Time-resolved,defect-hosted,trace element mobility in deformed Witwatersrand pyrite

The Pb isotopic composition of rocks is widely used to constrain the sources and mobility of melts and hydrothermal fluids in the Earth's crust. In many cases, the Pb isotopic composition appears to represent mixing of multiple Pb reservoirs. However, the nature, scale and mechanisms responsible for isotopic mixing are not well known. Additionally, the trace element composition of sulphide minerals are routinely used in ore deposit research, mineral exploration and environmental studies, though little is known about element mobility in sulphides during metamorphism and deformation. To investigate the mechanisms of trace element mobility in a deformed Witwatersrand pyrite(FeS_2), we have combined electron backscatter diffraction(EBSD) and atom probe microscopy(APM). The results indicate that the pyrite microstructural features record widely different Pb isotopic compositions, covering the entire range of previously published sulphide Pb compositions from the Witwatersrand basin. We show that entangled dislocations record enhanced Pb, Sb, Ni, Tl and Cu composition likely due to entrapment and short-circuit diffusion in dislocation cores. These dislocations preserve the Pb isotopic composition of the pyrite at the time of growth(~3 Ga) and show that dislocation intersections, likely to be common in deforming minerals, limit trace element mobility. In contrast, Pb, As, Ni, Co, Sb and Bi decorate a highangle grain boundary which formed soon after crystallisation by sub-grain rotation recrystallization.Pb isotopic composition within this boundary indicates the addition of externally-derived Pb and trace elements during greenschist metamorphism at ~2 Ga. Our results show that discrete Pb reservoirs are nanometric in scale, and illustrate that grain boundaries may remain open systems for trace element mobility over 1 billion years after their formation.     

Geological setting and SHRIMP U–Pb geochronological evidence for ca. 2680–2660 Ma lode-gold mineralization at Jundee–Nimary in the Yilgarn Craton, Western Australia

The 7 million oz. Jundee–Nimary lode-gold deposit occurs in the northern portion of the Yandal greenstone belt in the northeastern part of the Archean Yilgarn Craton of Western Australia. Gold mineralization at Jundee–Nimary is similar in structural style, mineralogy, geochemistry and relative timing with respect to deformation and metamorphism, to other Western Australian Archean greenstone-hosted gold deposits, but is unusual in the fact that mineralized structures are crosscut by structurally late intermediate to felsic dykes. Within the Deakin South open cut, gold mineralization is hosted in brittle–ductile shear zones primarily developed within the dacitic Mitchell Porphyry. The Moore Porphyry, a broad dyke of porphyritic granodiorite, intrudes the Mitchell Porphyry, crosscutting and post-dating gold mineralization. Analytically indistinguishable SHRIMP U–Pb zircon ages of 2678 ± 5 Ma for the Mitchell Porphyry and 2669 ± 7 Ma for the Moore Porphyry require that gold mineralization at Jundee–Nimary occurred at ca. 2680–2660 Ma, approximately 40 million years earlier than the majority of published robust ages for gold mineralization in the Yilgarn Craton, which mostly overlap at ca. 2640–2630 Ma. The close spatial and temporal relationship between gold mineralization and felsic to intermediate magmatism at Jundee–Nimary also raises the possibility of a genetic link between hydrothermal and igneous activity. However, additional work is required to establish a firm connection. Current research on lode-gold mineralization in Archean, Paleozoic and Phanerozoic terranes suggests a model which postulates that these deposits formed during transpressional to compressional deformation in accretionary and collisional orogens and that their formation is intimately related to orogenic processes. Consequently, mineralization and regional metamorphism are expected to be diachronous, as terranes are accreted and the front of orogenesis migrates. Consideration of the new data presented in this paper in conjunction with previously published dates supports the hypothesis that gold mineralization, along with regional metamorphism, was generally diachronous from northeast to southwest across the Yilgarn Craton, over a period of approximately 40 million years from ca. 2680–2660 Ma to ca. 2640–2630 Ma. This is directly analogous to the accepted model for the timing of orogenic lode-gold mineralization in other provinces and therefore provides further support for a unified model for this style of deposit through geological time. Received: 17 March 2000 / Accepted: 8 September 2000     

Variations in Isochore Thickness of the Ecca Sediments in the Eastern Cape Province of South Africa, as Deduced from Gravity Models

Gravity modelling was carried out along five profiles that traverse the Eastern Cape Province of South Africa in order to determine the depositional surface and isochore thickness of the Ecca sediments.Gravity models of the subsurface rock density reveal that the Ecca Group has a maximum vertical thickness of about 3215 ± 160 m.The maximum depositional surface(elevation)above sea level for the Ecca sediments is about 500 m,whilst the depth below sea level reaches about10000 m.Correlation of the isochore thickness maps with the depositional surfaces shows that the sediments in the basement highs were subsided,deformed,eroded and deposited in the basement lows.The basement highs served as the source area(s) for the sediments in the basement lows,thus basement highs are characterized with thin sediment cover whilst the lows have thick sediment cover.     

The Late Cenozoic uplift – climate change paradox

The geologic evidence for worldwide uplift of mountain ranges in the Neogene is ambiguous. Estimates of paleoelevation vary, according to whether they are based on the characteristics of fossil floras, on the masses and grain sizes of eroded sediments, or on calculations of increased thickness of the lithosphere as a result of faulting. Detrital erosion rates can be increased both by increased relief in the drainage basin and by a change to more seasonal rainfall patterns. The geologic record provides no clear answer to the question whether uplift caused the climatic deterioration of the Neogene or whether the changing climate affected the erosion system in such a way as to create an illusion of uplift. We suggest that the spread of C₄ plants in the Late Miocene may have altered both the erosion and climate systems. These changes are responsible for the apparent contradictions between data supporting uplift and those supporting high elevations in the past.     

A transfer function for estimating paleoceanographic conditions based on deep-sea surface sediment distribution of radiolarian assemblages in the South Atlantic

A quantitative analysis of radiolarian species in 57 deep-sea surface sediment samples from the South Atlantic Ocean produced four geographically distinct assemblages (tropical, polar, gyre margin, and subtropical). The distributions of these assemblages or factors coincide with present-day patterns of sea-surface temperatures or water masses.These four assemblages were used to construct a transfer function relating radiolarian distribution in the surface sediments to present-day winter and summer temperatures using standard regression techniques. As a test of the quality of this transfer function, temperatures were estimated on surface sediment samples from the eastern South Pacific. The temperatures produced by the transfer function compared favorably with the observed (present-day) winter and summer sea-surface temperatures at these sites.     

Consumer shopping strategies and purchasing activity: An exploratory investigation

Geographers have relied on somewhat simplistic stimulus-response models to explain shopping expenditure patterns. It is argued that this has resulted in an emphasis on the end-points of the shopping process (places of purchase), rather than on the process itself; so failing to recognise that the same end-points can be reached along a variety of paths. More attention should be given to process and hence to the strategies consumers adopt when engaging in purchasing activity. In this exploratory study, set in a North Yorkshire parish, it was found that the criteria consumers used to select amongst retail outlets were associated with particlar styles of shopping activity, which were in turn tied to particular spatial patterns of purchasing.     

Cryospheric hazards and risk perceptions in the Sagarmatha (Mt. Everest) National Park and Buffer Zone,Nepal

Glacial lake outburst floods (GLOFs) are among the most serious cryospheric hazards for mountain communities. Multiple studies have predicted the potential risks posed by rapidly expanding glacial lakes in the Sagarmatha (Mt. Everest) National Park and Buffer Zone of Nepal. People’s perceptions of such cryospheric hazards can influence their actions, beliefs, and responses to those hazards and associated risks. This study provides a systematic approach that combines household survey data with ethnography to analyze people’s perceptions of GLOF risks and the socioeconomic and cultural factors influencing their perceptions. A statistical logit model of household data showed a significant positive correlation between the perceptions of GLOF risks and livelihood sources, mainly tourism. Risk perceptions are also influenced by spatial proximity to glacial lakes and whether a village is in potential flood zones. The 2016 emergency remediation work implemented in the Imja Tsho (glacial lake) has served as a cognitive fix, especially in the low-lying settlements. Much of uncertainty and confusions related GLOF risks among locals can be attributed to a disconnect between how scientific information is communicated to the local communities and how government climate change policies have been limited to awareness campaigns and emergency remediation efforts. A sustainable partnership of scientists, policymakers, and local communities is urgently needed to build a science-driven, community-based initiative that focuses not just in addressing a single GLOF threat but develops on a comprehensive cryospheric risk management plan and considers opportunities and challenges of tourism in the local climate adaptation policies.

     

Response of unconfined turbidity current to deep‐water fold and thrust belt topography: Orthogonal incidence on solitary and segmented folds

Sea‐floor topography of deep‐water folds is widely considered to have a major impact on turbidity currents and their depositional systems, but understanding the flow response to such features was limited mainly to conceptual notions inspired by small‐scale laboratory experiments. High‐resolution three‐dimensional numerical experiments can compensate for the lack of natural‐scale flow observations. The present study combines numerical modelling of thrusts with fault‐propagation folds by Trishear3D software with computational fluid dynamics simulations of a natural‐scale unconfined turbidity current by MassFlow‐3D? software. The study reveals the hydraulic and depositional responses of a turbidity current (ca 50 m thick) to typical topographic features that it might encounter in an orthogonal incidence on a sea‐floor deep‐water fold and thrust belt. The supercritical current (ca 10 m sec^?1) decelerated and thickened due to the hydraulic jump on the fold backlimb counter‐slope, where a reverse overflow formed through current self‐reflection and a reverse underflow was issued by backward squeezing of a dense near‐bed sediment load. The reverse flows were re‐feeding sediment to the parental current, reducing its waning rate and extending its runout. The low‐efficiency current, carrying sand and silt, outran a downslope distance of >17 km with only modest deposition (<0·2 m) beyond the fold. Most of the flow volume diverted sideways along the backlimb to surround the fold and spread further downslope, with some overspill across the fold and another hydraulic jump at the forelimb toe. In the case of a segmented fold, a large part of the flow went downslope through the segment boundary. Preferential deposition (0·2 to 1·8 m) occurred on the fold backlimb and directly upslope, and on the forelimb slope in the case of a smaller fold. The spatial patterns of sand entrapment revealed by the study may serve as guidelines for assessing the influence of substrate folds on turbiditic sedimentation in a basin.     

Characteristics of cloud-to-ground lightning in warm-season thunderstorms in the Central Great Plains

In July 2005, a field campaign was conducted in the Central Great Plains to obtain 60-field/s video imagery of lightning in correlation with reports from the U.S. National Lightning Detection Network (NLDN) and broadband electric field waveforms from the Los Alamos Sferic Array (LASA). A total of 342 GPS time-stamped cloud-to-ground (CG) flashes were recorded in 17 different sessions, and 311 (91%) of these were correlated with reports from the NLDN. Only 6 of the 17 recording sessions were dominated by flashes that lowered negative charge to ground, and 11 were dominated by positive CG flashes. A total of 103 flashes recorded on video were correlated with at least one NLDN report of negative CG strokes, 204 video flashes were correlated with one or two positive stroke reports, and 4 had bipolar reports. In this paper, we will give distributions of the estimated peak current, I_p, as reported by the NLDN, of negative and positive first strokes that were recorded on video, the multiplicity of strokes that were recorded on video, and the number of ground contacts per flash that were resolved on video. 41 (40%) of the negative flashes produced just a single-stroke on video, and 62 (60%) showed two or more strokes. The observed multiplicity of negative flashes averaged 2.83, which becomes about 3.14 after correcting for the finite time-resolution of the video camera. 195 (96%) of the positive flashes produced just a single-stroke on video, and 9 (4%) showed two strokes; therefore, the observed multiplicity of positive flashes averaged 1.04. Five out of 9 (56%) of the positive subsequent strokes re-illuminated a previous channel, and 4 out of 9 (44%) created a new ground contact. Simultaneous video, LASA, and NLDN measurements also allowed us to examine the classification of NLDN reports during 3 single-cell storms (one negative and two positive). Based on the LASA waveforms, a total of 204 out of 376 (54%) NLDN reports of CG strokes were determined to be for cloud pulses. The misclassified negative reports had |I_p| values ranging from 3.8 kA to 29.7 kA, but only 58 (24%) of these had |I_p| > 10 kA, and only one misclassified positive report had I_p > 20 kA. Radar analyses showed that most of the negative and positive CG strokes that were recorded on video were produced within or near the convective cores of storms. The radar imagery also showed that single-cell storms tended to produce one polarity of CG flashes at a time, and that such storms could switch rapidly from negative to positive CG flashes when the reflectivity was near maximum. Multiple-cell storms produced both negative and positive flashes over a broad region, but each polarity tended to cluster near regions of high-reflectivity.