Effect of water on the fluorine and chlorine partitioning behavior between olivine and silicate melt

Halogens show a range from moderate (F) to highly (Cl, Br, I) volatile and incompatible behavior, which makes them excellent tracers for volatile transport processes in the Earth’s mantle. Experimentally determined fluorine and chlorine partitioning data between mantle minerals and silicate melt enable us to estimate Mid Ocean Ridge Basalt (MORB) and Ocean Island Basalt (OIB) source region concentrations for these elements. This study investigates the effect of varying small amounts of water on the fluorine and chlorine partitioning behavior at 1280?°C and 0.3 GPa between olivine and silicate melt in the Fe-free CMAS+F–Cl–Br–I–H₂O model system. Results show that, within the uncertainty of the analyses, water has no effect on the chlorine partitioning behavior for bulk water contents ranging from 0.03 (2) wt% H₂O (D_Cl ^ol/melt = 1.6?±?0.9 × 10^?4) to 0.33 (6) wt% H₂O (D_Cl ^ol/melt = 2.2?±?1.1 × 10^?4). Consequently, with the effect of pressure being negligible in the uppermost mantle (Joachim et al. Chem Geol 416:65–78, 2015), temperature is the only parameter that needs to be considered for the determination of chlorine partition coefficients between olivine and melt at least in the simplified iron-free CMAS+F–Cl–Br–I–H₂O system. In contrast, the fluorine partition coefficient increases linearly in this range and may be described at 1280?°C and 0.3 GPa with (R ²?=?0.99): \(D_{F}^{\text{ol/melt}}\ =\ 3.6\pm 0.4\ \times \ {{10}^{-3}}\ \times \ {{X}_{{{\text{H}}_{\text{2}}}\text{O}}}\left( \text{wt }\!\!\%\!\!\text{ } \right)\ +\ 6\ \pm \ 0.4\times \,{{10}^{-4}}\). The observed fluorine partitioning behavior supports the theory suggested by Crépisson et al. (Earth Planet Sci Lett 390:287–295, 2014) that fluorine and water are incorporated as clumped OH/F defects in the olivine structure. Results of this study further suggest that fluorine concentration estimates in OIB source regions are at least 10% lower than previously expected (Joachim et al. Chem Geol 416:65–78, 2015), implying that consideration of the effect of water on the fluorine partitioning behavior between Earth’s mantle minerals and silicate melt is vital for a correct estimation of fluorine abundances in OIB source regions. Estimates for MORB source fluorine concentrations as well as chlorine abundances in both mantle source regions are within uncertainty not affected by the presence of water.     

Hydraulic evolution and total suspended solids capture of an infiltration trench

Stormwater best management practice (BMP) design must incorporate the expected long‐term performance from both a water quantity and water quality perspective to sustainably mitigate hydrologic and water quality impacts of development. Infiltration trench structures are one of many infiltration BMPs that reduce runoff volume and capture pollutants. Research on the longevity of these structures is sparse, leading to concerns about their long‐term value and impeding implementation. In the present study, an infiltration trench was monitored from its inception to determine its hydrologic performance over time and total suspended solids (TSS) capture efficiency. The infiltration trench was intentionally undersized to accelerate longevity‐related processes. The infiltration trench provided a 36% TSS removal rate and displayed a distinct decrease in its ability to infiltrate stormwater runoff over the first three years of operation. Results indicate that infiltration through the bottom of the BMP became negligible, while infiltration through the sides of the BMP remained active over the 3‐year study period. The results lead to recommendations for BMP design. Copyright © 2010 John Wiley & Sons, Ltd.     

Merging circulations on Jupiter: Observed differences between cyclonic and anticyclonic mergers

The dynamics of mergers of large circulations in Jupiter's atmosphere may permit different models of the atmosphere to be tested. We report well-resolved observations of such events at visible wavelengths: three anticyclonic and three cyclonic events. A merger of anticyclonic white ovals in the South South Temperate domain (2002 March) is compared with the previously reported merger of ovals BE and FA in the South Temperate domain (2000 March). In each case, the two similar-sized ovals converged rapidly once they were separated by less than the sum of their diameters; they orbited around each other anticyclonically during the merger; the merged oval initially had the same rapid drift as the western parent; and, in an unexpected similarity, a cyclonic oval emerged westward from the point of merger. Evidence suggests that a merger of smaller ovals in the North North Temperate domain (2002 February) had similar dynamics. In contrast, mergers of cyclonic ovals in the North Equatorial Belt (‘barges’: 2001 November, 2005 May) proceeded in a different manner. The two parent barges showed no consistent acceleration towards each other as they converged; on contact there was no obvious sign of mutual circulation, and the low-albedo regions had almost passed each other before they finally merged; and the resulting barge had a drift rate intermediate between the two parents, and a length that was greater than either parent. Again, a third such event involving a smaller barge (2002 December) showed many of the same characteristics. These observations define different dynamical behaviour during anticyclonic and cyclonic mergers.     

Plasma clouds associated with Comet P/Borrelly dust impacts

The NASA DS1 spacecraft encountered Comet P/Borrelly on September 22, 2001 at a distance of ∼2171 km on the sunward side of the comet. The flyby speed was ∼16.5 km s⁻¹. Using high temporal resolution (50 μs) absolute electric field amplitude measurements from a ∼1 m dipole antenna, new features of plasma clouds created by cometary dust impacts have been detected. The pulses have 1/e exponential decays of ∼650 μs duration, exponentially shaped overshoots with rise times of ∼2 ms, and exponential-shaped overshoot decay times of ∼10 ms. Assuming a plasma temperature of 10⁴ K, these pulse features have been explained as plasma cloud space charge effects from the electron, proton and heavy ion portions of the clouds passing the antenna. Complex pulse shapes were also detected. These are believed to be due to either plasma cloud scattering off of the spacecraft, or to secondary impacts. Small electric pulses of duration 10-15 ms of cometary origin were detected but are presently unexplained. The electric component of the plasma wave spectra at closest approach had an f^−2.4 power law shape from 10 Hz to 1 kHz. The electron cyclotron frequency was approximately 1 kHz. One possible explanation of the wave spectrum is that whistler mode waves associated with phase steepened cometary plasma waves are dispersed, leading to the broad spectrum. Finally, based on the present results, a new type of low-cost, large-area dust detector is proposed.     

Carbon dioxide fluxes and DOC concentrations of eroding blanket peat gullies

UK peatlands are affected by severe gully erosion with consequent impacts on ecosystem services from these areas. Incision into the peat can damage the vegetation and hydrology and lead to increases in carbon loss and sediment transfer downstream. Gullies represent then a conduit for and a hotspot of carbon loss but the relatively high water tables of gullies have meant that they have been identified as areas with a high restoration potential because of easily restored peat‐forming conditions. This study uses a series of gully sites, subject to different restoration interventions, to investigate differences in carbon pathways (DOC, CO₂) and hydrology between restoration strategies and gully position. The results show that the position within the gully (interfluve, gully side, or gully floor) does not significantly affect water quality but that it plays a significant role in CO₂ exchange. Gully floors are areas of high photosynthesis and ecosystem respiration, though net ecosystem exchange is not significantly different across the gully. While gully position plays a role in the cycling of some carbon species, this study highlights the importance of vegetation as a key control on carbon cycling. Copyright © 2012 John Wiley & Sons, Ltd.     

Garnet peridotite from Colorado Plateau ultramafic diatremes: Hydrates,carbonates, and comparative geothermometry

Crystal fragments of pyrope from diatremes of ultramafic microbreccia in the Navajo Province of the Colorado Plateau contain inclusions of olivine, pyroxene, spinel, chlorite, amphibole, chlorapatite, and dolomite. The included suite supports earlier hypotheses that hydrous phases and carbonates were primary parts of some garnet peridotite assemblages in the Plateau lithosphere. Garnets with spinel and orthopyroxene inclusions likely all were sampled at pressures less than 36 kb and perhaps as low as 15–20 kb; no evidence was found for inclusions from greater depths. Temperature estimates are 800°–900° C for garnet-clinopyroxene equilibration, but only 500°–700° C for garnetolivine equilibration. Inherent differences between geothermometry methods account for only part of the discrepancy. Pronounced Fe-Mg zoning in garnet at olivine contacts and the lack of such zoning at clinopyroxene contacts are evidence that the difference in part relates to relative reequilibration rates with cooling. The garnet-olivine temperature estimates may be the best approximations to mantle temperatures before eruption. Our data are compatible both with the hypothesis that the garnet peridotite was emplaced in the mantle by large-scale, horizontal transport in the lithosphere and with the hypothesis that rocks were sampled from Precambrian lithosphere cooled to temperatures like those along a low heat flow geotherm. Discordances between the geothermometers here and in other lherzolite localities may be keys to evaluating tectonic histories of lherzolite masses.     

Estuaries of the South Atlantic coast of North America: Their geographical signatures

Estuaries of the southeastern Atlantic coastal plain are dominated by shallow meso-tidal bar-built systems interspersed with shallow sounds and both low flow coastal plain and high flow piedmont riverine systems. Three general geographical areas can be discriminated: the sounds of North Carolina; the alternating series of riverine and ocean dominated bar-built systems of South Carolina, Georgia, and northeast Florida, and the subtropical bar-built estuaries of the Florida southeast coast. The regional climate ranges from temperate to subtropical with sea level rise and hurricanes having a major impact on the region's estuaries because of its low and relatively flat geomorphology. Primary production is highest in the central region. Seagrasses are common in the northern and southern most systems, while intertidal salt marshes composed ofSpartina alterniflora reach their greatest extent and productivity in South Carolina and Georgia. Nuisance blooms (cyanobacteria, dinoflagellates, and cryptomonads) occur more frequently in the northern and extreme southern parts of the region. Fishery catches are highest in the North Carolina and Florida areas. Human population growth with its associated urbanization reaches a maximum in Florida and it is thought that the long-term sustainability of the Florida coast for human habitation will be lost within the next 25 years. Tidal flushing appears to play an important role in mitigating anthropogenic inputs in systems of moderate to high tidal range, i.e., the South Carolina and Georgia coasts. The most pressing environmental problems for the estuaries of the southeastern Atlantic coast seem to be nutrient loading and poor land use in North Carolina and high human population density and growth in Florida. The future utilization of these estuarine systems and their services will depend on the development of improved management strategies based on improved data quality.