Relatively short-term correlation among deformation,degassing, and seismicity: a case study from Concepción volcano,Nicaragua

Concepción is a frequently active composite volcano in Nicaragua, and is located on Ometepe Island, within Lake Nicaragua. Significant eruptive activity took place at this volcano between March and May 2010, consisting of ash and gas explosions (VEI 1–2). We compare geodetic baseline changes observed with global positioning system (GPS), sulfur dioxide flux (SO₂), and seismic amplitude (SAM) data collected at Concepción during April – June, 2010, and February – April, 2011. Time series analysis reveals a remarkable correlation among the data sets during 2010, when the volcano was erupting. In contrast, the volcano was at its background level of activity in 2011 and the statistical correlation among the time series is not significant for this period. We explain the emergence of correlation among the time series during eruptive activity through modeling of the GPS data with emplacement of a magma column in an open conduit. In the model, magma rose in the conduit, between May 5 and 14, 2010, from a shallow reservoir located at ～ 1.8 km depth. Later, between May 24 and 31, 2010, the top of the magma column descended to almost 600 m depth, corresponding to the cessation of eruptive activity. Thus, cross-correlation and an integrated analysis of these geophysical time series on a timescale of days helps to reveal the dynamics of the magma plumbing system operating below Concepción volcano.     

Environmental Factors Associated With Natural Methane Occurrence in the Appalachian Basin

The recent boom in shale gas development in the Marcellus Shale has increased interest in the methods to distinguish between naturally occurring methane in groundwater and stray methane associated with drilling and production operations. This study evaluates the relationship between natural methane occurrence and three principal environmental factors (groundwater redox state, water type, and topography) using two pre‐drill datasets of 132 samples from western Pennsylvania, Ohio, and West Virginia and 1417 samples from northeastern Pennsylvania. Higher natural methane concentrations in residential wells are strongly associated with reducing conditions characterized by low nitrate and low sulfate ([NO₃^?] < 0.5 mg/L; [SO₄^2?] < 2.5 mg/L). However, no significant relationship exists between methane and iron [Fe(II)], which is traditionally considered an indicator of conditions that have progressed through iron reduction. As shown in previous studies, water type is significantly correlated with natural methane concentrations, where sodium (Na) ‐rich waters exhibit significantly higher (p<0.001) natural methane concentrations than calcium (Ca)‐rich waters. For water wells exhibiting Na‐rich waters and/or low nitrate and low sulfate conditions, valley locations are associated with higher methane concentrations than upland topography. Consequently, we identify three factors (“Low NO₃^? & SO₄^2?” redox condition, Na‐rich water type, and valley location), which, in combination, offer strong predictive power regarding the natural occurrence of high methane concentrations. Samples exhibiting these three factors have a median methane concentration of 10,000 µg/L. These heuristic relationships may facilitate the design of pre‐drill monitoring programs and the subsequent evaluation of post‐drill monitoring results to help distinguish between naturally occurring methane and methane originating from anthropogenic sources or migration pathways.     

GPR investigation of tephra fallout, Cerro Negro volcano, Nicaragua: a method for constraining parameters used in tephra sedimentation models

Most tephra fallout models rely on the advection–diffusion equation to forecast sedimentation and hence volcanic hazards. Here, we test the application of the advection–diffusion equation to tephra sedimentation using data collected on the proximal (350 to ~1,200?m from the vent) to medial (greater than ~1,200?m from the vent) tephra blanket of a basaltic cinder cone, Cerro Negro volcano, located in Nicaragua. Our understanding of tephra depositional processes at this volcano is significantly improved by combination of sample pit data in the medial zone and high-resolution ground-penetrating radar (GPR) data collected in the near vent and proximal zones. If the advection–diffusion equation applies, then the thickness of individual tephra deposits should have Gaussian crosswind profiles and exponential decay with distance away from the vent. At Cerro Negro, steady trade winds coupled with brief eruptions of relatively low energy (VEI 2–3) create relatively simple deposits. GPR data were collected along three crosswind profiles at distances of 700–1,600?m from the vent; sample pits were used to estimate thickness of the 1992 tephra deposit up to 13?km from the vent. Horizons identified in proximal GPR profiles exhibit Gaussian distributions with a high degree of statistical confidence, with diffusion coefficients of ~500?m²?s^?1 estimated for the deposits, confirming that the advection–diffusion equation is capable of modeling sedimentation in the proximal zone. The thinning trend downwind of the vent decreases exponentially from the cone base (350?m) to ~1,200?m from the vent. Beyond this distance, deposit overthickening occurs, identified in both GPR and sample pit datasets. The combined data reveal three depositional regimes: (1) a near-vent region on the cone itself, where fallout remobilizes in granular flows upon deposition; (2) a proximal zone in which particles fall from a height of less than ~2?km; and (3) a medial zone, in which particles fall from ~4 to 7?km and the deposit is thicker than expected based on thinning trends observed in the proximal zone of the deposit. This overthickening of the tephra blanket, defining the transition from proximal to medial depositional facies, is indicative of transition from sedimentation dominated by fallout from plume margins to that dominated by fallout from the buoyant eruption cloud—a feature of deposits previously identified in larger-volume eruptions. We interpret this change to represent a change in diffusion law, occurring at total particle fall times (the fall time threshold of numerical models) of ~400?s. Thus, the detailed GPR profiles and pit data collected at Cerro Negro help to validate current numerical models of tephra sedimentation.     

利用DEM提取地貌指数的方法述评

介绍了几个广泛应用于水文科学的流域地貌指数(包括地表坡度、流量分配系数、单宽集水面积、集水面积以及湿度指数)的计算方法,阐述了这些地貌指数在水文科学中所代表的物理意义和对流域水文过程空间分布的描述能力。对了解流域地貌对降雨径流的影响,揭示产汇流过程的物理机制,研制和开发分布式水文物理模型均有重要意义。     

Potential for offsetting diamond mine carbon emissions through mineral carbonation of processed kimberlite: an assessment of De Beers mine sites in South Africa and Canada

De Beers kimberlite mine operations in South Africa (Venetia and Voorspoed) and Canada (Gahcho Kué, Victor, and Snap Lake) have the potential to sequester carbon dioxide (CO₂) through weathering of kimberlite mine tailings, which can store carbon in secondary carbonate minerals (mineral carbonation). Carbonation of ca. 4.7 to 24.0 wt% (average = 13.8 wt%) of annual processed kimberlite production could offset 100% of each mine site’s carbon dioxide equivalent (CO₂e) emissions. Minerals of particular interest for reactivity with atmospheric or waste CO₂ from energy production include serpentine minerals, olivine (forsterite), brucite, and smectite. The most abundant minerals, such as serpentine polymorphs, provide the bulk of the carbonation potential. However, the detection of minor amounts of highly reactive brucite in tailings from Victor, as well as the likely presence of brucite at Venetia, Gahcho Kué, and Snap Lake, is also important for the mineral carbonation potential of the mine sites.

     

Evaluation of Methane Sources in Groundwater in Northeastern Pennsylvania

Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium‐sodium‐bicarbonate, sodium‐bicarbonate, and sodium‐chloride rich waters—indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale‐gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale‐gas extraction.     

Chemical and genetic characterization of the ungrouped pallasite Lieksa

The meteorite Lieksa was found in 2017 in Löpönvaara, Finland, and later donated to the Finnish Museum of Natural History. Here, we report siderophile element concentrations, genetic isotopic data, and a metal–silicate segregation age for the meteorite. The ~280 g Lieksa is ~80% metal and ~20% silicate and oxide inclusions by volume, with the inclusions consisting primarily of Fe-rich olivine. Due to Lieksa's silicate content, coupled with a texture characterized by metal enclosing the silicates, it has been classified as a pallasite. Lieksa's olivine and bulk chemical characteristics are distinct from those of the known pallasite and iron meteorite groups, consistent with its classification as ungrouped. The meteorite exhibits a flat, chondrite-normalized highly siderophile element pattern, consistent with an origin as an early crystallization product from a metallic melt with chondritic relative abundances. Molybdenum, Ru, and ¹⁸³W isotopic data indicate that Lieksa formed in the non-carbonaceous (NC) domain of the solar nebula. Radiogenic ¹⁸²W abundances for Lieksa yield a model metal–silicate segregation age of 1.5 ± 0.8 Myr after calcium-aluminum-rich inclusion formation, which is within the range established for other NC-type pallasite and iron meteorite parent bodies.