Coordinated Ocean-ice Reference Experiments (COREs)

Coordinated Ocean-ice Reference Experiments (COREs) are presented as a tool to explore the behaviour of global ocean-ice models under forcing from a common atmospheric dataset. We highlight issues arising when designing coupled global ocean and sea ice experiments, such as difficulties formulating a consistent forcing methodology and experimental protocol. Particular focus is given to the hydrological forcing, the details of which are key to realizing simulations with stable meridional overturning circulations.The atmospheric forcing from [Large, W., Yeager, S., 2004. Diurnal to decadal global forcing for ocean and sea-ice models: the data sets and flux climatologies. NCAR Technical Note: NCAR/TN-460+STR. CGD Division of the National Center for Atmospheric Research] was developed for coupled-ocean and sea ice models. We found it to be suitable for our purposes, even though its evaluation originally focussed more on the ocean than on the sea-ice. Simulations with this atmospheric forcing are presented from seven global ocean-ice models using the CORE-I design (repeating annual cycle of atmospheric forcing for 500 years). These simulations test the hypothesis that global ocean-ice models run under the same atmospheric state produce qualitatively similar simulations. The validity of this hypothesis is shown to depend on the chosen diagnostic. The CORE simulations provide feedback to the fidelity of the atmospheric forcing and model configuration, with identification of biases promoting avenues for forcing dataset and/or model development.     

Reconstruction of the volcanic history of the Tacámbaro-Puruarán area (Michoacán, México) reveals high frequency of Holocene monogenetic eruptions

The 690?km² Tacámbaro-Puruarán area located at the arc-front part of the Michoácan-Guanajuato volcanic field in the Trans-Mexican Volcanic Belt (TMVB) records a protracted history of volcanism that culminated with intense monogenetic activity in the Holocene. Geologic mapping, ⁴⁰Ar/³⁹Ar and ¹⁴C radiometric dating, and whole-rock chemical analyses of volcanic products provide insights to that history. Eocene volcanics (55–40?Ma) exposed at uplifted blocks are related to a magmatic arc that preceded the TMVB. Early TMVB products are represented by poorly exposed Pliocene silicic domes (5–2?Ma). Quaternary (<2?Ma) volcanoes (114 mapped) are mainly scoria cones with lavas (49 vol.%), viscous lava flows (22 vol.%), and lava shields (22 vol.%). Erupted products are dominantly either basaltic andesites (37 vol. %), or andesites (17 vol.%), or span across both compositions (28 vol.%). Basalts (9 vol.%), dacites (4 vol.%), shoshonites (2 vol.%), and other alkali-rich rocks (<3 vol.%) occur subordinately. Early-Pleistocene volcanism was bimodal (dacites and basalts) and voluminous while since 1?Ma small-volume eruptions of intermediate magmas have dominated. Higher rates of lithospheric extension in the Quaternary may have allowed a larger number of small, poorly evolved dikes to reach the surface during this period. Eruptive centers as old as 1.7?Ma are aligned in a NE direction parallel to both, basement faults and the direction of regional compressive stress, implying structural control on volcanic activity. Data suggest that volcanism was strongly pulsatory and fed by localized low-degree partial melting of mantle sources. In the Holocene, at least 13 eruptions occurred (average recurrence interval of 800?years). These produced ~3.8?km³ of basaltic andesitic to andesitic magma and included four eruptions dated at ~1,000; 4,000; 8,000; and 11,000?years bc (calibrated ¹⁴C ages). To date, this is one of the highest monogenetic eruption frequencies detected within such a small area in a subduction-related arc-setting. These anomalous rates of monogenetic activity in an area with thick crust (>30?km) may be related to high rates of magma production at depth and a favorable tectonic setting.     

Total Solar Irradiance Observations

The record of total solar irradiance (TSI) during the past 35?years has overlapping observations from space which can be merged to a composite, and three are available, namely the PMOD, the ACRIM and the IRMB composites. There are important differences between them, which are discussed in detail in order to find the best representation of solar variability during the last three cycles, for the following discussions of solar irradiance variability. Moreover, the absolute value of TSI from TIM on SORCE is 1,361?Wm^?2, substantially lower than the value 1,365?Wm^?2, which was observed by the classical radiometers. New results from specific experiments are now available, which are discussed in order to define the value to be used in, e.g., climate models. The most important issue regarding the recent TSI records is the low value observed during the minimum in 2009, which is 25% of a typical cycle amplitude lower than the value in 1996. The validity of this low value has been confirmed by comparing all existing TSI observations during cycle 23. On the other hand, activity indices, such as the sunspot number, the 10.7-cm radio flux (F10.7), the CaII and MgII indices and also the Ly-α irradiance or the frequency changes in low-order p modes, show a much smaller decreases relative to their respective typical cycle amplitude. It is most likely that an increasing contrast of the facular and network elements with decreasing magnetic field is responsible for this discrepancy. The value of TSI at minima is correlated with the open magnetic field of the Sun, B _R,?at minima. Using B _R at minima, interpolated linearly in between as a fourth component of a proxy model based on the photometric sunspot index and on the MgII index improves the explanation of the variance of TSI over the full period of the last three solar cycles to 84.7%. Results from other models are also discussed.     

Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.     

Degradation and Transformation of Aquatic Humic Substances by Laccase-producing Fungi Cladosporium cladosporioides and Polyporus versicolor

A phenoloxidase-producing fungus – Cladosporium cladosporioides – was isolated from water of a bog lake. At high concentrations of carbon (333 mM) and nitrogen (12 mM), the fungus demonstrated the formation of a laccase and a high ligninolytic activity. After addition of riverine or groundwater humic substances into culture media (ca. 1 mg mL^–1), the fungus showed the ability of degrading (utilizing) of about 60% of these substances. However, the exact quantification of the degree of degradation was difficult because of adsorption of humic matter on fungal mycelium. Reisolated humic substances were lower in aromatic and higher in aliphatic structures. A crude enzyme from the C. cladosporioides culture showed only low activity in decolorizing humic substances, whereas decolorization up to 50% was observed when using a laccase preparation from Polyporus versicolor, and especially in the presence of a redox mediator.     

Assessment of susceptibility to landslides through geographic information systems and the logistic regression model

Natural Hazards - The increase in the frequency of natural disasters in recent years and its consequent social, economic and environmental impacts make it possible to prioritize areas of risk as an...     

Large microplastic particles in sediments of tributaries of the River Thames,UK – Abundance,sources and methods for effective quantification

Sewage effluent input and population were chosen as predictors of microplastic presence in sediments at four sites in the River Thames basin (UK). Large microplastic particles (1 mm–4 mm) were extracted using a stepwise approach to include visual extraction, flotation and identification using Raman spectroscopy. Microplastics were found at all four sites. One site had significantly higher numbers of microplastics than other sites, average 66 particles 100 g^? 1, 91% of which were fragments. This site was downstream of a storm drain outfall receiving urban runoff; many of the fragments at this site were determined to be derived of thermoplastic road-surface marking paints. At the remaining three sites, fibres were the dominant particle type. The most common polymers identified included polypropylene, polyester and polyarylsulphone. This study describes two major new findings: presence of microplastic particles in a UK freshwater system and identification of road marking paints as a source of microplastics.

A New Approach to 3D Dense LiDAR Data Classification in Urban Environment

Classification of Mobile Mapping LiDAR (Light Detection and Ranging) data is a challenge in the research community since the day when laser scanner system were integrated and mounted on vehicles for collection of 3D data in urban environment. The approach proposed here for classifying LiDAR data is analogous to the process followed for classifying data from satellite images. Pixel based and segmentation based methods have been employed in past for classifying images obtained from satellites. These methods were based on spectral properties of objects present in the images. But for Mobile mapping LiDAR data this approach has been applied and tested for the first time. The properties of this data are completely different from that of satellite images. So even if the basic approach remains the same, many changes have to be made in the entire classification process. The paper here aims to propose the basic procedure of using pixel-wise classification on dense 3D LiDAR data.     

A high-resolution stellar library for evolutionary population synthesis

We present a library of 1654 high-resolution stellar spectra, with a sampling of 0.3 Å and covering the wavelength range from 3000 to 7000 Å. The library was computed with the latest improvements in stellar atmospheres, incorporating non-local thermodynamic equilibrium (non-LTE) line-blanketed models for hot, massive  ( T _eff≥ 27 500 K)  and line-blanketed models for cool  (3000 ≤ T _eff≤ 4500 K)  stars. The total coverage of the grid is  3000 K ≤ T _eff≤ 55 000 K  and  −0.5 ≤ log g ≤ 5.5  , for four chemical abundance values: twice solar, solar, half solar and 1/10 solar. Evolutionary synthesis models using this library are presented in a companion paper. We tested the general behaviour of the library by calculating and comparing equivalent widths of numerous H and He  i lines, and some of the commonly used metallic indices. We also compared the library with the empirical libraries STELIB and Indo-US. The full set of the synthetic stellar spectra is available from our websites ( http://www.iaa.csic.es/~rosa and http://www.astro.iag.usp.br/~lucimara/library.htm ).