The first detection of propane on Saturn

We report the first detection of propane, C₃H₈, in Saturn's stratosphere. Observations taken on September 8, 2002 UT at NASA's IRTF using TEXES, show multiple emission lines due to the 748 cm⁻¹ν₂₁ band of C₃H₈. Using a line-by-line radiative transfer code, we are able to fit the data by scaling the propane vertical mixing ratio profile from the photochemical model of Moses et al. [2000. Icarus 143, 244-298]. Multiplicative factors of 0.7 and 0.65 are required to fit the −20° and −80° planetocentric latitude spectra. The resultant profiles are characterized by a 5 mbar mixing ratio of 2.7±0.8×¹⁰⁻⁸ at −20° and at −80° latitude. These results suggest that the time scale for meridional circulation lies between the net photochemical lifetimes of C₂H₂ and C₃H₈, ≈30-600 years.     

Spectral properties of volcanic materials from hyperspectral field and satellite data compared with LiDAR data at Mt. Etna

Spectral properties of volcanic materials in the optical region (350–2500 nm) of the electromagnetic spectrum are analyzed. The goal is to characterize air-fall deposits, recent lava flows, and old lava flows based on their spectral reflectance properties and on the textural characteristics (grain size) of pyroclastic deposits at an active basaltic volcano. Data were acquired during a spectroradiometric field survey at Mt. Etna (Italy) in summer 2003 and combined with hyperspectral satellite (Hyperion) and airborne LiDAR (Light Detection and Ranging) data. In addition, air-fall deposits produced by the highly explosive 2002–2003 eruption have been sampled and spectrally characterized at different distances from the new vents. The spectral analysis shows that air-fall deposits are characterized by low reflectance values besides variations in grain size. This distinguishes them from other surface materials. Old lava flows show highest reflectance values due to weathering and vegetation cover. The spectral data set derived from the field survey has been compared to corrected satellite hyperspectral data in order to investigate the Hyperion capabilities to differentiate the surface cover using the reflectance properties. This has allowed us to identify the 2002–2003 air-fall deposits in a thematic image just few months after their emplacement. Moreover, the observed differences in the field spectra of volcanic surfaces have been compared with differences in the signal intensity detected by airborne LiDAR survey showing the possibility to include information on the texture of volcanic surfaces at Mt. Etna. The approach presented here may be particularly useful for remote and inaccessible volcanic areas and also represents a potentially powerful tool for the exploration of extraterrestrial volcanic surfaces.     

Development of Kinetic Inductance Detectors for Cosmic Microwave Background experiments

We describe the design, optimization, electrical and optical tests of Microwave Kinetic Inductance Detectors (MKIDs) for the mm-wave range. Our detectors are based on a novel resonator design, and are suitable for ground-based astronomical observations in the 143 GHz atmospheric window. The measured optical Noise Equivalent Power (NEP) at 0.3 K is $\sim 10^{-16}~\text{W}/\sqrt{\rm Hz}$ under a 300 K background load. This is equivalent or better than the performance of the best current bolometric detectors for the 140 GHz atmospheric window, limited by atmospheric noise in the best available sites. We also describe which improvements can be introduced to reduce the NEP of our detector, for lower background applications (narrow band or space-based).     

Contributions of individual countries?? emissions to climate change and their uncertainty

We have compiled historical greenhouse gas emissions and their uncertainties on country and sector level and assessed their contribution to cumulative emissions and to global average temperature increase in the past and for a the future emission scenario. We find that uncertainty in historical contribution estimates differs between countries due to different shares of greenhouse gases and time development of emissions. Although historical emissions in the distant past are very uncertain, their influence on countries?? or sectors?? contributions to temperature increase is relatively small in most cases, because these results are dominated by recent (high) emissions. For relative contributions to cumulative emissions and temperature rise, the uncertainty introduced by unknown historical emissions is larger than the uncertainty introduced by the use of different climate models. The choice of different parameters in the calculation of relative contributions is most relevant for countries that are different from the world average in greenhouse gas mix and timing of emissions. The choice of the indicator (cumulative GWP weighted emissions or temperature increase) is very important for a few countries (altering contributions up to a factor of 2) and could be considered small for most countries (in the order of 10%). The choice of the year, from which to start accounting for emissions (e.g. 1750 or 1990), is important for many countries, up to a factor of 2.2 and on average of around 1.3. Including or excluding land-use change and forestry or non-CO₂ gases changes relative contributions dramatically for a third of the countries (by a factor of 5 to a factor of 90). Industrialised countries started to increase CO₂ emissions from energy use much earlier. Developing countries?? emissions from land-use change and forestry as well as of CH₄ and N₂O were substantial before their emissions from energy use.     

Reproductive success of Calanus pacificus during diatom blooms in Dabob Bay, Washington

While numerous laboratory studies in the last decade have shown that diatoms can induce reproductive failure in copepods, field evidence for a negative diatom effect is equivocal. To unambiguously elucidate the effects diatoms have on copepod reproduction in situ, we undertook a study of the abundance, distribution, grazing rates, and reproductive success of Calanus pacificus in Dabob Bay, Washington, USA, during two spring bloom periods. We simultaneously measured the phytoplankton composition, abundance, and distribution. Here we present results for the reproductive success of C. pacificus using four measurements: egg production rate, clutch size, egg hatching success, and naupliar survival (to the first feeding stage). Egg production rate was positively correlated with chlorophyll a concentration, and egg hatching success and naupliar survival were usually greater than 80%. However, in February 2002 and 2003 – during blooms of diatoms of the genus Thalassiosira – either egg hatching success, naupliar survival, or both were significantly depressed compared to other times in spring and summer. These effects, combined with evidence that C. pacificus was grazing aldehyde-producing Thalassiosira at the time of their blooms, indicate that diatoms can negatively affect copepod reproduction in the field, albeit only under specific circumstances and for brief periods.     

Sedimentary provenance in the central Ribeira belt based on laser-ablation ICPMSPb/Pb zircon ages

²⁰⁷Pb/²⁰⁶Pb ages from 420 zircons from 9 upper amphibolite and granulite facies quartzites of the post-1.8 Ga metasedimentary cover from the Occidental and Oriental terranes from the Neoproterozoic central Ribeira belt, in eastern Brazil, are discussed. Ages from the Occidental terrane show that Proterozoic ages predominate with a modal class at 2.1–2.2 Ga and that Archean ages are less common and lie within the 2.5–3.6 Ga range. A wider dispersion on Proterozoic ages down to 1.1 Ga and youngest Neoproterozoic ages (550–700 Ma) were also observed and could be related to the Brasiliano/PanAfrican metamorphic events. The data show that detrital sediments of the Occidental terrane were derived predominantly from erosion of a 1.8–2.2 Ga Paleoproterozoic terrane with a small proportion of a 2.6–3.6 Ga Archean crust. Ages from the Oriental terrane are greatly dispersed, but show a significant proportion of ages between 1.7 and 2.1 Ga, although the great majority are between 0.5 and 1.6 Ga. Only 3 out of 144 grains yield Archean ages, between 2.5 and 2.9 Ga. Based on the greatest errors observed on the data from the Oriental Terrane (100–300 Ma), and a continuum of obtained ages between 2072 Ma (Paleoproterozoic) and 517 Ma (Cambrian), the more plausible interpretation is that the dispersion of ages results from partial resetting of the U–Pb system by Brasiliano metamorphism in Proterozoic–Archean zircons, although a Mesoproterozoic source could not be discarded.