Analyses of precipitation,temperature and evapotranspiration in a French Mediterranean region in the context of climate change

This study is focused on the western part of the French Mediterranean area, namely the Pyrénées-Orientales and Aude administrative departments. The water resources (surface and groundwater) in the region are sensitive to climate change. The study addresses the question of whether any trend in the annual and monthly series of temperature, rainfall and potential evapotranspiration (PET) already appears at the scale of this region. Two data sources have been used: (a) direct local measurements using the meteorological network; and (b) spatially interpolated data from the French weather service model SAFRAN for the period 1970–2006. The non-parametric Mann–Kendall test was applied to identify significant trends at the local scale and, because of the natural spatial variability of the Mediterranean climate, regional interpretation was also performed. The trends observed in the 13 catchments of interest are consistent with those observed at a larger scale. An increase in annual mean temperature and annual PET was observed throughout the study area, whereas annual precipitation has not exhibited any trend. The monthly scale has revealed strong seasonal variability in trend. The trend for an increase in monthly PET has been observed mainly in the spring, and has not been seen in the coastal areas. A trend for an increase in monthly temperature has been observed in June and in the spring throughout the entire area. Monthly rainfall has been found to decrease in June and increase in November throughout the area. The significant trends observed in rainfall and temperature seem to be consistent between the different data sources.     

High-precision U-series measurements of more than 500,000 year old fossil corals

Robust, independent age constraints on the absolute timing of climate events based on the U-series dating of fossil coral are sparse before the last glacial cycle. Using multiple-collector inductively coupled plasma mass spectrometry with multiple-Faraday protocols, we are able to date ～ 600 ka samples with an uncertainty of better than ± 15 ka (2σ), representing a three-fold improvement in precision compared with previous techniques. Using these methods, we report U-series measurements for a suite of > 500 thousand year old (ka) corals from Henderson Island, an emergent atoll in the south-central Pacific Ocean. The fossil corals show extraordinarily little diagenetic alteration for their age and the best-preserved sample yields a U-series age of 600 ± 15 ka (2σ), which overlaps with the timing of the warm Marine Isotope Stage (MIS) 15 interglacial. The open-system model of Villemant and Feuillet [Villemant B. and Feuillet N. (2003) Dating open systems by the ²³⁸U–²³⁴U–²³⁰Th method: application to Quaternary reef terraces. Earth and Planetary Science Letters 210(1–2), 105–118.] and the linear regression (or open-system isochron) is clearly limited for such old samples. However, the open-system model developed by Thompson et al. [Thompson W.G., Spiegelman M.W., Goldstein S.L., and Speed R.C. (2003) An open-system model for U-series age determinations of fossil corals. Earth and Planetary Science Letters 210(1–2), 365–381.] appears to reliably correct for open-system effects in roughly half of the corals, giving a MIS 15 origin for these. Thus the data provide evidence that the systematic addition of ²³⁰Th and ²³⁴U through α-recoil is a dominant open-system process occurring in the Henderson Island fossil reef system. Several coral samples yield significantly older Thompson et al. open-system ages between 650 and 750 ka. The uncertainty on these ages (typically ± 30 kyrs) is too great for precise assignment but most data overlap with the MIS 17 interglacial. The reliability of these ages is currently unclear. It is shown that separate aliquots of the same coral can yield different Thompson model ages. Therefore, there appear to be additional diagenetic mechanisms that create further anomalous excursions in the U-series systematics, limiting the reliability of the Thompson et al. open-system model.     

Dust tail of the active distant Comet C/2003 WT42 (LINEAR) studied with photometric and spectroscopic observations

We present the study of dust environment of dynamically new Comet C/2003 WT42 (LINEAR) based on spectroscopic and photometric observations. The comet was observed before and after the perihelion passage at heliocentric distances from 5.2 to 9.5 AU. Although the comet moved beyond the zone where water ice sublimation could be significant, its bright coma and extended dust tail evidenced the high level of physical activity. Afρ values exceeded 3000 cm likely reaching its maximum before the perihelion passage. At the same time, the spectrum of the comet did not reveal molecular emission features above the reflected continuum. Reddening of the continuum derived from the cometary spectrum is nonlinear along the dispersion with the steeper slop in the blue region. The pair of the blue and red continuum images was analyzed to estimate a color of the comet. The mean normalized reflectivity gradient derived from the innermost part of the cometary coma equals to 8% per 1000 Å that is typical for Oort cloud objects. However, the color map shows that the reddening of the cometary dust varies over the coma increasing to 15% per 1000 Å along the tail axis. The photometric images were fitted with a Monte Carlo model to construct the theoretical brightness distribution of the cometary coma and tail and to investigate the development of the cometary activity along the orbit. As the dust particles of distant comets are expected to be icy, we propose here the model, which describes the tail formation taking into account sublimation of grains along their orbits. The chemical composition and structure of these particles are assumed to correspond with Greenberg’s interstellar dust model of comet dust. All images were fitted with the close values of the model parameters. According to the results of the modeling, the physical activity of the comet is mainly determined by two active areas with outflows into the wide cones. The obliquity of the rotation axis of the nucleus equals to 20° relative to the comet’s orbital plane. The grains occupying the coma and tail are rather large amounting to 1 mm in size, with the exponential size distribution of a^−4.5. The outflow velocities of the dust particles vary from a few centimeters to tens of meters per second depending on their sizes. Our observations and the model findings evidence that the activity of the nucleus decreased sharply to a low-level phase at the end of April–beginning of May 2007. About 190 days later, in the first half of November 2007 the nucleus stopped any activity, however, the remnant tail did not disappear for more than 1.5 years at least.     

Multiple Collector ICP-MS: Introduction to Instrumentation, Measurement Techniques and Analytical Capabilities

The technique of multiple collector ICP-MS (MC-ICP-MS) has recently attracted much attention, because it permits the precise measurement of isotope compositions for a wide range of elements. This review article discusses the particular advantages of this mass spectrometric technique and provides an overview of the instrumentation. The performance characteristics of MC-ICP-MS instruments and procedures for the correction of instrumental mass discrimination are covered. The strategies that are employed to avoid analytical artefacts from spectral interferences and matrix effects are also considered. A range of applications are then discussed, to provide an overview of the versatility of this mass spectrometric technique. The diversity of applications, which include the measurement of radiogenic and stable isotope ratios, the determination of trace element concentrations by isotope dilution and in situ isotopic measurements using a laser ablation system, highlight the great relevance of MC-ICP-MS to present and future research in various Earth science disciplines.     

Erratum to: Climate change projections over three metropolitan regions in Southeast Brazil using the non-hydrostatic Eta regional climate model at 5-km resolution

Theoretical and Applied Climatology -     

Discovery of cryptotephra at Middle–Upper Paleolithic sites Arma Veirana and Riparo Bombrini,Italy: a new link for broader geographic correlations

Chemical characterization of cryptotephra is critical for temporally linking archaeological sites. Here, we describe cryptotephra investigations of two Middle–Upper Paleolithic sites from north-west Italy, Arma Veirana and Riparo Bombrini. Cryptotephra are present as small (<100 µm) rhyolitic glass shards at both sites, with geochemical signatures rare for volcanoes in the Mediterranean region. Two chemically distinct shard populations are present at Arma Veirana (P1 and P2). P1 is a high silica rhyolite (>75 wt.%) with low FeO (<1 wt.%) and a K₂O/Na₂O > 1 and P2 is also a high silica rhyolite (>75 wt.%) but with higher FeO (2.33–2.65 wt.%). Shards at Riparo Bombrini (P3) are of the same composition as P1 shards at Arma Veirana, providing a distinct link between deposits at both sites. Geochemical characteristics suggest three possible sources for P1 and P3: eruptions from Lipari Island (56–37.7 ka) in Italy, the Acigöl volcanic field (200–20 ka) in Turkey and the Miocene Kirka-Phrigian caldera (18 Ma) in Turkey. Eruptions from Lipari Island are the most likely source for P1,3 cryptotephra. This study highlights how cryptotephra can benefit archaeology, by providing a direct link between Arma Veirana and Riparo Bombrini as well as other deposits throughout the Mediterranean.     

National GHG emissions reduction pledges and 2°C: comparison of studies

This article provides further detail on expected global GHG emission levels in 2020, based on the Emissions Gap Report (United Nations Environment Programme, December 2010), assuming the emission reduction proposals in the Copenhagen Accord and Cancun Agreements are met. Large differences are found in the results of individual groups owing to uncertainties in current and projected emission estimates and in the interpretation of the reduction proposals. Regardless of these uncertainties, the pledges for 2020 are expected to deliver emission levels above those that are consistent with a 2°C limit. This emissions gap could be narrowed through implementing the more stringent conditional pledges, minimizing the use of ‘lenient’ credits from forests and surplus emission units, avoiding double-counting of offsets and implementing measures beyond current pledges. Conversely, emission reduction gains from countries moving from their low to high ambition pledges could be more than offset by the use of ‘lenient’ land use, land-use change and forestry (LULUCF) credits and surplus emissions units, if these were used to the maximum. Laying the groundwork for faster emission reduction rates after 2020 appears to be crucial in any case.     

Climate change projections over three metropolitan regions in Southeast Brazil using the non-hydrostatic Eta regional climate model at 5-km resolution

Theoretical and Applied Climatology - The objective of this work is to assess changes in three metropolitan regions of Southeast Brazil (Rio de Janeiro, São Paulo, and Santos) based on the...