Environmental changes in northern New Zealand since the Middle Holocene inferred from stable isotope records (δ15N, δ13C) of Lake Pupuke

Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??¹³C_OM) and nitrogen (??¹⁵N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??¹⁵N and ??¹³C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.     

Identification of groundwater mean transit times of precipitation and riverbank infiltration by two‐component lumped parameter models

Groundwater transit time is an essential hydrologic metric for groundwater resources management. However, especially in tropical environments, studies on the transit time distribution (TTD) of groundwater infiltration and its corresponding mean transit time (mTT) have been extremely limited due to data sparsity. In this study, we primarily use stable isotopes to examine the TTDs and their mTTs of both vertical and horizontal infiltration at a riverbank infiltration area in the Vietnamese Mekong Delta (VMD), representative of the tropical climate in Asian monsoon regions. Precipitation, river water, groundwater, and local ponding surface water were sampled for 3 to 9 years and analysed for stable isotopes (δ¹⁸O and δ²H), providing a unique data set of stable isotope records for a tropical region. We quantified the contribution that the two sources contributed to the local shallow groundwater by a novel concept of two‐component lumped parameter models (LPMs) that are solved using δ¹⁸O records. The study illustrates that two‐component LPMs, in conjunction with hydrological and isotopic measurements, are able to identify subsurface flow conditions and water mixing at riverbank infiltration systems. However, the predictive skill and the reliability of the models decrease for locations farther from the river, where recharge by precipitation dominates, and a low‐permeable aquitard layer above the highly permeable aquifer is present. This specific setting impairs the identifiability of model parameters. For river infiltration, short mTTs (<40 weeks) were determined for sites closer to the river (<200 m), whereas for the precipitation infiltration, the mTTs were longer (>80 weeks) and independent of the distance to the river. The results not only enhance the understanding of the groundwater recharge dynamics in the VMD but also suggest that the highly complex mechanisms of surface–groundwater interaction can be conceptualized by exploiting two‐component LPMs in general. The model concept could thus be a powerful tool for better understanding both the hydrological functioning of mixing processes and the movement of different water components in riverbank infiltration systems.     

Intercomparison of measurements of bulk snow density and water equivalent of snow cover with snow core samplers: Instrumental bias and variability induced by observers

Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.     

Magma evolution and the formation of porphyry Cu–Au ore fluids: evidence from silicate and sulfide melt inclusions

Silicate and sulfide melt inclusions from the andesitic Farallón Negro Volcanic Complex in NW Argentina were analyzed by laser ablation ICPMS to track the behavior of Cu and Au during magma evolution, and to identify the processes in the source of fluids responsible for porphyry-Cu-Au mineralization at the 600 Mt Bajo de la Alumbrera deposit. The combination of silicate and sulfide melt inclusion data with previously published geological and geochemical information indicates that the source of ore metals and water was a mantle-derived mafic magma that contained approximately 6 wt.% H₂O and 200 ppm Cu. This magma and a rhyodacitic magma mixed in an upper-crustal magma chamber, feeding the volcanic systems and associated subvolcanic intrusions over 2.6 million years. Generation of the ore fluid from this magma occurred towards the end of this protracted evolution and probably involved six important steps: (1) Generation of a sulfide melt upon magma mixing in some parts of the magma chamber. (2) Partitioning of Cu and Au into the sulfide melt (enrichment factor of 10,000 for Cu) leading to Cu and Au concentrations of several wt.% or ppm, respectively. (3) A change in the tectonic regime from local extension to compression at the end of protracted volcanism. (4) Intrusion of a dacitic magma stock from the upper part of the layered magma chamber. (5) Volatile exsolution and resorption of the sulfide melt from the lower and more mafic parts of the magma chamber, generating a fluid with a Cu/Au ratio equal to that of the precursor sulfide. (6) Focused fluid transport and precipitation of the two metals in the porphyry, yielding an ore body containing Au and Cu in the proportions dictated by the magmatic fluid source. The Cu/S ratio in the sulfide melt inclusions requires that approximately 4,000 ppm sulfur is extracted from the andesitic magma upon mixing. This exceeds the solubility of sulfide or sulfate in either of the silicate melts and implies an additional source for S. The extra sulfur could be added in the form of anhydrite phenocrysts present in the rhyodacitic magma. It appears, thus, that unusually sulfur-rich, not Cu-rich magmas are the key to the formation of porphyry-type ore deposits. Our observations imply that dacitic intrusions hosting the porphyry–Cu–Au mineralization are not representative of the magma from which the ore-fluid exsolved. The source of the ore fluid is the underlying more mafic magma, and unaltered andesitic dikes emplaced immediately after ore formation are more likely to represent the magma from which the fluids were generated. At Alumbrera, these andesitic dikes carry relicts of the sulfide melt as inclusions in amphibole. Sulfide inclusions in similar dykes of other, less explored magmatic complexes may be used to predict the Au/Cu ratio of potential ore-forming fluids and the expected metal ratio in any undiscovered porphyry deposit.Editorial handling: B. Lehmann     

Neoproterozoic calc‐alkaline peraluminous granitoids of the Deleihimmi pluton,Central Eastern Desert,Egypt: implications for transition from late‐ to post‐collisional tectonomagmatic evolution in the northern Arabian–Nubian Shield

The widely distributed late‐collisional calc‐alkaline granitoids in the northern Arabian–Nubian Shield (ANS) have a geodynamic interest as they represent significant addition of material into the ANS juvenile crust in a short time interval (∼630–590 Ma). The Deleihimmi granitoids in the Egyptian Central Eastern Desert are, therefore, particularly interesting since they form a multiphase pluton composed largely of late‐collisional biotite granitoids enclosing granodiorite microgranular enclaves and intruded by leuco‐ and muscovite granites. Geochemically, different granitoid phases share some features and distinctly vary in others. They display slightly peraluminous (ASI = 1–1.16), non‐alkaline (calc‐alkaline and highly fractionated calc‐alkaline), I‐type affinities. Both biotite granitoids and leucogranites show similar rare earth element (REE) patterns [(La/Lu)_N = 3.04–2.92 and 1.9–1.14; Eu/Eu* = 0.26–0.19 and 0.11–0.08, respectively) and related most likely by closed system crystal fractionation of a common parent. On the other hand, the late phase muscovite granites have distinctive geochemical features typical of rare‐metal granites. They are remarkably depleted in Sr and Ba (4–35 and 13–18 ppm, respectively), and enriched in Rb (381–473 ppm) and many rare metals. Moreover, their REE patterns show a tetrad effect (TE_1,3 = 1.13 and 1.29) and pronounced negative Eu anomalies (Eu/Eu* = 0.07 and 0.08), implying extensive open system fractionation via fluid–rock interaction during the magmatic stage. Origin of the calc‐alkaline granitoids by high degree of partial melting of mafic lower crust with subsequent crystal fractionation is advocated. The broad distribution of late‐collisional calc‐alkaline granitoids in the northern ANS is related most likely to large areal and intensive lithospheric delamination subsequent to slab break‐off and crustal/mantle thickening. Such delamination caused both crustal uplift and partial melting of the remaining mantle lithosphere in response to asthenospheric uprise. The melts produced underplate the lower crust to promote its melting. The presence of microgranular enclaves, resulting from mingling of mantle‐derived mafic magma with felsic crustal‐derived liquid, favours this process. The derivation of the late‐phase rare‐metal granites by open system fractionation via fluid interaction is almost related to the onset of extension above the rising asthenosphere that results in mantle degassing during the switch to post‐collisional stage. Consequently, the switch from late‐ to post‐collisional stage of crustal evolution in the northern ANS could be potentially significant not only geodynamically but also economically. Copyright © 2011 John Wiley & Sons, Ltd.     

Controls on event runoff coefficients in the eastern Italian Alps

Analyses of event runoff coefficients provide essential insight on catchment response, particularly if a range of catchments and a range of events are compared by a single indicator. In this study we examine the effect of climate, geology, land use, flood types and initial soil moisture conditions on the distribution functions of the event runoff coefficients for a set of 14 mountainous catchments located in the eastern Italian Alps, ranging in size from 7.3 to 608.4 km². Runoff coefficients were computed from hourly precipitation, runoff data and estimates of snowmelt. A total of 535 events were analysed over the period 1989–2004. We classified each basin using a “permeability index” which was inferred from a geologic map and ranged from “low” to “high permeability”. A continuous soil moisture accounting model was applied to each catchment to classify ‘wet’ and ‘dry’ initial soil moisture conditions. The results indicate that the spatial distribution of runoff coefficients is highly correlated with mean annual precipitation, with the mean runoff coefficient increasing with mean annual precipitation. Geology, through the ‘permeability index’, is another important control on runoff coefficients for catchments with mean annual precipitation less than 1200 mm. Land use, as indexed by the SCS curve number, influences runoff coefficient distribution to a lesser degree. An analysis of the runoff coefficients by flood type indicates that runoff coefficients increase with event snowmelt. Results show that there exists an intermediate region of subsurface water storage capacity, as indexed by a flow–duration curve-based index, which maximises the impact of initial wetness conditions on the runoff coefficient. This means that the difference between runoff coefficients characterised by wet and dry initial conditions is negligible both for basins with very large storage capacity and for basins with small storage capacity. For basins with intermediate storage capacities, the impact of the initial wetness conditions may be relatively large.     

Transpiration and plant water relations of evergreen woody vegetation on a recently constructed artificial ecosystem under seasonally dry conditions in Western Australia

Understanding transpiration and plant physiological responses to environmental conditions is crucial for the design and management of vegetated engineered covers. Engineered covers rely on sustained transpiration to reduce the risk of deep drainage into potentially hazardous wastes, thereby minimizing contamination of water resources. This study quantified temporal trends of plant water potential (ψ_p), stomatal conductance (g_s), and transpiration in a 4‐year‐old evergreen woody vegetation growing on an artificial sandy substrate at a mine waste disposal facility. Transpiration averaged 0.7 mm day^?1 in winter, when rainfall was frequent, but declined to 0.2 mm day^?1 in the dry summer, when the plants were quite stressed. In winter, the mean ψ_p was ?0.6 MPa at predawn and ?1.5 MPa at midday, which were much higher than the corresponding summer values of ?2.0 MPa and ?4.8 MPa, respectively. The g_s was also higher in winter (72.1–95.0 mmol m^?2 s^?1) than in summer (<30 mmol m^?2 s^?1), and negatively correlated with ψ_p (p < 0.05, r² = 0.71–0.75), indicating strong stomatal control of transpiration in response to moisture stress. Total annual transpiration (147.2 mm) accounted for only 22% of the annual rainfall (673 mm), compared with 77% to 99% for woody vegetation in Western Australia. The low annual transpiration was attributed to the collective effects of a sparse and young vegetation, low moisture retention of the sandy substrate, and a superficial root system constrained by high subsoil pH. Amending the substrate with fine‐textured materials should improve water storage of the substrate and enhance canopy growth and deep rooting, while further reducing the risk of deep drainage during the early stages of vegetation establishment and in the long term. Overall, this study highlights the need to understand substrate properties, vegetation characteristics, and rainfall patterns when designing artificial ecosystems to achieve specific hydrological functions. Copyright © 2011 John Wiley & Sons, Ltd.