Thermal processing and crystallization of amorphous Mg‐Ca silicates

The structural evolution of sol–gel‐produced amorphous Mg_(x)Ca_(1–x)SiO₃ silicates is investigated. Mid‐IR Fourier transform infrared spectroscopy and synchrotron X‐ray diffraction are used to confirm the amorphous nature of the as‐prepared silicates, while subsequent in situ synchrotron X‐ray powder diffraction measurements are used to study the evolution of crystalline mineral phases as a function of annealing temperature. Multiple silicate phases, including diopside, enstatite, forsterite, and SiO₂, are identified, while Rietveld (i.e., structure) refinement of the diffraction data is used to quantify phase change relationships. Investigated as possible analogs for the refractory dust grain materials likely to have been present in the early solar nebula, the likely relevance of these investigations to the observed silicate compositions of chondritic meteorites and cometary bodies and the processing of their precursor materials is discussed.     

Adsorption of copper and cobalt from fresh and marine systems

The adsorption of copper and cobalt from aqueous solution on to illite and other substrates has been studied as a function of pH, solution composition and solid phase concentration. The results are interpreted in terms of a model whereby the trace metals are adsorbed in exchange for surface bound H⁺ ions. Adsorption varies with solution ionic strength and the concentrations of complex forming ligands; both of these parameters tend to reduce the trace metal adsorption. The Cu²⁺ is two orders of magnitude more reactive toward solid surfaces than Co²⁺ , which is consistent with the general reactivities of these two metal ions. It is also found that Mg₂₊ interferes with adsorption, presumably by competing with the trace metals for the surface sites. A quantitative model was developed which describes adsorption of these metals from natural waters ranging from river water to sea water as a function of pH, complexing ligands and magnesium activity.     

Acute toxicity of heavy metals to some marine larvae

The toxicity of copper, mercury and zinc to the larvae of oysters, shrimp, crab and lobsters has been examined over periods of up to 64 hours. Mercury was found to be more toxic than copper and zinc, which had similar levels of toxicity. Over the experimental period, the relationship between toxicity and concentration was linear. Larvae were from 14 to 1,000 times more susceptible than adults of the same species. The median lethal concentrations (LC₅₀) of each metal to the most sensitive species of larvae, tested over a 48 hour period, exceeded the concentrations found in natural sea water by a factor of 100. For longer test periods, the LC₅₀ would be considerably less and this factor would then be considerably reduced. Hence the continued addition of these metals to confined waters should give cause for concern.     

Coastal issues and conflicts in North West Europe: A comparative analysis

This paper identifies and examines current coastal issues and conflicts in the northwest Europe region through the use of questionnaire surveys. The overall management concerns and outstanding problems across the region are highlighted and the results are presented in relation to previously identified management issues in northeast England, east Grampian in Scotland, and France. The survey presents a list of identified issues, each of which has a direct relationship to one of the 3 pillars of sustainable development, (environment, economic and social), and therefore the Lisbon Agenda (economic and social) and the Gothenburg Agenda (environment and environmental risk). The survey reveals that the important coastal management issues across the region are the large-scale concerns traditionally associated with ICZM: land-use planning, estuary management, natural resource and landscape protection, and water quality. Generally, respondents considered that management response to these issues is poor. Dissatisfaction levels were particularly high in France and Ireland, and to a lesser extent, in England. Water quality management escapes general criticism. This can be regarded as a positive finding, because it indicates that pan-European initiatives (the water-related EU directives) can deal effectively with this pan-European problem. The paper considers the links between the main issues across North West Europe and aims to distinguish how current coastal management practices have affected the range of issues arising.     

Causal thinking and support for climate change policies: International survey findings

Few comparative international studies describe the climate change policies people are willing to support and the reasons for their support of different policies. Using survey data from 664 economics and business undergraduates in Austria, Bangladesh, Finland, Germany, Norway, and the United States, we explore how perceived risk characteristics and mental models of climate change influence support for policy alternatives. General green policies such as funding research on renewable technologies and planting trees were the overwhelmingly most popular policy alternatives. Around half the students support carbon reduction policies such as requiring higher car fuel efficiency and increasing taxes on fossil fuels. Least popular were engineering alternatives such as fertilizing the oceans and replacing fossil fuels with nuclear power. Variations among nations are generally small. Support for different policy alternatives corresponds with different causal thinking. Those who hold a pollution model of the causes of climate change, tend to blame environmental harms (e.g., air pollution from toxic chemicals), see general green policy alternatives as effective, and support general green policies. Support of carbon reduction strategies is associated with seeing carbon emissions as the cause and reducing carbon emissions as effective solutions. Support of engineering solutions increases with identifying volcanoes among causes and regarding engineering solutions as effective. Although these international students agree that climate change is a threatening problem, their causal thinking correlates with support for different mitigative policy actions, with the most popular ones not necessarily the most effective.     

Modelling the hydrodynamics of offshore sandbanks

This paper describes the details of a quasi-three-dimensional model (3DBANK), which has been developed to investigate medium and long-term morphological evolution and development of offshore sandbanks. The model is based on a three-dimensional tidal module using the Galerkin-eigenfunction method, but also includes four sub-modules to compute: the instantaneous bedform characteristics from which the temporal and spatial variations of the shear stresses at the sea bed can be derived; the suspended sediment concentration through the water column; the bed-load and suspended sediment fluxes at a point-in-plan; and the resulting morphological changes, respectively. The model also includes the effects of the wind and waves at the sea surface, as well as the wave–current interaction (WCI), and operates with full hydrodynamic and morphodynamic interaction. The components of the model were tested against laboratory and field data, and the complete model was then applied to Middlekerke Bank off the Flemish coast where extensive field measurements were taken during the European Community (EC) funded Circulation and Sediment Transport Around Banks (CSTAB) Project using various advanced instrumentation including STABLE and HF OSCR. Comparisons of the model results with the field measurements and observations show that the model is capable of reproducing the current and wave-induced bedforms, bed roughness, tidal currents and tidal residuals around the sandbank satisfactorily, and can be used to study the long-term sandbank evolution under various offshore conditions. This paper, however, focuses on the hydrodynamic aspects of the model, while the details of the morphological components will be given in a companion paper.