Geochemical environment of Cenomanian - Turonian black shale deposition at Wunstorf (northern Germany)

Major- and minor- element determinations were carried out on a high-resolution sample set obtained from a sediment drill core at Wunstorf (N. Germany). This study interval includes the black shale-bearing Hesseltal Formation associated with the Oceanic Anoxic Event 2 (OAE 2), also referred to as Cenomanian-Turonian Boundary Event (CTBE). Seven black shale packages, each containing several black shale layers, were defined by elevated TOC values, with black shale packages 1-4 deposited during OAE 2. Packages 5-7 extend above the level of the positive carbon-isotope excursion defining OAE 2, indicating that conditions favouring organic carbon burial must have prevailed longer in the Wunstorf Basin than elsewhere. Geochemical analyses revealed no significant differences between black shale packages deposited during and after OAE 2. Enrichment patterns of sulphur, iron and redox-sensitive and sulphide-forming trace metals point to suboxic to anoxic conditions existing at the sediment-water interface during black shale deposition, whereas sulphidic conditions prevailed deeper in the sediment. Variations in element/Al ratios follow cyclic patterns which are interpreted to represent climatically-induced changes in sediment supply. Reduced vertical mixing led to water-column stratification and caused black shale deposition.     

IFKIS-Hydro: an early warning and information system for floods and debris flows

IFKIS-Hydro is an information and warning system for hydrological hazards in small- and medium-scale catchments. The system collects data such as weather forecasts, precipitation measurements, water level gauges, discharge simulations and local observations of event-specific phenomena. In addition, IFKIS-Hydro incorporates a web-based information platform, which serves as a central hub for the submission and overview of data. Special emphasis is given to local information. This is accomplished particularly by human observers. In medium-scale catchments, discharge forecast models have an increasing importance in providing valuable information. IFKIS-Hydro was developed in several test regions in Switzerland and the first results of its application are available now. The system is constantly extended to additional regions and may become the standard for warning systems in smaller catchments in Switzerland.     

Geological evolution of the West Luzon Basin (South China Sea,Philippines)

Interpretation of deep 2-D multi-channel seismic data sheds insights into the geological evolution of the West Luzon Basin, Philippines. This basin is a sediment-filled trough that is located between the island of Luzon and the outer arc high of the west Luzon subduction zone. High-amplitude, low-frequency reflection bands mark the acoustic basement. The basement, at about 6 s (TWT), is dissected by normal faults with some of them being inverted in a later phase of deformation. The sedimentary successions, overlying the basement are stratified with partly chaotic structures and discontinuous reflectors. Five regional unconformities separate major stratigraphic units. Grid calculations of our seismic data reveal variations in the sedimentation pattern of the basin with a shift of the deposition centre from east to west and backwards during formation. A distinct bottom-simulating reflector is commonly observed. Because the northern boundary of the continental fragments to the South of the West Luzon Basin is unclear we speculate that the basin may be (partly) underlain by continental crust. The continental crust was affected by rifting prior to and during the opening of the South China Sea and the basin was overprinted at a later stage by a forearc structural setting when subduction was initiated.     

Factors affecting the Nd3+ (REE3+) luminescence of minerals

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.     

CFD modeling of high-pressurized CO2 released from onshore pipeline leakages

Safe pipeline transportation of carbon dioxide is a critical issue in the developing field of carbon capture and storage technology. Inadequate fluid thermo- and regimes for on- and offshore transport through high-pressurized pipelines can induce pipe material obsolescence or even pipeline rupture. In such cases, CO₂ (Carbon dioxide) will be released and dispersed in the ambient medium. The dispersion is influenced by the total amount of released fluid, jet pressure and direction, the released concentrations, leakage hole size, ambient material properties and is also affected by the dynamical conditions of the environmental medium. The goal of this study is the hydrodynamical characterization of carbon dioxide jet expansion and dispersion in the ambient atmosphere in case of onshore pipeline accidental leaks. Numerical simulations were carried out by means of a 3D turbulent CFD (computational fluid dynamics) code which includes multi-component flow treatment. The influence of the jet release pressure and size of the leakage hole on harmful CO₂ concentration distances will be analyzed.     

Quantifying sediment storage in a high alpine valley (Turtmanntal,Switzerland)

The determination of sediment storage is a critical parameter in sediment budget analyses. But, in many sediment budget studies the quantification of magnitude and time‐scale of sediment storage is still the weakest part and often relies on crude estimations only, especially in large drainage basins (>100 km²). We present a new approach to storage quantification in a meso‐scale alpine catchment of the Swiss Alps (Turtmann Valley, 110 km²). The quantification of depositional volumes was performed by combining geophysical surveys and geographic information system (GIS) modelling techniques. Mean thickness values of each landform type calculated from these data was used to estimate the sediment volume in the hanging valleys and the trough slopes. Sediment volume of the remaining subsystems was determined by modelling an assumed parabolic bedrock surface using digital elevation model (DEM) data. A total sediment volume of 781·3×10⁶–1005·7×10⁶ m³ is deposited in the Turtmann Valley. Over 60% of this volume is stored in the 13 hanging valleys. Moraine landforms contain over 60% of the deposits in the hanging valleys followed by sediment stored on slopes (20%) and rock glaciers (15%). For the first time, a detailed quantification of different storage types was achieved in a catchment of this size. Sediment volumes have been used to calculate mean denudation rates for the different processes ranging from 0·1 to 2·6 mm/a based on a time span of 10 ka. As the quantification approach includes a number of assumptions and various sources of error the values given represent the order of magnitude of sediment storage that has to be expected in a catchment of this size. Copyright © 2009 John Wiley & Sons, Ltd.     

Concentrated flow erosion rates reduced through biological geotextiles

Soil erosion by concentrated flow can cause serious environmental damage. Erosion‐control geotextiles have considerable potential for reducing concentrated flow erosion. However, limited data are available on the erosion‐reducing potential of geotextiles. In this study, the effectiveness of three biological geotextiles in reducing soil losses during concentrated flow is investigated. Hereto, runoff was simulated in a concentrated flow flume, filled with an erodible sandy loam on three slope gradients (13·5, 27·0 and 41·5%). Treatments included three biological geotextiles (borassus, buriti and bamboo) and one bare soil surface. Darcy–Weisbach friction coefficients ranged from 0·01 to 2·84. The highest values are observed for borassus covered soil surfaces, followed by buriti, bamboo and bare soil, respectively. The friction coefficients are linearly correlated with geotextile thickness. For the specific experimental conditions of this study, borassus geotextiles reduced soil detachment rate on average to 56%, buriti geotextiles to 59% and bamboo geotextiles to 66% of the soil detachment rate for bare soil surfaces. Total flow shear stress was the hydraulic parameter best predicting soil detachment rate for bare and geotextile covered surfaces (R² = 0·75–0·84, p <0·001, n = 12–15). The highest resistance against soil detachment was observed for the borassus covered soil surfaces, followed by buriti, bamboo and bare soil surfaces, respectively. Overall, biological geotextiles are less effective in controlling concentrated flow erosion compared with interrill erosion. Copyright © 2009 John Wiley & Sons, Ltd.     

Heat Transport Processes in the Earth’s Crust

The heat of the Earth derives from internal and external sources. A heat balance shows that most of the heat provided by external sources is re-emitted by long-wavelength heat radiation and that the dominant internal sources are original heat and heat generated by decay of unstable radioactive isotopes. Understanding of the thermal regime of the Earth requires appreciation of properties and mechanisms for heat generation, storage, and transport. Both experimental and indirect methods are available for inferring the corresponding rock properties. Heat conduction is the dominant transport process in the Earth’s crust, except for settings where appreciable fluid flow provides a mechanism for heat advection. For most crustal and mantle rocks, heat radiation becomes significant only at temperatures above 1200°C.

Chronology building using objective identification of annual signals in trace element profiles of stalagmites

Determination of annual lamination provides important additional constraints to radiometric dates on speleothems, both for dating the duration of specific growth intervals and optimizing growth models. In the absence of visible laminae, however, speleothem age models are reliant upon curve fitting through discretely dated points and are therefore inherently more uncertain than annual chronologies from laminae. Given that the impact of seasonality on speleothems is expected to be strong enough to generate an annual pulse in trace element chemistry regardless of whether or not visible or fluorescent growth laminae are visible, we demonstrate the potential for deriving high-resolution stalagmite chronologies from non-laminated samples using annual chemical variations in stalagmites from two Alpine caves (Obir, Austria and Ernesto, NE Italy). Trace element data were obtained by ion microprobe analyses for H, P, Mg, Na, Sr and Ba and the annual signal was sought using spectral and wavelet analysis. An automated chemical peak-counting software tool was developed in MATLAB^©. It counts significant annual peaks using criteria of minimum amplitude in relation to the local standard deviation of signal variation and minimum separation between peaks determined by the thickness of the preceding layers. Verification of the tool using visibly laminated samples suggests the software is a reliable and accurate method of chronology building, with hit ratios greater than 0.93 and less than 0.75% false alarm occurrences. Used in conjunction with other dating methods such as radiocarbon, U–Th and sulphur peak dating, the automated chemical laminae chronology-building approach provides a more meaningful alternative to simple age-depth curve fitting for non-laminated samples.