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31.
“Salt” giants are typically halite‐dominated, although they invariably contain other evaporite (e.g. anhydrite, bittern salts) and non‐evaporite (e.g. carbonate, clastic) rocks. Rheological differences between these rocks mean they impact or respond to rift‐related, upper crustal deformation in different ways. Our understanding of basin‐scale lithology variations in ancient salt giants, what controls this and how this impacts later rift‐related deformation, is poor, principally due to a lack of subsurface datasets of sufficiently regional extent. Here we use 2D seismic reflection and borehole data from offshore Norway to map compositional variations within the Zechstein Supergroup (ZSG) (Lopingian), relating this to the structural styles developed during Middle Jurassic‐to‐Early Cretaceous rifting. Based on the proportion of halite, we identify and map four intrasalt depositional zones (sensu Clark et al., Journal of the Geological Society, 1998, 155, 663) offshore Norway. We show that, at the basin margins, the ZSG is carbonate‐dominated, whereas towards the basin centre, it becomes increasingly halite‐dominated, a trend observed in the UK sector of the North Sea Basin and in other ancient salt giants. However, we also document abrupt, large magnitude compositional and thickness variations adjacent to large, intra‐basin normal faults; for example, thin, carbonate‐dominated successions occur on fault‐bounded footwall highs, whereas thick, halite‐dominated successions occur only a few kilometres away in adjacent depocentres. It is presently unclear if this variability reflects variations in syn‐depositional relief related to flooding of an underfilled presalt (Early Permian) rift or syn‐depositional (Lopingian) rift‐related faulting. Irrespective of the underlying controls, variations in salt composition and thickness influenced the Middle Jurassic‐to‐Early Cretaceous rift structural style, with diapirism characterising hangingwall basins where autochthonous salt was thick and halite‐rich and salt‐detached normal faulting occurring on the basin margins and on intra‐basin structural highs where the salt was too thin and/or halite‐poor to undergo diapirism. This variability is currently not captured by existing tectono‐stratigraphic models largely based on observations from salt‐free rifts and, we argue, mapping of suprasalt structural styles may provide insights into salt composition and thickness in areas where boreholes are lacking or seismic imaging is poor.  相似文献   
32.
Two thermal parameters, initial volatilization temperature (IVT) and average volatilization rate (AVR), have been determined by thermogravimetric analysis in argon for 38 coal samples ranging in rank from lignite to low-volatile bituminous. Both IVT and AVR are correlated with percent volatile matter and vitrinite reflectance.The IVT values increase gradually from about 250 to 445°C with increasing rank; however, a change in slope is observed in the region of high-volatile bituminous coals (from about 340°C to about 380°C) when IVT's are plotted against percent volatile matter or percent fixed carbon. The changes in slope near 340°C and near 380°C occur at “coalification jumps” recognized on the basis of changes in the optical and chemical character of the macerals. In general, AVR values decrease gradually with increasing rank for the lignite and sub-bituminous coals and for the medium- and low-volatile bituminous coals; however, a sharp increase in AVR occurs in high-volatile bituminous coals. The change in slope of the IVT curves and sharp increase in the AVR values for high-volatile bituminous coals reflect the development of new, higher vapor pressure organic compounds produced during this stage of the coalification process.A plot of AVR vs IVT reveals three regions which correspond to: (1) lignite and sub-bituminous coals; (2) high-volatile bituminous coals; and (3) medium- to low-volatile bituminous coals.  相似文献   
33.
R. Burgess  G.B. Kiviets  J.W. Harris 《Lithos》2004,77(1-4):113-124
Ar–Ar age measurements are reported for selected eclogitic clinopyroxene and garnet inclusions in Orapa diamonds and clinopyroxene inclusions in Venetia diamonds. Laser drilling of encapsulated clinopyroxene inclusions within Venetia diamonds released a maximum of 3% of the total 40Ar, indicating little diffusive transfer and storage of radiogenic 40Ar at the diamond–inclusion boundary. Apparent ages obtained during stepped heating of three diamonds are consistent with diamond crystallisation occurring just prior to the kimberlite eruption 520 Ma ago. Stepped heating of three clinopyroxene-bearing Orapa diamonds gave ages of 906–1032 Ma, significantly above the eruption age, but consistent with previously determined isotopic ages. A few higher apparent ages hint at the presence an older generation of Orapa diamonds that formed >2500 Ma ago. Orapa garnets also contain measurable K contents, and record a range of ages between 1000 and 2500 Ma. The old apparent ages and lack of significant interface 40Ar released by the laser probe, suggests that pre-eruption radiogenic 40Ar and mantle-derived 40Ar components are trapped in microinclusions within the pyroxene and garnet inclusions.  相似文献   
34.
In 1996 Bennett published a cladistic analysis of the Archosauromorpha with 14 taxa and 126 characters, combining all the characters from several previous analyses (e.g., Gauthier 1984, Sereno and Arcucci 1990, Benton and Clark 1988) unless justification for discarding a character could be presented.  相似文献   
35.
Building pressure cycling (BPC) is becoming an increasingly important tool for studying vapor intrusion. BPC has been used to distinguish subslab and indoor sources of vapor intrusion as well as to define reasonable worst case volatile organic compound mass discharge into a structure. Analyses have been performed both semi-quantitatively with concentration trends and quantitatively with more rigorous flux calculation and source attribution methods. This paper reviews and compares the protocols and outcomes from multiple published applications of this technology to define the key variables that control performance. Common lessons learned are identified, including those that help define the range of building size and type to which BPC is applicable. Differences in test protocols are discussed, recognizing that the complexity of the test protocol required depends on the particular objectives of each project. Research gaps are identified and tabulated for future validation studies and applications.  相似文献   
36.
The objective of this study was to evaluate the effect of mine tailings composition on shear behavior and shear strength of co-mixed mine waste rock and tailings (WR&T). Crushed gravel was used as a synthetic waste rock and mixed with four types of tailings: (1) fine-grained garnet, (2) coarse-grained garnet, (3) copper, and (4) soda ash. Co-mixed WR&T specimens were prepared to target mixture ratios of mass of waste rock to mass of tailings (R) such that tailings “just filled” interparticle void space of the waste rock (i.e., optimum mixture ratio, R opt). Triaxial compression tests were conducted on waste rock, tailings, and mixed waste at effective confining stresses (\(\sigma_{\text{c}}^{{\prime }}\)) ranging from 5 to 40 kPa to represent stresses anticipated in final earthen covers for waste containment facilities. Waste rock and co-mixed WR&T specimens were 150 mm in diameter by 300 mm tall, whereas tailings specimens were 38 mm in diameter by 76 mm tall. Shear strength was quantified using effective stress friction angles (?′) from undrained tests: ?′ for waste rock was 37°, ?′ for tailings ranged from 34° to 41°, and ?′ for WR&T mixtures ranged from 38° to 40°. Thus, shear strength of co-mixed WR&T was comparable to waste rock regardless of tailings composition. Shear behavior of WR&T mixtures was a function of R and tailings composition. Tailings influenced shear behavior for R < R opt and when tailings predominantly were silt. Shear behavior was influenced by waste rock for R ≥ R opt and when tailings predominantly were sand or included clay particles.  相似文献   
37.
This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg–1 pH of 7.6 and p(CO2) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg–1, pH of 7.70 and p(CO2) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO2) up to 5.6 times the atmospheric P(CO2).  相似文献   
38.
The tropical fruit durian in Southeast and East Asia has witnessed a surge in popularity in the past two decades to assume the rank of a fetishized commodity. This research investigates the construction of the multidimensional concept of terroir as applied to the durian economy of Penang, Malaysia based on personal interviews with orchard owners and state government officials to strategically embed the local in the global through the promotion of agritourism. While environmental terroir is a contingent dimension, the construction of a place bound cultural terror is anchored in a strong cultivation tradition, cultivar diversity, and a historical sense of community. This research deepens the cultural terroir dimension in two ways. First, it injects the otherwise aspatial concept of refinement to the cultural terroir narratives of orchard owners allowing the on-farm tourist consumption experience to be more geographically rooted. Second, it conceptually links cultural terroir to the marketing terroir instrument of the Balik Pulau geographical indication; while functioning as a governance tool to prevent fraud and to construct a place bound product valorization and differentiation within an expanding and larger scale durian economy, it also indirectly assists in preserving agro-diversity and local identity.  相似文献   
39.
Extensional faults and folds exert a fundamental control on the location, thickness and partitioning of sedimentary deposits on rift basins. The connection between the mode of extensional fault reactivation, resulting fault shape and extensional fold growth is well‐established. The impact of folding on accommodation evolution and growth package architecture, however, has received little attention; particularly the role‐played by fault‐perpendicular (transverse) folding. We study a multiphase rift basin with km‐scale fault displacements using a large high‐quality 3D seismic data set from the Fingerdjupet Subbasin in the southwestern Barents Sea. We link growth package architecture to timing and mode of fault reactivation. Dip linkage of deep and shallow fault segments resulted in ramp‐flat‐ramp fault geometry, above which fault‐parallel fault‐bend folds developed. The folds limited the accommodation near their causal faults, leading to deposition within a fault‐bend synclinal growth basin further into the hangingwall. Continued fold growth led to truncation of strata near the crest of the fault‐bend anticline before shortcut faulting bypassed the ramp‐flat‐ramp structure and ended folding. Accommodation along the fault‐parallel axis is controlled by the transverse folds, the location and size of which depends on the degree of linkage in the fault network and the accumulated displacement on causal faults. We construct transverse fold trajectories by tracing transverse fold hinges through space and time to highlight the positions of maximum and minimum accommodation and potential sediment entry points to hangingwall growth basins. The length and shape of the constructed trajectories relate to the displacement on their parent faults, duration of fault activity, timing of transverse basin infill, fault linkage and strain localization. We emphasize that the considerable wavelength, amplitudes and potential periclinal geometry of extensional folds make them viable targets for CO2 storage or hydrocarbon exploration in rift basins.  相似文献   
40.
Strain style, magnitude and distribution within mass‐transport complexes (MTCs) are important for understanding the process evolution of submarine mass flows and for estimating their runout distances. Structural restoration and quantification of strain in gravitationally driven passive margins have been shown to approximately balance between updip extensional and downdip contractional domains; such an exercise has not yet been attempted for MTCs. We here interpret and structurally restore a shallowly buried (c. 1,500 mbsf) and well‐imaged MTC, offshore Uruguay using a high‐resolution (12.5 m vertical and 15 × 12.5 m horizontal resolution) three‐dimensional seismic‐reflection survey. This allows us to characterise and quantify vertical and lateral strain distribution within the deposit. Detailed seismic mapping and attribute analysis shows that the MTC is characterised by a complicated array of kinematic indicators, which vary spatially in style and concentration. Seismic‐attribute extractions reveal several previously undocumented fabrics preserved in the MTC, including internal shearing in the form of sub‐orthogonal shear zones, and fold‐thrust systems within the basal shear zone beneath rafted‐blocks. These features suggest multiple transport directions and phases of flow during emplacement. The MTC is characterised by a broadly tripartite strain distribution, with extensional (e.g. normal faults), translational and contractional (e.g. folds and thrusts) domains, along with a radial frontally emergent zone. We also show how strain is preferentially concentrated around intra‐MTC rafted‐blocks due to their kinematic interactions with the underlying basal shear zone. Overall, and even when volume loss within the frontally emergent zone is included, a strain difference between extension (1.6–1.9 km) and contraction (6.7–7.3 km) is calculated. We attribute this to a combination of distributed, sub‐seismic, ‘cryptic’ strain, likely related to de‐watering, grain‐scale deformation and related changes in bulk sediment volume. This work has implications for assessing MTCs strain distribution and provides a practical approach for evaluating structural interpretations within such deposits.  相似文献   
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