegetation density with LST was developed. Minimum noise fraction (MNF) was used for LU/LC classification which
gave better accuracy than classification with original bands. The satellite derived emissivity values were found to be in
good agreement with literature and field measured values. It was observed that fallow land, waste land/bare soil, commercial/industrial
and high dense built-up area have high surface temperature values during day time, compared to those over water bodies, agricultural
cropland, and dense vegetation. During night time high surface temperature values are found over high dense built-up, water
bodies, commercial/industrial and low dense built-up than over fallow land, dense vegetation and agricultural cropland. It
was found that there is a strong negative correlation between surface temperature and NDVI over dense vegetation, sparse vegetation
and low dense built-up area while with fraction vegetation cover, it indicates a moderate negative correlation. The results
suggest that the methodology is feasible to estimate NDVI, surface emissivity and surface temperature with reasonable accuracy
over heterogeneous urban area. The analysis also indicates that the relationship between the spatial distribution of LU/LC
and vegetation density is closely related to the development of urban heat islands (UHI). 相似文献
87.
Martin Schlerf Clement Atzberger Joachim Hill Henning Buddenbaum Willy Werner Gebhard Schüler 《International Journal of Applied Earth Observation and Geoinformation》2010
The research evaluated the information content of spectral reflectance (laboratory and airborne data) for the estimation of needle chlorophyll (CAB) and nitrogen (CN) concentration in Norway spruce (Picea abies L. Karst.) needles. To identify reliable predictive models different types of spectral transformations were systematically compared regarding the accuracy of prediction. The results of the cross-validated analysis showed that CAB can be well estimated from laboratory and canopy reflectance data. The best predictive model to estimate CAB was achieved from laboratory spectra using continuum-removal transformed data (R2cv = 0.83 and a relative RMSEcv of 8.1%, n = 78) and from hyperspectral HyMap data using band-depth normalised spectra (R2cv = 0.90, relative RMSEcv = 2.8%, n = 13). Concerning the nitrogen concentration, we observed somewhat weaker relations, with however still acceptable accuracies (at canopy level: R2cv = 0.57, relative RMSEcv = 4.6%). The wavebands selected in the regression models to estimate CAB were typically located in the red edge region and near the green reflectance peak. For CN, additional wavebands related to a known protein absorption feature at 2350 nm were selected. The portion of selected wavebands attributable to known absorption features strongly depends on the type of spectral transformation applied. A method called “water removal” (WR) produced for canopy spectra the largest percentage of wavebands directly or indirectly related to known absorption features. The derived chlorophyll and nitrogen maps may support the detection and the monitoring of environmental stressors and are also important inputs to many bio-geochemical process models. 相似文献
88.
Numerous paleoecological questions concern the mobility of ancient fauna in eastern Beringia. Strontium (Sr) isotope ratio (87Sr/86Sr) analysis has emerged as a powerful tracer for determining the provenance of ancient biological materials. However, it is important to characterize 87Sr/86Sr variation across a landscape. We measured the 87Sr/86Sr composition of teeth from present-day, herbivorous rodents (n = 162) sampled from across eastern Beringia to estimate bio-available 87Sr/86Sr values. We compiled these data with the very limited number of previously published 87Sr/86Sr values from the region. We then used this dataset and a machine learning, random-forest regression to predict bio-available 87Sr/86Sr variations across eastern Beringia. As a case study using our new 87Sr/86Sr map (isoscape), we measured the 87Sr/86Sr and oxygen stable isotope values (δ18O) of five radiocarbon-dated steppe bison from eastern Beringia and compared these to our 87Sr/86Sr isoscape and a δ18O isoscape to estimate the probable landscape use of these ancient fauna. Our model and isoscape provide important foundations for a wide range of additional applications, including studies of the paleo-mobility of other fauna, ancient people and present-day fauna in eastern Beringia. 相似文献
89.
Microbial Mn(II) oxidation kinetics in response to oxygen concentration were assessed in suboxic zone water at six sites throughout the Black Sea. Mn(II) oxidation rates increased asymptotically with increasing oxygen concentration, consistent with Michaelis-Menten enzyme kinetics. The environmental half-saturation constant, KE, of Mn(II) removal (oxidation) varied from 0.30 to 10.5 μM dissolved oxygen while the maximal environmental rate, VE−max, ranged from 4 to 50 nM h−1. These parameters varied spatially and temporally, consistent with a diverse population of enzymes catalyzing Mn oxide production in the Black Sea. Coastally-influenced sites produced lower KE and higher VE−max constants relative to the Western and Eastern Gyre sites. In the Bosporus Region, the Mn(II) residence time calculated using our KE and VE−max values with 0.1 μM oxygen was 4 days, 25-fold less than previous estimates. Our results (i) indicate that rapid Mn(II) oxidation to solid phase Mn oxides in the Black Sea’s suboxic zone is stimulated by oxygen concentrations well below the 3-5 μM concentration reliably detected by current oceanographic methods, (ii) suggest the existence of multiple, diverse Mn(II)-oxidizing enzymes, (iii) are consistent with shorter residence times than previously calculated for Mn(II) in the suboxic zone and (iv) cast further doubt on the existence of proposed reactions coupling solid phase Mn oxide production to electron acceptors other than oxygen. 相似文献
90.
Domenico solution--is it valid? 总被引:1,自引:0,他引:1
The Domenico solution is widely used in several analytical models for simulating ground water contaminant transport scenarios. Unfortunately, many textbook as well as journal article treatments of this approximate solution are full of empirical statements that are developed without mathematical rigor. For this reason, a rigorous analysis of this solution is warranted. In this article, we present a mathematical method to derive the Domenico solution and explore its limits. Our analysis shows that the Domenico solution is a true analytical solution when the value of longitudinal dispersivity is zero. For nonzero longitudinal dispersivity values, the Domenico solution will introduce a finite amount of error. We use an example problem to quantify the nature of this error and suggest some general guidelines for the appropriate use of this solution. 相似文献