Combining CLUE-S and SWAT models to forecast land use change and non-point source pollution impact at a watershed scale in Liaoning Province,China

Non-point source （NPS） pollution has become a major source of water pollution. A combination of models would provide the necessary direction and approaches designed to control NPS pollution through land use planning. In this study, NPS pollution load was simulated in urban planning, historic trends and ecological protection land use scenarios based on the Conversion of Land Use and its Effect at Small regional extent （CLUE-S） and Soil and Water Assessment Tool （SWAT） models applied to Hunhe-Taizi River Watershed, Liaoning Province, China. Total nitrogen （TN） and total phosphorus （TP） were chosen as NPS pollution indices. The results of models validation showed that CLUE-S and SWAT models were suitable in the study area. NPS pollution mainly came from dry farmland, paddy, rural and urban areas. The spatial distribution of TN and TP exhibited the same trend in 57 sub-catchments. The TN and TP had the highest NPS pollution load in the western and central plains, which concentrated the urban area and farm land. The NPS pollution load would increase in the urban planning and historic trends scenarios, and would be even higher in the urban planning scenario. How- ever, the NPS pollution load decreased in the ecological protection scenario. The differences observed in the three scenarios indicated that land use had a degree of impact on NPS pollution, which showed that scientific and ecologically sound construction could effec- tively reduce the NPS pollution load in a watershed. This study provides a scientific method for conducting NPS pollution research at the watershed scale, a scientific basis for non-point source pollution control, and a reference for related policy making.     

我国硫资源供需状况及需求预测

全球硫资源特征及国内硫资源供需现状表明,国内硫资源贫乏,硫资源生产与消费逐年增加,尤其磷肥生产对硫资源的需求越来越迫切,预计到2020~2025年磷肥用硫量将达到峰值1620万t左右,不包括出口磷肥耗硫量。因此,加强硫资源的综合利用、加大硫铁矿找矿及矿山设计是非常有必要的。     

四川盆地东部下古生界页岩储集空间特征及其对含气性的影响

四川盆地东部下古生界海相页岩是一套有利的页岩气储层,通过野外泥页岩剖面及井下岩芯观察、电镜扫描、常规物性及微孔隙结构测试、等温吸附实验等技术方法,对页岩气储层空间特征进行了研究分析,发现下古生界页岩的孔隙可分为三大类六小类,裂缝可分为两大类五小类,具有颗粒细小、致密、大孔发育少、微孔发育多、具有一定孔隙度、渗透率小、喉道细、连通性差的特征。页岩总孔体积主体是由孔径小于200nm的微孔隙提供的,纳米级孔隙和微裂缝是页岩主要的储集空间,页岩有机质孔对于孔隙度具有一定贡献,是富有机质页岩的主要微孔隙类型。页岩的微孔隙结构决定了页岩气的赋存状态和流动方式,孔缝发育程度在一定程度上决定了页岩的含气性及其渗透性能,但大型或巨型裂缝的发育,将给页岩气的有效保存带来破坏。有机质(干酪根和沥青质)和黏土颗粒内的微孔隙表面是吸附态页岩气赋存的主要空间,但有机质孔提供了大部分具吸附性的孔比表面,是控制页岩吸附性能的主要因素,而黏土矿物的作用是次要的。     

The Insect Oviposition Firstly Discovered on the Middle Jurassic Ginkgoales Leaf from Inner Mongolia,China

Although the evidence of insect oviposition on plant organs has been reported from the late Paleozoic to the Miocene, record from the middle Jurassic is still blank. This paper reports a significant evidence of insect oviposition on plant leaf from the middle Jurassic for the first time. The ovipositional scar is distributed on the abaxial surface of Sphenobaiera leaf（Ginkgoales） from the middle Jurassic Daohugou Formation of Inner Mongolia, China. A new ichnospecies Paleoovoidus venustus sp. nov. is described. The scar is elliptic to oval, arranged in longitudinal rows between leaf veins with almost regular distance, with its long axis paralleling to the leaf venation. This discovery adds new information to the morphology of insect endophytic oviposition probably produced by Odonata existed in a terrestrial ecosystem ~165 Ma ago. The new materials also provide important data for the study of insect reproductive biology, plant-insect interaction and coevolution, as well as understanding the paleoclimate and palaeoenvironment during that time in northeast China.     

滇东老厂地区地热水成因：来自水化学和碳氢氧硫同位素的约束

滇东弥勒-师宗断裂带地热资源丰富,但是由于研究程度较低,成因机制不明,制约了区内地热资源的可持续开发利用。本文以弥勒-师宗断裂带北段老厂地区天然温泉水和地热钻孔水为研究对象,综合应用野外调查、水文地球化学和环境同位素方法,对区内地热水的地球化学特征和成因机制进行了研究。结果显示,区内地热水pH值介于7.30～8.12之间,TDS在224～382 mg/L之间,属于弱碱性淡水。地热水水化学类型为HCO₃·SO₄^Ca型和HCO₃·SO₄-Ca·Na型,且含有较高含量的Fe、As、Sb等微量组分,不宜饮用。地热水中HCO₃^-的δ¹³C值为-3.31‰～-7.79‰,计算得出参与水岩作用的CO₂的δ¹³C值为-9.50‰～-15.68‰,具有明显的沉积有机质来源特征。离子比值分析及硫同位素特征表明碳酸盐岩矿物和石膏的溶解是区内地热水主要离子来源的控制因素,此外赋存于浅部断裂带内...     

接地电阻随季节及天气过程变化规律分析

为了解框架结构建筑物基础接地电阻的季节变化特征及天气过程对其变化的影响,分析了2010年广州从化气象局框架建筑物基础接地电阻和相关气象要素的自动气象站观测资料。从季节变化特征来看,框架结构接地电阻相对较为稳定,月平均值2月最大为0.78 Ω,9月份最小为0.57 Ω,全年变化最大值约为0.21 Ω。统计季节变化曲线和暴雨过程发现,接地体电阻与1.5 m土壤温度和1.0 m土壤含水量呈现明显的负相关,接地电阻减小值与暴雨的强度无明显的相关性。文中还对较长时间无降水的干旱过程进行了分析,结果表明：干旱时框架结构接地电阻值有明显的上升趋势,尤其在夏季,干旱对接地电阻影响较大。     

CO2 flux evaluation over the evergreen coniferous and broad-leaved mixed forest in Dinghushan,China

The Dinghushan flux observation site, as one of the four forest sites of ChinaFLUX, aims to acquire long-term measurements of CO₂ flux over a typical southern subtropical evergreen coniferous and broad-leaved mixed forest ecosystem using the open path eddy covariance method. Based on two years of data from 2003 to 2004, the characteristics of temporal variation in CO₂ flux and its response to environmental factors in the forest ecosystem are analyzed. Provided two-dimensional coordinate rotation, WPL correction and quality control, poor energy-balance and underestimation of ecosystem respiration during nighttime implied that there could be a CO₂ leak during the nighttime at the site. Using daytime (PAR > 1.0 μmol⁻¹·m⁻²·s⁻¹) flux data during windy conditions (u* > 0.2 m·s⁻¹), monthly ecosystem respiration (Reco) was derived through the Michaelis-Menten equation modeling the relationship between net ecosystem C0₂ exchange (NEE) and photosynthetically active radiation (PAR). Exponential function was employed to describe the relationship between Reco and soil temperature at 5 cm depth (Ts05), then Reco of both daytime and nighttime was calculated respectively by the function. The major results are: (i) Derived from the Michaelis-Menten equation, the apparent quantum yield (α) was 0.0027±0.0011 mgCO₂·μmol⁻¹ photons, and the maximum photosynthetic assimilation rate (Amax) was 1.102±0.288 mgCO₂·m⁻²·s⁻¹. Indistinctive seasonal variation of α or Amax was consistent with weak seasonal dynamics of leaf area index (LAf) in such a lower subtropical evergreen mixed forest, (ii) Monthly accumulated Reco was estimated as 95.3±21.1 gC·m⁻²mon⁻¹, accounting for about 68% of the gross primary product (GPP). Monthly accumulated WEE was estimated as −43.2±29.6 gC·m⁻²·mon⁻¹. The forest ecosystem acted as carbon sink all year round without any seasonal carbon efflux period. Annual NEE of 2003 and 2004 was estimated as −563.0 and −441.2 gC·m⁻²·a⁻¹ respectively, accounting for about 32% of GPP.

     

甘肃北山地区古亚洲南缘古生代岛弧带位置的讨论

综合研究得出结论:"甘肃北山红石山断裂带以北的雀儿山-英安山地区为一种与俯冲洋壳板块相关的岛弧带,它记录了古亚洲大洋向南缘东天山古陆系统下俯冲消减的整个地史过程".主要依据:①该地区缺少古老基底陆壳;②发育于区内的中奥陶世-泥盆纪不同时代地层中的火山岩和石炭-三叠纪的中酸性侵入岩,主要以钙碱性或TTG或埃达克成分系列为主要标志,揭示深部有消减洋壳板片或岩源的存在;③从中奥陶世和志留纪火山岩的玄武岩、安山岩和英安岩组合,到泥盆纪以安山岩、英安岩为主的流纹岩、玄武岩组合,至三叠纪马鞍山、小草湖中酸性侵入岩序列的部分高钾钙碱性岩石类型组合,反映古亚洲大洋在南侧消减带之上从一种不成熟岛弧到成熟岛弧和大陆边缘弧发育演化的过程;文章提出代表古亚洲大洋南缘消减带的实际位置应在雀儿山-英安山一线以北的蒙古境内,而北山岛弧带实属南侧东天山古陆陆缘增生地体的一部分.     

湘西北地区五峰-龙马溪组页岩物质组成特征与页岩气潜力分析

为了研究湘西北龙山-永顺地区上奥陶统五峰组-下志留统龙马溪组页岩气资源勘探潜力,利用野外典型露头地质剖面资料,通过对典型剖面页岩样品的系统观测、采样、利用有机地球化学和矿物组成特征研究,评价研究区目标地层页岩的成烃成藏物质基础。研究结果表明,研究区五峰-龙马溪组黑色泥页岩普遍具有有机碳含量高、残留可溶有机质氯仿沥青"A"低、生烃潜能S₁+S₂指数略低。分子生物标志化合物分析显示,正构烷烃无明显奇偶优势,受一定程度的微生物降解影响,多表现为双峰型（C₁₈/C₂₅）,∑C₂₁-/∑C₂₂₊值为0.45~1.11,显示轻烃组分缺失,重烃组分占绝对优势;Pr/Ph值范围在0.27~0.44,具有植烷优势,显示原始有机质发育于较强还原沉积环境。烃源岩样品饱和烃组成相对丰度五环三萜烷 > 三环萜烷 > 四环萜烷,三环萜烷中C₂₁、C₂₃、C₂₄呈倒V字形分布,Ts/Tm为0.39~0.66。C₂₇规则甾烷含量略大于C₂₉规则甾烷,显示沉积母质以浮游生物及海洋型自养菌为主,亦含有部分藻类为主的有机质输入。镜质组反射率Ro均在2.57%~3.01%,普遍小于3%,已经达到了过成熟阶段。全岩矿物组成成分分析显示,页岩中脆性矿物为主要组成成分,其次为黏土矿物。综合页岩有机和无机物质组成分析结果,提出研究区湘西北五峰-龙马溪组页岩具备页岩气成烃成藏的物质条件基础,有机质含量高、热演化程度适中、脆性和吸附性较好,为深入开展页岩气勘探目标区优选奠定了工作基础。     

Noah-MP模型中积雪模拟对参数化方案的敏感性评估

针对Noah-MP模型多参数化方案、模拟结果不确定性范围难以确定的特点,选取北疆地区具有代表性的阿勒泰站气象资料作为模型驱动数据,探讨了积雪对多参数化方案的敏感性。在不考虑模型参数和驱动数据不确定性的条件下,设计了集合数为13824的多参数化方案集合模拟试验。选用Natural selection方法对物理过程的敏感性进行分析,并在敏感性分析结果的基础上进一步讨论了模拟结果的不确定性。结果表明:积雪对地表热交换、雨雪分离、土壤温度底层边界条件和第一层积雪或土壤时间方案4个物理过程敏感;在不考虑驱动数据和模型参数不确定性的条件下,多参数化方案集合模拟试验中的不确定性主要来源于敏感物理过程。去除敏感物理过程中能够明显降低模拟性能的参数化方案后,集合模拟结果的不确定性大幅减小。最后,根据分析结果构建了该站雪深和雪水当量模拟的最优参数化方案组合。