Selective concentration of cesium in analcime during hydrothermal alteration,Yellowstone National Park,Wyoming

Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The $\text{Cs}\text{Cl}$ of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization.     

Towards evaluating cloud response to climate change using clustering technique identification of cloud regimes

Most of the discrepancies in the climate sensitivity of general circulation models (GCMs) are believed to be due to differences in cloud radiative feedback. Analysis of cloud response to climate change in different ‘regimes’ may offer a more detailed understanding of how the cloud response differs between GCMs. In which case, evaluation of simulated cloud regimes against observations in terms of both their cloud properties and frequency of occurrence will assist in assessing confidence in the cloud response to climate change in a particular GCM. In this study, we use a clustering technique on International Satellite Cloud Climatology Project (ISCCP) data and on ISCCP-like diagnostics from two versions of the Hadley Centre GCM to identify cloud regimes over four different geographical regions. The two versions of the model are evaluated against observational data and their cloud response to climate change compared within the cloud regime framework. It is found that cloud clusters produced by the more recent GCM, HadSM4, compare more favourably with observations than HadSM3. In response to climate change, although the net cloud response over particular regions is often different in the two models, in several instances the same basic processes may be seen to be operating. Overall, both changes in the frequency of occurrence of cloud regimes and changes in the properties (optical depth and cloud top height) of the cloud regimes contribute to the cloud response to climate change.     

Analysis of sustained long-period activity at Etna Volcano, Italy

Following the installation of a broadband network on Mt. Etna, sustained Long-Period (LP) activity was recorded accompanying a period of total quiescence and the subsequent onset of the 2004–2005 effusive episode. From about 56000 events detected by an automatic classification procedure, we analyse a subset of about 3000 signals spanning the December 17th, 2003–September 25th, 2004, time interval. LP spectra are characterised by several, unevenly-spaced narrow peaks spanning the 0.5–10 Hz frequency band. These peaks are common to all the recording sites of the network, and different from those associated with tremor signals. Throughout the analysed time interval, LP spectra and waveforms maintain significant similarity, thus indicating the involvement of a non-destructive source process that we interpret in terms of the resonance of a fluid-filled buried cavity. Polarisation analysis indicates radiation from a non-isotropic source involving large amounts of shear. Concurrently with LP signals, recordings from the summit station also depict Very-Long-Period (VLP) pulses whose rectilinear motion points to a region located beneath the summit craters at depths ranging between 800 and 1100 m beneath the surface. Based on a refined repicking of similar waveforms, we obtain robust locations for a selected subset of the most energetic LP events from probabilistic inversion of travel-times calculated for a 3D heterogenous structure. LP sources cluster in a narrow volume located beneath the summit craters, and extending to a maximum depth of ≈ 800 m beneath the surface. No causal relationships are observed between LP, VLP and tremor activities and the onset of the 2004–2005 lava effusions, thus indicating that magmatic overpressure played a limited role in triggering this eruption. These data represent the very first observation of LP and VLP activity at Etna during non-eruptive periods, and open the way to the quantitative modelling of the geometry and dynamics of the shallow plumbing system.     

Simulated effect of a forest road on near‐surface hydrologic response: redux

In the work reported here the comprehensive physics‐based Integrated Hydrology Model (InHM) was employed to conduct both three‐ and two‐dimensional (3D and 2D) hydrologic‐response simulations for the small upland catchment known as C3 (located within the H. J. Andrews Experimental Forest in Oregon). Results from the 3D simulations for the steep unchannelled C3 (i) identify subsurface stormflow as the dominant hydrologic‐response mechanism and (ii) show the effect of the down‐gradient forest road on both the surface and subsurface flow systems. Comparison of the 3D results with the 2D results clearly illustrates the importance of convergent subsurface flow (e.g. greater pore‐water pressures in the hollow of the catchment for the 3D scenario). A simple infinite‐slope model, driven by subsurface pore‐water pressures generated from the 3D and 2D hydrologic‐response simulations, was employed to estimate slope stability along the long‐profile of the C3 hollow axis. As expected, the likelihood of slope failure is underestimated for the lower pore pressures from the 2D hydrologic‐response simulation compared, in a relative sense, to the higher pore pressures from the 3D hydrologic response simulation. The effort reported herein provides a firm quantitative foundation for generalizing the effects that forest roads can have on near‐surface hydrologic response and slope stability at the catchment scale. Copyright © 2006 John Wiley & Sons, Ltd.     

A Simple Temporal and Spatial Analysis of Flow in Complex Terrain in the Context of Wind Energy Modelling

A simple temporal and spatial analysisis done on wind speed and direction data from a number ofmeteorological towers separated by distances between roughly 1 and 100 kilometres. The analysis is done in the context of expected model error in wind energy calculations. The study first uses single point statistics to show the evolution of mean values with time. It is shown that strong seasonal signals are present and that stable means are achieved only after averaging periods of a year or more. The study then uses discrete Fourier transforms to show that significant amounts of spectral energy reside in modes with periods of a few days to less than a day. Frequency dependent cross correlation values are then derived and used to show how correlation between towers diminishes with increasing frequency. The mechanism responsible for this diminished correlation is shown through the comparison of cross-correlation phase as a function of frequency and its relationship to distance between towers. Error in wind energy estimates are shown to be strongly related to correlation and therefore distance over which the prediction is made. In summary, much of the inaccuracy in modelling flow in the context of wind energy calculations is due to a lack of scale separation between the deterministic part of the flow, which is well modelled, and that part of the flow that is stochastic at the length and time scales modelled.     

Using winter flounder growth rates to assess habitat quality across an anthropogenic gradient in Narragansett Bay, Rhode Island

We used growth rates of juvenile winter flounderPseudopleuronectes americanus to assess anthropogenic influence on habitat quality at three sites in Narragansett Bay, Rhode Island. The upper bay site, Gaspee Point, had the highest population density and concentration of total nitrogen; human inputs decreased down bay. Growth rates of individually marked fish were measured in three 15-d experiments from June 8 to July 6, 1998 in 1-m² cages placed at upper, middle, and lower bay sites. Water temperature, salinity, dissolved oxygen (DO), and benthic food were also measured. Stable isotopes of nitrogen and carbon were measured in experimental fish as possible indicators of nutrient enrichment and to identify organic carbon sources. Growth rates were 0.22–0.60 mm d⁻¹, with the highest average at the mid-bay site. Growth was initially fastest at Gaspee Point, but dropped off as DO concentrations fell. Step-wise multiple regression indicated that location (upper, middle, or lower bay) explained most of the variability in fish growth (40%). Coefficients of other significant variables indicated that fish grew faster at lower salinities, smaller sizes, and with decreased time that DO was below 2.3 mg l⁻¹. Benthic prey varied among sites and there was significantly less food and fewer species at Gaspee Point.Polydora cornuta was a favored food at all sites and was found in over half the stomachs. Values of δ¹⁵N in fish and sediments did not reflect differences in total nitrogen concentrations recorded near the sites. We suggest that anthropogenic influences, such as nutrients and sewage, affected habitat quality by reducing DO, which lowered fish growth rates.     

R. E. (Ted) Munn — Founding editor; a mini-biography

Ted Munn founded Boundary-Layer Meteorology in 1970 and served as Editor for 75 volumes over a 25 year period. This short article briefly reviews Ted's scientific career with the Atmospheric Environment Service (of Canada), the International Institute for Applied Systems Analysis in Austria and with the Institute of Environmental Studies at the University of Toronto, and as editor of this journal.     

Geochemistry of waters in the Valley of Ten Thousand Smokes region, Alaska

Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8°C in early summer and from 15 to 17°C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area.Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953–1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation.