Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Fishers' responses to management measures and their socio-economic effects

This session presented a wide range of papers on cooperativeresearch, design of alternative gears and fishing strategies,and new analyses to support management. The contributed papersreflected a real desire to explore different approaches andstrategies to fishery management. It is apparent that fishery policy has had a mixed record ofsuccess and failure at best. In most regions of the world, manystocks are still being overfished or have been severely overfishedin the past. Although rebuilding programmes for overfished stockshave been developed, nationally as well as internationally,only a few have been successful, many others are works in progressand, in too many cases, rebuilding     

Relationship between the seismicity and geologic structure of the Blanco Transform Fault Zone

Morphologic studies of an oceanic transform, the Blanco Transform Fault Zone (BTFZ), have shown it to consist of a series of extensional basins that offset the major strike-slip faults. The largest of the extensional basins, the Cascadia Depression, effectively divides the transform into a northwest segment, composed of several relatively short strike-slip faults, and a southeast segment dominated by fewer, longer faults. The regional seismicity distribution (m _b 4.0) and frequency-magnitude relationships (b-values) of the BTFZ show that the largest magnitude events are located on the southeast segment. Furthermore, estimates of the cumulative seismic moment release and seismic moment release rate along the southeast segment are significantly greater than that of the northwest segment. These observations suggest that slip along the southeast segment is accommodated by a greater number of large magnitude earthquakes. Comparison of the seismic moment rate, derived from empirical estimates, with the seismic moment rate determined from plate motion constraints suggests a difference in the seismic coupling strength between the segments. This difference in coupling may partially explain the disparity in earthquake size distribution. However, the results appear to confirm the relation between earthquake size and fault length, observed along continental strike-slip faults, for this oceanic transform.     

Geomorphology and sedimentology of the continental shelf adjacent to Mac. Robertson Land,East Antarctica: A scalped shelf

During the Quaternary, the Mac. Robertson shelf of East Antarctica was deeply eroded by glaciers and currents exposing the underlying basement, resulting in a scalped shelf. Major geomorphic zones are: (1) high-relief, ridge and valley topography (200–1400 m); (2) smooth sea floors associated with low-energy, depositional shelf valleys and basins (400–800 m); (3) low-relief, planated banktops (100–200 m); and (4) iceberg gouged and current reworked seaward-bank margins and upper slope (200 to < 630 m). About 90% of the shelf's surface has net erosional conditions and about 10% is net depositional. The sedimentary processes and deposits may be common to large areas of the East Antarctic margin.     

Tidally incised valleys on tropical carbonate shelves: An example from the northern Great Barrier Reef, Australia

The formation of incised valleys on continental shelves is generally attributed to fluvial erosion under low sea level conditions. However, there are exceptions. A multibeam sonar survey at the northern end of Australia's Great Barrier Reef, adjacent to the southern edge of the Gulf of Papua, mapped a shelf valley system up to 220 m deep that extends for more than 90 km across the continental shelf. This is the deepest shelf valley yet found in the Great Barrier Reef and is well below the maximum depth of fluvial incision that could have occurred under a − 120 m, eustatic sea level low-stand, as what occurred on this margin during the last ice age. These valleys appear to have formed by a combination of reef growth and tidal current scour, probably in relation to a sea level at around 30–50 m below its present position.

Tidally incised depressions in the valley floor exhibit closed bathymetric contours at both ends. Valley floor sediments are mainly calcareous muddy, gravelly sand on the middle shelf, giving way to well-sorted, gravely sand containing a large relict fraction on the outer shelf. The valley extends between broad platform reefs and framework coral growth, which accumulated through the late Quaternary, coincides with tidal current scour to produce steep-sided (locally vertical) valley walls. The deepest segments of the valley were probably the sites of lakes during the last ice age, when Torres Strait formed an emergent land-bridge between Australia and Papua New Guinea. Numerical modeling predicts that the strongest tidal currents occur over the deepest, outer-shelf segment of the valley when sea level is about 40–50 m below its present position. These results are consistent with a Pleistocene age and relict origin of the valley.

Based on these observations, we propose a new conceptual model for the formation of tidally incised shelf valleys. Tidal erosion on meso- to macro-tidal, rimmed carbonate shelves is enhanced during sea level rise and fall when a tidal, hydraulic pressure gradient is established between the shelf-lagoon and the adjacent ocean basin. Tidal flows attain a maximum, and channel incision is greatest, when a large hydraulic pressure gradient coincides with small channel cross sections. Our tidal-incision model may explain the observation of other workers, that sediment is exported from the Great Barrier Reef shelf to the adjacent ocean basins during intermediate (rather than last glacial maximum) low-stand, sea level positions. The model may apply to other rimmed shelves, both modern and ancient.     

Spatial Variation in the Structure of Kelp Forest Communities Along a Wave Exposure Gradient

Abstract. Four sites were sampled in kelp (Macrocysiis pyrifera) forests occupying rocky bottom habitats along a wave exposure gradient in central California. Consistent betwecn-site differences were found in the three major structural elements - the surface canopy, the undcrstory assemblage, and the ground cover/turf assemblage - of kelp forest communities. Macrocysiis pyrifera was found at all four sites. Nereucyslis tuelkeana only at the most exposed site. The understory kelps Laminaria setchellii and Pterygopltora californica were also characteristic of exposed sites. Articulated coralline algae were more abundant at exposed sites than protected, while fleshy red algae showed the opposite pattern. All four study sites were located along 8.5 km of coastline, and thus were assumed to have available to them the same species pool for colonization. The substrate composition was the same and the amount of unconsolidated substrate was similar at all four sites. We suggest that exposure to wave-generated water motion, through its influence on the surface canopy and therefore on the amount of light reaching the bottom, is responsible for these between-site differences.     

Nutrient attenuation in a shallow,gravel-bed river. II. Spatial and temporal changes in nitrogen dynamics and community metabolism

ABSTRACT

Instream processes alter the concentration and bioavailability of nutrients as they are transported downstream. By relating primary production and periphyton composition to changes in nutrient concentration in a gravel-bed river this study made inferences about recycling and attenuation. Where dissolved inorganic nitrogen (DIN) was abundant, concentrations decreased linearly with distance but by less than required to meet the nitrogen demand of primary production. Where DIN was barely measurable photosynthesis was reduced but only by 50%. We infer that recycling sustained primary production even when DIN concentrations were negligibly small. One implication is that DIN removal underestimates attenuation. Further experimental research on recycling and improved modelling is required to better quantify the length of streams adversely affected by nutrients.     

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.