87Rb-86Sr age of rocks from the Apollo 15 landing site and significance of internal isochrons

Internal isochrons for two Apollo 15 rocks give an age of(3.34 ± 0.09)and(3.46 ± 0.04) × 10⁹ years with an identical⁸⁷Sr/⁸⁶Sr initial ratio of 0.69928. Considering the possibility for the line obtained in a⁸⁷Sr/⁸⁶Sr,⁸⁷Rb/⁸⁶Sr diagram to be a mixing line, the significance of these results are discussed.     

Comments on the low-wavenumber power of granulation brightness fluctuations

A comment is made on the Edmonds' study of the low-wavenumber power of solar granulation. It is concluded that its one-dimensional power spectrum is biased, and that the corresponding two-dimensional power spectrum shows negative parts.     

Evolution of the late Pleistocene Mojanda–Fuya Fuya volcanic complex (Ecuador), by progressive adakitic involvement in mantle magma sources

The Mojanda–Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of viscous Si-rich andesitic lavas and dacitic domes, and the emission of a thick sequence of pyroclastic-flow and fallout deposits which include two voluminous rhyolitic layers. An intermediate construction phase at Fuya Fuya is represented by a mainly effusive cone, andesitic in composition (San Bartolo edifice), the construction of which was interrupted by a major sector collapse in the Late Pleistocene. Finally, a complex of thick siliceous lavas and domes was emplaced within the avalanche amphitheatre, forming the Upper Fuya Fuya volcanic centre. This paper shows that the general evolution from an effusive to an explosive eruptive style is related to a progressive adakitic contribution to the magma source. Although all the rocks of the complex are included in the medium-K field of continental arcs, the Fuya Fuya suite (61–75 wt.% SiO₂) shows depletion in Y and HREE and high Sr/Y and La/Yb values, compared to the less silicic Mojanda suite (55–66.5 wt.% SiO₂). The Mojanda calc-alkaline suite was generated by partial melting of an adakite-metasomatised mantle source that left a residue with 2% garnet, followed by fractional crystallization of dominant plagioclase + pyroxene + olivine at shallow, intra-crustal depths. For Fuya Fuya, geochemical and mineralogical data suggest either (1) partial melting of a similar metasomatised mantle with more garnet in the residue (4%), followed by fractional crystallization involving plagioclase, amphibole and pyroxene, or (2) mixing of mafic mantle-derived magma from the Mojanda suite and slab melts, followed by the same fractional crystallization process.     

Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.     

Building Temporal Topology in a GIS Database to Study the Land‐Use Changes in a Rural‐Urban Environment

This article addresses the issue of linking temporal and spatial information into a GIS database structure to investigate the land‐use changes in a rural‐urban region over a thirty‐five‐year period. More specifically, it describes the application of a programming package developed to build temporal topology in an historical land‐use GIS database to efficiently perform spatiotemporal queries. The program was created within the MapInfo environment using MapBasic language. Different types of information, such as the rate of change, the relationship between the change of land use and zoning regulations, and land‐use succession were extracted from the database. A user‐friendly interface was also developed to easily address spatiotemporal queries to the database. This approach represents a flexible and performing tool for scientists and planners who need to efficiently capture essential spatiotemporal information required for geographical inquiry and decision‐making.     

Isochron‐burial dating of glaciofluvial deposits: First results from the Swiss Alps

In this study, we use isochron‐burial dating to date the Swiss Deckenschotter, the oldest Quaternary deposits of the northern Alpine Foreland. Concentrations of cosmogenic ¹⁰Be and ²⁶Al in individual clasts from a single stratigraphic horizon can be used to calculate an isochron‐burial age based on an assumed initial ratio and the measured ²⁶Al/¹⁰Be ratio. We suggest that, owing to deep and repeated glacial erosion, the initial isochron ratio of glacial landscapes at the time of burial varies between 6.75 and 8.4. Analysis of 22 clasts of different lithology, shape, and size from one 0.5 m thick gravel bed at Siglistorf (Canton Aargau) indicates low nuclide concentrations: <20 000 ¹⁰Be atoms/g and <150 000 ²⁶Al atoms/g. Using an ²⁶Al/¹⁰Be ratio of 7.6 (arithmetical mean of 6.75 and 8.4), we calculate a mean isochron‐burial age of 1.5 ± 0.2 Ma. This age points to an average bedrock incision rate between 0.13 and 0.17 mm/a. Age data from the Irchel, Stadlerberg, and Siglistorf sites show that the Higher Swiss Deckenschotter was deposited between 2.5 and 1.3 Ma. Our results indicate that isochron‐burial dating can be successfully applied to glaciofluvial sediments despite very low cosmogenic nuclide concentrations. Copyright © 2017 John Wiley & Sons, Ltd.     

A three dimensional perspective on the evolution of Archaean crust: LITHOPROBE seismic reflection images in the southwestern Superior province

15011993

Abstract

In 1990–1991 the LITHOPROBE project completed 450 km of seismic reflection profiles across the late Archaean crust of the southwestern Superior province. The results define a broad three-fold division of crust: upper crust in the Abitibi greenstone belt is non-reflective and is a 6–8 km veneer of volcanic and plutonic supracrustal rocks, whereas, in the sediment-gneiss dominated Pontiac subprovince, upper crust comprises shallow northwest-dipping turbidite sequences; mid-crust, in both the Abitibi and the Pontiac subprovinces, is interpreted as imbricate sequences of metasedimentary and metaplutonic rocks; lower crust in both subprovinces has a horizontal layer parallel strycture which may represent interleaved mafic-intermediate gneisses. The seismic signature of the northern Abitibi greenstone belt may be represented in an exposed 25 km crustal section in the Kapuskasing stuctural zone.

Preliminary tectonic models based on the seismic data are consistent with a plate-tectonic scenario involving oblique subduction and imbrication of sedimentary, plutonic and volcanic sequences. The northern Abitibi supracrustal sequences either represent an allochthon, or overlie an allochthonous underthrust metasedimentary and plutonic sequence which may be equivalent to a metasedimentary subprovince such as the Pontiac or Quetico.

Seismic velocities have yet to be defined. However, crustal thicknesses are relatively constant at 35–40 km. The thinnest crust is adjacent to the Grenville Front where Moho is very well defined.     

Textural, isotopic and REE variations in spinel peridotite xenoliths, Massif Central, France

Sr and Nd isotope analyses and REE patterns are presented for a suite of well-documented mantle-derived xenoliths from the French Massif Central. The xenoliths include spinel harzburgites, spinel lherzolites and some pyroxenites. They show a wide range of textures from undeformed protogranular material through porphyroclastic to equigranular and recrystallised secondary types. Textural differences are strongly linked to trace element geochemistry and variations in radiogenic isotope ratios. Many undeformed protogranular xenoliths are Type IA LREE-depleted with MORB-type ε_Sr values between − 30.7 and − 23.6, and ε_Nd values + 13.9 to + 9.4. A second group of undeformed xenoliths are Type IB LREE-enriched with higher ε_Sr values (− 22.7 to − 10.6) and lower ε_Nd values (+ 11.9 to + 5.6). Deformed xenoliths with porphyroclastic, equigranular and secondary recrystallised textures are all Type IB (LREE-enriched, ε_Nd < 6.4, ε_Sr > 11.8). It is proposed that two separate events have given rise to the observed mixing arrays: (1) MORB-source depleted mantle was enriched by a component derived from an enriched mantle. Deformation and recrystallisation accompanied this event. (2) Subsequently, unenriched MORB-source mantle interacted with magmas chemically akin to the host basalts, and enrichment occurred with little deformation. Hypotheses of Tertiary mantle diapirism resulting in isochemical deformation and refinement of protogranular mantle to equigranular mantle are untenable because of differences in REE patterns and isotopic ratios between different textural groups.     

Etude de la couche limite de surface sahelienne — Experience Yantala

This paper presents data concerning the energy budget in the surface layer in the Sahel region (a semi-desert area). The results are drawn from a measurement campaign made in the Niamey region in the Niger, in April–May 1984 (the Yantala Campaign). The sensible heat flux is computed with the profile method, the ground heat flux is deduced from measurement of the temperature field, and the radiative net flux is measured directly with a balancemeter. The latent heat flux, which is deduced from the energy budget balance is very weak and within the accuracy limit of the method. The diurnal variation of the net flux is symmetrical, with a maximum at noon. On the other hand, the sensible heat flux variation is asymmetrical, with an afternoon decrease much slower than the morning increase. After 3.30 pm, it becomes higher than the net flux. This is compensated for by the sign change of the ground heat flux, whose maximum is found in the morning at 11 am. The second part of this paper shows the importance of one term in the surface-layer energy budget: the long-wave radiative divergence between the ground and the top of the surface layer in high superadiabatic conditions. We show, with a radiative model on the one hand and direct measurement of the radiative divergence on the other hand, that this term reaches several tens of W m^-2 in the superadiabatic conditions found in the Sahel region.      

A Top-Cut Model for Deposits with Heavy-Tailed Grade Distribution

In some ore deposits, the grade distribution is heavy-tailed and high values make the inference of first- and second-order statistics nonrobust. In the case of gold data, high values are usually cut and the block estimation is performed using truncated grades. With this method, a part of the deposit is omitted, resulting in a potential bias on resources figures. Ad-hoc corrections can be applied on the final figures to take into account the tail of the grade distribution, but no theoretical guidelines are available. A geostatistical model has been developed to handle high values based on the assumption that for high grade zones, the only tangible information is the geometry. The grade variable z can be split into three parts: the truncated grade ( $\operatorname{Min} (z, z_{\mathrm{e}})$ where z _e is the top-cut grade), a weighted indicator above top-cut grade (1{z≥z _e}), and a residual. Within this framework, the residual is poorly structured, and in most cases is a pure nugget-effect. Moreover, it has no spatial correlation with the truncated grade and the indicator above top-cut grade. This decomposition makes the variographic study more robust because variables (indicator and truncated grade) do not keep high grade values. The underlying hypotheses can be tested on experimental indicator variograms and the top-cut grade can be justified. Finally, the estimation is based on a truncated grade and indicator cokriging. The model is applied to blast holes from a gold deposit and on a simulated example. Both cases illustrate the benefits of keeping the high values in the estimation process via an appropriate mathematical model.